Abstract
Differential-pulse polarography has been used to study the simple and mixed-ligand complexes of cadmium-imidazole-citrate systems in solution. Using the graphical DeFord-Hume and Schaap-McMasters treatments the overall stability constants, βij, for the mixed-ligand complexes were found to be: log β11 = 5.89, log β12 = 6.38, log β21 = 7.38, log β22 = 7.08, log β31 = 8.38, and log β41 = 9.00. The equilibria between the various mixed-ligand species coexisting in the solution together with their stepwise stability constants are also given.
| Original language | English |
|---|---|
| Pages (from-to) | 1701-1707 |
| Number of pages | 7 |
| Journal | Polyhedron |
| Volume | 5 |
| Issue number | 11 |
| DOIs | |
| State | Published - 1986 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry