Structural characterization of tetrakis(1,3-diazinane-2-thione)cadmium(II) sulfate

R. Mahmood; S. G. Hussain; A. A. Isab; M. Fettouhi; A. Fazal; S. Ahmad

doi:10.1134/S0022476615030099

Structural characterization of tetrakis(1,3-diazinane-2-thione)cadmium(II) sulfate

R. Mahmood, S. G. Hussain^*, A. A. Isab, M. Fettouhi, A. Fazal, S. Ahmad

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

A cadmium(II) complex tetrakis(1,3-diazinane-2-thione)cadmium(II) sulfate [Cd(Diaz)₄]SO₄ (1) is prepared and its crystal structure is determined by X-ray crystallography. The crystal structure of 1 consists of [Cd(Diaz)₄]²⁺ and SO₄^2- ions. In the complex ion, the central cadmium atom is coordinated by four Diaz molecules through sulfur atoms adopting a distorted tetrahedral geometry. The molecular structure is stabilized by N-H...O and N-H...S hydrogen bonding interactions. The complex is also characterized by IR and NMR spectroscopy and the spectroscopic data are discussed in terms of the nature of bonding.

Original language	English
Pages (from-to)	463-467
Number of pages	5
Journal	Journal of Structural Chemistry
Volume	56
Issue number	3
DOIs	https://doi.org/10.1134/S0022476615030099
State	Published - 29 Jun 2015

Bibliographical note

Publisher Copyright:
© 2015 Pleiades Publishing, Ltd.

Keywords

1,3-diazinane-2-thione
cadmium sulfate
crystal structure

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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title = "Structural characterization of tetrakis(1,3-diazinane-2-thione)cadmium(II) sulfate",

abstract = "A cadmium(II) complex tetrakis(1,3-diazinane-2-thione)cadmium(II) sulfate [Cd(Diaz)4]SO4 (1) is prepared and its crystal structure is determined by X-ray crystallography. The crystal structure of 1 consists of [Cd(Diaz)4]2+ and SO42- ions. In the complex ion, the central cadmium atom is coordinated by four Diaz molecules through sulfur atoms adopting a distorted tetrahedral geometry. The molecular structure is stabilized by N-H...O and N-H...S hydrogen bonding interactions. The complex is also characterized by IR and NMR spectroscopy and the spectroscopic data are discussed in terms of the nature of bonding.",

keywords = "1,3-diazinane-2-thione, cadmium sulfate, crystal structure",

author = "R. Mahmood and Hussain, {S. G.} and Isab, {A. A.} and M. Fettouhi and A. Fazal and S. Ahmad",

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year = "2015",

month = jun,

day = "29",

doi = "10.1134/S0022476615030099",

language = "English",

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T1 - Structural characterization of tetrakis(1,3-diazinane-2-thione)cadmium(II) sulfate

AU - Mahmood, R.

AU - Hussain, S. G.

AU - Isab, A. A.

AU - Fettouhi, M.

AU - Fazal, A.

AU - Ahmad, S.

PY - 2015/6/29

Y1 - 2015/6/29

N2 - A cadmium(II) complex tetrakis(1,3-diazinane-2-thione)cadmium(II) sulfate [Cd(Diaz)4]SO4 (1) is prepared and its crystal structure is determined by X-ray crystallography. The crystal structure of 1 consists of [Cd(Diaz)4]2+ and SO42- ions. In the complex ion, the central cadmium atom is coordinated by four Diaz molecules through sulfur atoms adopting a distorted tetrahedral geometry. The molecular structure is stabilized by N-H...O and N-H...S hydrogen bonding interactions. The complex is also characterized by IR and NMR spectroscopy and the spectroscopic data are discussed in terms of the nature of bonding.

AB - A cadmium(II) complex tetrakis(1,3-diazinane-2-thione)cadmium(II) sulfate [Cd(Diaz)4]SO4 (1) is prepared and its crystal structure is determined by X-ray crystallography. The crystal structure of 1 consists of [Cd(Diaz)4]2+ and SO42- ions. In the complex ion, the central cadmium atom is coordinated by four Diaz molecules through sulfur atoms adopting a distorted tetrahedral geometry. The molecular structure is stabilized by N-H...O and N-H...S hydrogen bonding interactions. The complex is also characterized by IR and NMR spectroscopy and the spectroscopic data are discussed in terms of the nature of bonding.

KW - 1,3-diazinane-2-thione

KW - cadmium sulfate

KW - crystal structure

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DO - 10.1134/S0022476615030099

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VL - 56

SP - 463

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JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

IS - 3

ER -

Structural characterization of tetrakis(1,3-diazinane-2-thione)cadmium(II) sulfate

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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