Structural characterization of dichloridobis(N,N′-dimethylthiourea-S)cadmium(II)

M. R. Malik; S. Ali; M. Fettouhi; A. A. Isab; S. Ahmad

doi:10.1007/s10947-010-0150-8

Structural characterization of dichloridobis(N,N′-dimethylthiourea-S)cadmium(II)

M. R. Malik, S. Ali^*, M. Fettouhi, A. A. Isab, S. Ahmad

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

A cadmium(II) complex, dichloridobis(N,N′-dimethylthiourea-S)cadmium(II), [Cd(Dmtu)₂Cl₂] (1), was prepared and its structure was determined by X-ray crystal structure analysis. The cadmium(II) ion is four-coordinated and the complex has a distorted tetrahedral geometry. The bond angles are in the range of 108. 18(3)-110.45(2)°. The metal ion is bonded to two chloride ions and two dimethylthiourea molecules through the sulfur atoms. The crystal structure shows both intra- and intermolecular hydrogen bonds. The new complex was also characterized by IR and NMR spectroscopy and the spectroscopic data are discussed in terms of the nature of bonding.

Original language	English
Pages (from-to)	976-979
Number of pages	4
Journal	Journal of Structural Chemistry
Volume	51
Issue number	5
DOIs	https://doi.org/10.1007/s10947-010-0150-8
State	Published - Oct 2010

Keywords

Cadmium chloride
N,N'-dimethylthiourea
crystal structure

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1007/s10947-010-0150-8

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title = "Structural characterization of dichloridobis(N,N′-dimethylthiourea-S)cadmium(II)",

abstract = "A cadmium(II) complex, dichloridobis(N,N′-dimethylthiourea-S)cadmium(II), [Cd(Dmtu)2Cl2] (1), was prepared and its structure was determined by X-ray crystal structure analysis. The cadmium(II) ion is four-coordinated and the complex has a distorted tetrahedral geometry. The bond angles are in the range of 108. 18(3)-110.45(2)°. The metal ion is bonded to two chloride ions and two dimethylthiourea molecules through the sulfur atoms. The crystal structure shows both intra- and intermolecular hydrogen bonds. The new complex was also characterized by IR and NMR spectroscopy and the spectroscopic data are discussed in terms of the nature of bonding.",

keywords = "Cadmium chloride, N,N'-dimethylthiourea, crystal structure",

author = "Malik, \{M. R.\} and S. Ali and M. Fettouhi and Isab, \{A. A.\} and S. Ahmad",

year = "2010",

month = oct,

doi = "10.1007/s10947-010-0150-8",

language = "English",

volume = "51",

pages = "976--979",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

number = "5",

}

TY - JOUR

T1 - Structural characterization of dichloridobis(N,N′-dimethylthiourea-S)cadmium(II)

AU - Malik, M. R.

AU - Ali, S.

AU - Fettouhi, M.

AU - Isab, A. A.

AU - Ahmad, S.

PY - 2010/10

Y1 - 2010/10

N2 - A cadmium(II) complex, dichloridobis(N,N′-dimethylthiourea-S)cadmium(II), [Cd(Dmtu)2Cl2] (1), was prepared and its structure was determined by X-ray crystal structure analysis. The cadmium(II) ion is four-coordinated and the complex has a distorted tetrahedral geometry. The bond angles are in the range of 108. 18(3)-110.45(2)°. The metal ion is bonded to two chloride ions and two dimethylthiourea molecules through the sulfur atoms. The crystal structure shows both intra- and intermolecular hydrogen bonds. The new complex was also characterized by IR and NMR spectroscopy and the spectroscopic data are discussed in terms of the nature of bonding.

AB - A cadmium(II) complex, dichloridobis(N,N′-dimethylthiourea-S)cadmium(II), [Cd(Dmtu)2Cl2] (1), was prepared and its structure was determined by X-ray crystal structure analysis. The cadmium(II) ion is four-coordinated and the complex has a distorted tetrahedral geometry. The bond angles are in the range of 108. 18(3)-110.45(2)°. The metal ion is bonded to two chloride ions and two dimethylthiourea molecules through the sulfur atoms. The crystal structure shows both intra- and intermolecular hydrogen bonds. The new complex was also characterized by IR and NMR spectroscopy and the spectroscopic data are discussed in terms of the nature of bonding.

KW - Cadmium chloride

KW - N,N'-dimethylthiourea

KW - crystal structure

UR - https://www.scopus.com/pages/publications/78649472999

U2 - 10.1007/s10947-010-0150-8

DO - 10.1007/s10947-010-0150-8

M3 - Article

AN - SCOPUS:78649472999

SN - 0022-4766

VL - 51

SP - 976

EP - 979

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

IS - 5

ER -

Structural characterization of dichloridobis(N,N′-dimethylthiourea-S)cadmium(II)

Abstract

Keywords

ASJC Scopus subject areas

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