Structural characterization of dicyanidobis-(N,N′-dimethylthiourea- κS)cadmium(II)

M. R. Malik; T. Rüffer; H. Lang; A. A. Isab; S. Ali; S. Ahmad; H. Stoeckli-Evans

doi:10.1134/S0022476613040240

Structural characterization of dicyanidobis-(N,N′-dimethylthiourea- κS)cadmium(II)

M. R. Malik, T. Rüffer, H. Lang, A. A. Isab, S. Ali, S. Ahmad, H. Stoeckli-Evans

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

A cadmium(II) complex dicyanidobis(N,N′-dimethylthiourea-S) cadmium(II) [Cd(Dmtu)₂(CN)₂] (1) is prepared and its structure in the solid state is determined by single crystal X-ray structural analysis. The cadmium(II) ion is four-coordinate having a distorted tetrahedral geometry composed of two cyanide C atoms and two thione S atoms of N,N′-dimethylthiourea (dmtu). The molecular structure is stabilized by intermolecular N-H.N(CN) hydrogen bonding interactions that lead to a 3D network structure. The complex was also characterized by IR and NMR spectroscopy.

Original language	English
Pages (from-to)	810-814
Number of pages	5
Journal	Journal of Structural Chemistry
Volume	54
Issue number	4
DOIs	https://doi.org/10.1134/S0022476613040240
State	Published - 2013

Keywords

N,N′-dimethylthiourea
cadmium cyanide
crystal structure

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1134/S0022476613040240

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@article{176e413ff85848b9ad44dcf4f02bfd30,

title = "Structural characterization of dicyanidobis-(N,N′-dimethylthiourea- κS)cadmium(II)",

abstract = "A cadmium(II) complex dicyanidobis(N,N′-dimethylthiourea-S) cadmium(II) [Cd(Dmtu)2(CN)2] (1) is prepared and its structure in the solid state is determined by single crystal X-ray structural analysis. The cadmium(II) ion is four-coordinate having a distorted tetrahedral geometry composed of two cyanide C atoms and two thione S atoms of N,N′-dimethylthiourea (dmtu). The molecular structure is stabilized by intermolecular N-H.N(CN) hydrogen bonding interactions that lead to a 3D network structure. The complex was also characterized by IR and NMR spectroscopy.",

keywords = "N,N′-dimethylthiourea, cadmium cyanide, crystal structure",

author = "Malik, \{M. R.\} and T. R{\"u}ffer and H. Lang and Isab, \{A. A.\} and S. Ali and S. Ahmad and H. Stoeckli-Evans",

year = "2013",

doi = "10.1134/S0022476613040240",

language = "English",

volume = "54",

pages = "810--814",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

number = "4",

}

TY - JOUR

T1 - Structural characterization of dicyanidobis-(N,N′-dimethylthiourea- κS)cadmium(II)

AU - Malik, M. R.

AU - Rüffer, T.

AU - Lang, H.

AU - Isab, A. A.

AU - Ali, S.

AU - Ahmad, S.

AU - Stoeckli-Evans, H.

PY - 2013

Y1 - 2013

N2 - A cadmium(II) complex dicyanidobis(N,N′-dimethylthiourea-S) cadmium(II) [Cd(Dmtu)2(CN)2] (1) is prepared and its structure in the solid state is determined by single crystal X-ray structural analysis. The cadmium(II) ion is four-coordinate having a distorted tetrahedral geometry composed of two cyanide C atoms and two thione S atoms of N,N′-dimethylthiourea (dmtu). The molecular structure is stabilized by intermolecular N-H.N(CN) hydrogen bonding interactions that lead to a 3D network structure. The complex was also characterized by IR and NMR spectroscopy.

AB - A cadmium(II) complex dicyanidobis(N,N′-dimethylthiourea-S) cadmium(II) [Cd(Dmtu)2(CN)2] (1) is prepared and its structure in the solid state is determined by single crystal X-ray structural analysis. The cadmium(II) ion is four-coordinate having a distorted tetrahedral geometry composed of two cyanide C atoms and two thione S atoms of N,N′-dimethylthiourea (dmtu). The molecular structure is stabilized by intermolecular N-H.N(CN) hydrogen bonding interactions that lead to a 3D network structure. The complex was also characterized by IR and NMR spectroscopy.

KW - N,N′-dimethylthiourea

KW - cadmium cyanide

KW - crystal structure

UR - https://www.scopus.com/pages/publications/84885436067

U2 - 10.1134/S0022476613040240

DO - 10.1134/S0022476613040240

M3 - Article

AN - SCOPUS:84885436067

SN - 0022-4766

VL - 54

SP - 810

EP - 814

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

IS - 4

ER -

Structural characterization of dicyanidobis-(N,N′-dimethylthiourea- κS)cadmium(II)

Abstract

Keywords

ASJC Scopus subject areas

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