31P CPMAS NMR studies of some mono- and di-nuclear complexes of copper (I) iodide and phosphines

Zaki S. Seddigi; Mohamed I.M. Wazeer

³¹P CPMAS NMR studies of some mono- and di-nuclear complexes of copper (I) iodide and phosphines

Zaki S. Seddigi
, Mohamed I.M. Wazeer

King Fahd University of Petroleum & Minerals

Research output: Contribution to journal › Article › peer-review

Abstract

Phosphorus-31 CPMAS spectra are reported for some copper(I) iodide phosphine complexes showing monomeric and dimeric structures. The spectra show distorted quartets of unequal line spacing, indicating significant deviation from spherical symmetry at the copper nucleus. A larger quadrupole induced distortion is observed for the three-coordinate monomeric complexes than that for the four-coordinate dimeric complexes.

Original language	English
Pages (from-to)	65-69
Number of pages	5
Journal	Canadian Journal of Analytical Sciences and Spectroscopy
Volume	50
Issue number	2
State	Published - 2005

Keywords

Copper (I) iodide phosphine complex
Dimeric copper complex
Monomeric copper complex
P CPMAS NMR

ASJC Scopus subject areas

Analytical Chemistry
Atomic and Molecular Physics, and Optics
Spectroscopy

Cite this

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title = "31P CPMAS NMR studies of some mono- and di-nuclear complexes of copper (I) iodide and phosphines",

abstract = "Phosphorus-31 CPMAS spectra are reported for some copper(I) iodide phosphine complexes showing monomeric and dimeric structures. The spectra show distorted quartets of unequal line spacing, indicating significant deviation from spherical symmetry at the copper nucleus. A larger quadrupole induced distortion is observed for the three-coordinate monomeric complexes than that for the four-coordinate dimeric complexes.",

keywords = "Copper (I) iodide phosphine complex, Dimeric copper complex, Monomeric copper complex, P CPMAS NMR",

author = "Seddigi, \{Zaki S.\} and Wazeer, \{Mohamed I.M.\}",

year = "2005",

language = "English",

volume = "50",

pages = "65--69",

journal = "Canadian Journal of Analytical Sciences and Spectroscopy",

issn = "1205-6685",

publisher = "Spectroscopy Society of Canada",

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T1 - 31P CPMAS NMR studies of some mono- and di-nuclear complexes of copper (I) iodide and phosphines

AU - Seddigi, Zaki S.

AU - Wazeer, Mohamed I.M.

PY - 2005

Y1 - 2005

N2 - Phosphorus-31 CPMAS spectra are reported for some copper(I) iodide phosphine complexes showing monomeric and dimeric structures. The spectra show distorted quartets of unequal line spacing, indicating significant deviation from spherical symmetry at the copper nucleus. A larger quadrupole induced distortion is observed for the three-coordinate monomeric complexes than that for the four-coordinate dimeric complexes.

AB - Phosphorus-31 CPMAS spectra are reported for some copper(I) iodide phosphine complexes showing monomeric and dimeric structures. The spectra show distorted quartets of unequal line spacing, indicating significant deviation from spherical symmetry at the copper nucleus. A larger quadrupole induced distortion is observed for the three-coordinate monomeric complexes than that for the four-coordinate dimeric complexes.

KW - Copper (I) iodide phosphine complex

KW - Dimeric copper complex

KW - Monomeric copper complex

KW - P CPMAS NMR

UR - https://www.scopus.com/pages/publications/72749110558

M3 - Article

AN - SCOPUS:72749110558

SN - 1205-6685

VL - 50

SP - 65

EP - 69

JO - Canadian Journal of Analytical Sciences and Spectroscopy

JF - Canadian Journal of Analytical Sciences and Spectroscopy

IS - 2