13C n.m.r. studies of the interaction of HgII with methionine and selenamethionine in the acidic aqueous solution

Anvarhusein A. Isab

doi:10.1007/BF01043805

¹³C n.m.r. studies of the interaction of Hg^II with methionine and selenamethionine in the acidic aqueous solution

Anvarhusein A. Isab^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

The interactions of L-methionine (Met) and DL-selenamethionine (SeMet) with Hg²⁺ were studied using¹³C n.m.r. spectroscopy in aqueous acid. Hg²⁺ binds to the selenoether group of SeMet and the thioether group of Met exclusively. The selenoether group binds more strongly than thioether.

Original language	English
Pages (from-to)	235-236
Number of pages	2
Journal	Transition Metal Chemistry
Volume	14
Issue number	3
DOIs	https://doi.org/10.1007/BF01043805
State	Published - Jun 1989

ASJC Scopus subject areas

Inorganic Chemistry
Metals and Alloys
Materials Chemistry

Access to Document

10.1007/BF01043805

Cite this

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title = "13C n.m.r. studies of the interaction of HgII with methionine and selenamethionine in the acidic aqueous solution",

abstract = "The interactions of L-methionine (Met) and DL-selenamethionine (SeMet) with Hg2+ were studied using13C n.m.r. spectroscopy in aqueous acid. Hg2+ binds to the selenoether group of SeMet and the thioether group of Met exclusively. The selenoether group binds more strongly than thioether.",

author = "Isab, \{Anvarhusein A.\}",

year = "1989",

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journal = "Transition Metal Chemistry",

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T1 - 13C n.m.r. studies of the interaction of HgII with methionine and selenamethionine in the acidic aqueous solution

AU - Isab, Anvarhusein A.

PY - 1989/6

Y1 - 1989/6

N2 - The interactions of L-methionine (Met) and DL-selenamethionine (SeMet) with Hg2+ were studied using13C n.m.r. spectroscopy in aqueous acid. Hg2+ binds to the selenoether group of SeMet and the thioether group of Met exclusively. The selenoether group binds more strongly than thioether.

AB - The interactions of L-methionine (Met) and DL-selenamethionine (SeMet) with Hg2+ were studied using13C n.m.r. spectroscopy in aqueous acid. Hg2+ binds to the selenoether group of SeMet and the thioether group of Met exclusively. The selenoether group binds more strongly than thioether.

UR - https://www.scopus.com/pages/publications/2342484016

U2 - 10.1007/BF01043805

DO - 10.1007/BF01043805

M3 - Article

AN - SCOPUS:2342484016

SN - 0340-4285

VL - 14

SP - 235

EP - 236

JO - Transition Metal Chemistry

JF - Transition Metal Chemistry

IS - 3