Superior lithium-ion storage performance of hierarchical tin disulfide and carbon nanotube-carbon cloth composites

Tin-based composites are promising anode materials for high-performance lithium-ion batteries (LIBs); however, insufficient conductivity, as well as fatal volume expansion during cycling lead to poor electrochemical reversibility and cycling stability. In this work, we demonstrate the lithium-ion storage behaviors of SnS₂ anode material deposited on different electrode supports. The SnS₂ grown on 3D hierarchical carbon nanotube-carbon cloth composites (SnS₂-CNT-CC) shows superior capacity retention and cycle stability, compared to that on planar Mo sheets and carbon cloth. The specific capacity of SnS₂ on Mo, CC, and CNT-CC is around 240, 840, and 1250 g⁻¹, respectively. The SnS₂-CNT-CC electrode outperforms in the cyclic performance and rate capability compared to other electrode configurations due to the multi-electron pathway and high surface area derived from 3D hierarchical CNT-CC electrode support. Furthermore, a significant decrease in the charge transfer resistance is observed by utilizing 3D hierarchical CNT-CC electrode support. The use of 3D hierarchical structures as electrode support could be the best alternative to enhance the electrochemical performances for the next generation LIBs.