SPE coupled to AAS trace determination of Cd(II) and Zn(II) in food samples using amine functionalized GMA-MMA-EGDMA terpolymer: Isotherm and kinetic studies

Aminul Islam; Suneel Kumar; Noushi Zaidi; Hilal Ahmad

doi:10.1016/j.foodchem.2016.07.033

SPE coupled to AAS trace determination of Cd(II) and Zn(II) in food samples using amine functionalized GMA-MMA-EGDMA terpolymer: Isotherm and kinetic studies

Aminul Islam^*, Suneel Kumar, Noushi Zaidi, Hilal Ahmad

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

An ethylenediamine functionalized glycidyl methacrylate (GMA) based terpolymeric chelating resin was synthesized for the separation and preconcentration of Cd(II) and Zn(II) by SPE from bread, rice and fruit juice prior to FAAS determination. The resin was characterized by FT-IR, TGA/DTA, SEM, BET analysis and EDS. Synthesized resin shows a good capacity of 53.96 mg g⁻¹ for Cd(II) and 24.19 mg g⁻¹ for Zn(II) at pH 8.0. Five isotherm equilibrium models were studied to explain the sorption phenomenon out of which Langmuir, Dubinin–Radushkevich, Scatchard and Temkin models were found to be the best fitted. The limit of detection (LOD) and limit of quantification (LOQ) were observed to be 1.5 and 5.1 μg L⁻¹ for Cd and 1.2 and 4.1 μg L⁻¹ for Zn. The reliability of the method was investigated by the analysis of SRM and the recovery of analytes from various spiked food samples.

Original language	English
Pages (from-to)	775-783
Number of pages	9
Journal	Food Chemistry
Volume	213
DOIs	https://doi.org/10.1016/j.foodchem.2016.07.033
State	Published - 15 Dec 2016
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2016

Keywords

FAAS
Terpolymer
food analysis
solid phase extraction

ASJC Scopus subject areas

Analytical Chemistry
Food Science

Access to Document

10.1016/j.foodchem.2016.07.033

Cite this

@article{5c9bc770b396497590465fa14cd974a6,

title = "SPE coupled to AAS trace determination of Cd(II) and Zn(II) in food samples using amine functionalized GMA-MMA-EGDMA terpolymer: Isotherm and kinetic studies",

abstract = "An ethylenediamine functionalized glycidyl methacrylate (GMA) based terpolymeric chelating resin was synthesized for the separation and preconcentration of Cd(II) and Zn(II) by SPE from bread, rice and fruit juice prior to FAAS determination. The resin was characterized by FT-IR, TGA/DTA, SEM, BET analysis and EDS. Synthesized resin shows a good capacity of 53.96 mg g−1 for Cd(II) and 24.19 mg g−1 for Zn(II) at pH 8.0. Five isotherm equilibrium models were studied to explain the sorption phenomenon out of which Langmuir, Dubinin–Radushkevich, Scatchard and Temkin models were found to be the best fitted. The limit of detection (LOD) and limit of quantification (LOQ) were observed to be 1.5 and 5.1 μg L−1 for Cd and 1.2 and 4.1 μg L−1 for Zn. The reliability of the method was investigated by the analysis of SRM and the recovery of analytes from various spiked food samples.",

keywords = "FAAS, Terpolymer, food analysis, solid phase extraction",

author = "Aminul Islam and Suneel Kumar and Noushi Zaidi and Hilal Ahmad",

note = "Publisher Copyright: {\textcopyright} 2016",

year = "2016",

month = dec,

day = "15",

doi = "10.1016/j.foodchem.2016.07.033",

language = "English",

volume = "213",

pages = "775--783",

journal = "Food Chemistry",

issn = "0308-8146",

publisher = "Elsevier Ltd.",

}

TY - JOUR

T1 - SPE coupled to AAS trace determination of Cd(II) and Zn(II) in food samples using amine functionalized GMA-MMA-EGDMA terpolymer

T2 - Isotherm and kinetic studies

AU - Islam, Aminul

AU - Kumar, Suneel

AU - Zaidi, Noushi

AU - Ahmad, Hilal

PY - 2016/12/15

Y1 - 2016/12/15

N2 - An ethylenediamine functionalized glycidyl methacrylate (GMA) based terpolymeric chelating resin was synthesized for the separation and preconcentration of Cd(II) and Zn(II) by SPE from bread, rice and fruit juice prior to FAAS determination. The resin was characterized by FT-IR, TGA/DTA, SEM, BET analysis and EDS. Synthesized resin shows a good capacity of 53.96 mg g−1 for Cd(II) and 24.19 mg g−1 for Zn(II) at pH 8.0. Five isotherm equilibrium models were studied to explain the sorption phenomenon out of which Langmuir, Dubinin–Radushkevich, Scatchard and Temkin models were found to be the best fitted. The limit of detection (LOD) and limit of quantification (LOQ) were observed to be 1.5 and 5.1 μg L−1 for Cd and 1.2 and 4.1 μg L−1 for Zn. The reliability of the method was investigated by the analysis of SRM and the recovery of analytes from various spiked food samples.

AB - An ethylenediamine functionalized glycidyl methacrylate (GMA) based terpolymeric chelating resin was synthesized for the separation and preconcentration of Cd(II) and Zn(II) by SPE from bread, rice and fruit juice prior to FAAS determination. The resin was characterized by FT-IR, TGA/DTA, SEM, BET analysis and EDS. Synthesized resin shows a good capacity of 53.96 mg g−1 for Cd(II) and 24.19 mg g−1 for Zn(II) at pH 8.0. Five isotherm equilibrium models were studied to explain the sorption phenomenon out of which Langmuir, Dubinin–Radushkevich, Scatchard and Temkin models were found to be the best fitted. The limit of detection (LOD) and limit of quantification (LOQ) were observed to be 1.5 and 5.1 μg L−1 for Cd and 1.2 and 4.1 μg L−1 for Zn. The reliability of the method was investigated by the analysis of SRM and the recovery of analytes from various spiked food samples.

KW - FAAS

KW - Terpolymer

KW - food analysis

KW - solid phase extraction

UR - https://www.scopus.com/pages/publications/84978828755

U2 - 10.1016/j.foodchem.2016.07.033

DO - 10.1016/j.foodchem.2016.07.033

M3 - Article

C2 - 27451247

AN - SCOPUS:84978828755

SN - 0308-8146

VL - 213

SP - 775

EP - 783

JO - Food Chemistry

JF - Food Chemistry

ER -

SPE coupled to AAS trace determination of Cd(II) and Zn(II) in food samples using amine functionalized GMA-MMA-EGDMA terpolymer: Isotherm and kinetic studies

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

Access to Document

Fingerprint

Cite this