Stacking of double bonds for photochemical [2+2] cycloaddition reactions in the solid state

Mangayarkarasi Nagarathinam; Abdul Malik Puthan Peedikakkal; Jagadese J. Vittal

doi:10.1039/b809136f

Stacking of double bonds for photochemical [2+2] cycloaddition reactions in the solid state

Mangayarkarasi Nagarathinam
, Abdul Malik Puthan Peedikakkal
, Jagadese J. Vittal

Research output: Contribution to journal › Review article › peer-review

235 Scopus citations

Abstract

trans-1,2-Bis(4-pyridyl)ethylene (bpe), containing a C=C bond, has been extensively studied for solid-state photochemical [2+2] cycloaddition reactions, in discrete molecular and metal complexes, hydrogen bonded and coordination polymeric structures. The challenges in orienting a pair or more of bpe molecules in the solid-state using crystal engineering principles, and their photochemical behaviour and implications, based on Schmidt's postulates, are discussed.

Original language	English
Pages (from-to)	5277-5288
Number of pages	12
Journal	Chemical Communications
Issue number	42
DOIs	https://doi.org/10.1039/b809136f
State	Published - 2008
Externally published	Yes

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/b809136f

Cite this

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title = "Stacking of double bonds for photochemical [2+2] cycloaddition reactions in the solid state",

abstract = "trans-1,2-Bis(4-pyridyl)ethylene (bpe), containing a C=C bond, has been extensively studied for solid-state photochemical [2+2] cycloaddition reactions, in discrete molecular and metal complexes, hydrogen bonded and coordination polymeric structures. The challenges in orienting a pair or more of bpe molecules in the solid-state using crystal engineering principles, and their photochemical behaviour and implications, based on Schmidt's postulates, are discussed.",

author = "Mangayarkarasi Nagarathinam and Peedikakkal, \{Abdul Malik Puthan\} and Vittal, \{Jagadese J.\}",

year = "2008",

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journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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AU - Nagarathinam, Mangayarkarasi

AU - Peedikakkal, Abdul Malik Puthan

AU - Vittal, Jagadese J.

PY - 2008

Y1 - 2008

N2 - trans-1,2-Bis(4-pyridyl)ethylene (bpe), containing a C=C bond, has been extensively studied for solid-state photochemical [2+2] cycloaddition reactions, in discrete molecular and metal complexes, hydrogen bonded and coordination polymeric structures. The challenges in orienting a pair or more of bpe molecules in the solid-state using crystal engineering principles, and their photochemical behaviour and implications, based on Schmidt's postulates, are discussed.

AB - trans-1,2-Bis(4-pyridyl)ethylene (bpe), containing a C=C bond, has been extensively studied for solid-state photochemical [2+2] cycloaddition reactions, in discrete molecular and metal complexes, hydrogen bonded and coordination polymeric structures. The challenges in orienting a pair or more of bpe molecules in the solid-state using crystal engineering principles, and their photochemical behaviour and implications, based on Schmidt's postulates, are discussed.

UR - https://www.scopus.com/pages/publications/55349092017

U2 - 10.1039/b809136f

DO - 10.1039/b809136f

M3 - Review article

AN - SCOPUS:55349092017

SN - 1359-7345

SP - 5277

EP - 5288

JO - Chemical Communications

JF - Chemical Communications

IS - 42

ER -

Stacking of double bonds for photochemical [2+2] cycloaddition reactions in the solid state

Abstract

ASJC Scopus subject areas

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