Sub-nanometric Rh decorated magnetic nanoparticles as reusable catalysts for nitroarene reduction in water

M. Nasiruzzaman Shaikh; Aasif Helal; Abdul Nasar Kalanthoden; Basmah Najjar; Md Abdul Aziz; Hatim D. Mohamed

doi:10.1016/j.catcom.2018.09.002

Sub-nanometric Rh decorated magnetic nanoparticles as reusable catalysts for nitroarene reduction in water

M. Nasiruzzaman Shaikh^*
, Aasif Helal
, Abdul Nasar Kalanthoden
, Basmah Najjar
, Md Abdul Aziz
, Hatim D. Mohamed

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

Establishing a method of reduction of nitroarenes into corresponding amines in water without using flammable sodium borohydride or toxic hydrazine as hydrogen source, is quite challenging. Here, we show for the first time the propensity of sub-nanometric rhodium nanoparticles (< 1 nm) supported on ultra-small magnetic nanoparticles (8–10 nm), as reusable catalyst for the nitroarene reduction in aqueous medium using tetrahydroxydiboron (THDB) as reductant.

Original language	English
Pages (from-to)	134-138
Number of pages	5
Journal	Catalysis Communications
Volume	119
DOIs	https://doi.org/10.1016/j.catcom.2018.09.002
State	Published - 10 Jan 2019

Bibliographical note

Publisher Copyright:
© 2018 Elsevier B.V.

Keywords

Heterogeneous catalysis
Magnetic nanoparticles
Nitrophenol reduction
Rhodium

ASJC Scopus subject areas

Catalysis
General Chemistry
Process Chemistry and Technology

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10.1016/j.catcom.2018.09.002

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title = "Sub-nanometric Rh decorated magnetic nanoparticles as reusable catalysts for nitroarene reduction in water",

abstract = "Establishing a method of reduction of nitroarenes into corresponding amines in water without using flammable sodium borohydride or toxic hydrazine as hydrogen source, is quite challenging. Here, we show for the first time the propensity of sub-nanometric rhodium nanoparticles (< 1 nm) supported on ultra-small magnetic nanoparticles (8–10 nm), as reusable catalyst for the nitroarene reduction in aqueous medium using tetrahydroxydiboron (THDB) as reductant.",

keywords = "Heterogeneous catalysis, Magnetic nanoparticles, Nitrophenol reduction, Rhodium",

author = "Shaikh, \{M. Nasiruzzaman\} and Aasif Helal and Kalanthoden, \{Abdul Nasar\} and Basmah Najjar and \{Abdul Aziz\}, Md and Mohamed, \{Hatim D.\}",

note = "Publisher Copyright: {\textcopyright} 2018 Elsevier B.V.",

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doi = "10.1016/j.catcom.2018.09.002",

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T1 - Sub-nanometric Rh decorated magnetic nanoparticles as reusable catalysts for nitroarene reduction in water

AU - Shaikh, M. Nasiruzzaman

AU - Helal, Aasif

AU - Kalanthoden, Abdul Nasar

AU - Najjar, Basmah

AU - Abdul Aziz, Md

AU - Mohamed, Hatim D.

PY - 2019/1/10

Y1 - 2019/1/10

N2 - Establishing a method of reduction of nitroarenes into corresponding amines in water without using flammable sodium borohydride or toxic hydrazine as hydrogen source, is quite challenging. Here, we show for the first time the propensity of sub-nanometric rhodium nanoparticles (< 1 nm) supported on ultra-small magnetic nanoparticles (8–10 nm), as reusable catalyst for the nitroarene reduction in aqueous medium using tetrahydroxydiboron (THDB) as reductant.

AB - Establishing a method of reduction of nitroarenes into corresponding amines in water without using flammable sodium borohydride or toxic hydrazine as hydrogen source, is quite challenging. Here, we show for the first time the propensity of sub-nanometric rhodium nanoparticles (< 1 nm) supported on ultra-small magnetic nanoparticles (8–10 nm), as reusable catalyst for the nitroarene reduction in aqueous medium using tetrahydroxydiboron (THDB) as reductant.

KW - Heterogeneous catalysis

KW - Magnetic nanoparticles

KW - Nitrophenol reduction

KW - Rhodium

UR - https://www.scopus.com/pages/publications/85055967225

U2 - 10.1016/j.catcom.2018.09.002

DO - 10.1016/j.catcom.2018.09.002

M3 - Article

AN - SCOPUS:85055967225

SN - 1566-7367

VL - 119

SP - 134

EP - 138

JO - Catalysis Communications

JF - Catalysis Communications

ER -

Sub-nanometric Rh decorated magnetic nanoparticles as reusable catalysts for nitroarene reduction in water

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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