Suspension graft polymerization by chain transfer

A. G. Maadhah; M. B. Amin; A. M. Usmani

doi:10.1007/BF00263459

Suspension graft polymerization by chain transfer

A. G. Maadhah^*, M. B. Amin, A. M. Usmani

^*Corresponding author for this work

King Fahd University of Petroleum & Minerals

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Poly(vinyl oxazoline ester) and poly(stearyl methacrylate) were found to be good alien polymers for grafting of methyl methacrylate by suspension polymerization whereas poly(tridecyl methacrylate) was not a good backbone. Azobisisobutyronitrile was found to be an inefficient grafting initiator where azocumene that produces highly resonance and hyperconjugated stabilized dimethyl phenyl methyl radical was a superior initiator to benzoyl peroxide for grafting. Poly(stearyl methacrylate) was found to be a suitable polymeric stabilizer for nonaqueous suspension polymerizations.

Original language	English
Pages (from-to)	433-438
Number of pages	6
Journal	Polymer Bulletin
Volume	14
Issue number	5
DOIs	https://doi.org/10.1007/BF00263459
State	Published - Nov 1985

ASJC Scopus subject areas

General Chemistry
Condensed Matter Physics
Polymers and Plastics
Materials Chemistry

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10.1007/BF00263459

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title = "Suspension graft polymerization by chain transfer",

abstract = "Poly(vinyl oxazoline ester) and poly(stearyl methacrylate) were found to be good alien polymers for grafting of methyl methacrylate by suspension polymerization whereas poly(tridecyl methacrylate) was not a good backbone. Azobisisobutyronitrile was found to be an inefficient grafting initiator where azocumene that produces highly resonance and hyperconjugated stabilized dimethyl phenyl methyl radical was a superior initiator to benzoyl peroxide for grafting. Poly(stearyl methacrylate) was found to be a suitable polymeric stabilizer for nonaqueous suspension polymerizations.",

author = "Maadhah, {A. G.} and Amin, {M. B.} and Usmani, {A. M.}",

year = "1985",

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journal = "Polymer Bulletin",

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T1 - Suspension graft polymerization by chain transfer

AU - Maadhah, A. G.

AU - Amin, M. B.

AU - Usmani, A. M.

PY - 1985/11

Y1 - 1985/11

N2 - Poly(vinyl oxazoline ester) and poly(stearyl methacrylate) were found to be good alien polymers for grafting of methyl methacrylate by suspension polymerization whereas poly(tridecyl methacrylate) was not a good backbone. Azobisisobutyronitrile was found to be an inefficient grafting initiator where azocumene that produces highly resonance and hyperconjugated stabilized dimethyl phenyl methyl radical was a superior initiator to benzoyl peroxide for grafting. Poly(stearyl methacrylate) was found to be a suitable polymeric stabilizer for nonaqueous suspension polymerizations.

AB - Poly(vinyl oxazoline ester) and poly(stearyl methacrylate) were found to be good alien polymers for grafting of methyl methacrylate by suspension polymerization whereas poly(tridecyl methacrylate) was not a good backbone. Azobisisobutyronitrile was found to be an inefficient grafting initiator where azocumene that produces highly resonance and hyperconjugated stabilized dimethyl phenyl methyl radical was a superior initiator to benzoyl peroxide for grafting. Poly(stearyl methacrylate) was found to be a suitable polymeric stabilizer for nonaqueous suspension polymerizations.

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U2 - 10.1007/BF00263459

DO - 10.1007/BF00263459

M3 - Article

AN - SCOPUS:0022151688

SN - 0170-0839

VL - 14

SP - 433

EP - 438

JO - Polymer Bulletin

JF - Polymer Bulletin

IS - 5

ER -

Suspension graft polymerization by chain transfer

Abstract

ASJC Scopus subject areas

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