Solid-state photochemical behavior of a triple-stranded ladder coordination polymer

Abdul Malik Puthan Peedikakkal; Jagadese J. Vittal

doi:10.1021/ic902158w

Solid-state photochemical behavior of a triple-stranded ladder coordination polymer

Abdul Malik Puthan Peedikakkal, Jagadese J. Vittal

Research output: Contribution to journal › Article › peer-review

64 Scopus citations

Abstract

A triple-stranded ladder coordination polymer, [Pb₃(bpe) ₃(O₂CCF₃)₄(O₂CCH ₃)₂] [bpe = trans-1,2-bis(4-pyridyl)ethene] undergoes a photochemical [2 + 2] cycloaddition reaction In the solid state to furnish 100% rctt-tetrakls(4-pyridyl)cyclobutane (rctt-tpcb) In two steps via cooperative molecular movements of the partially dimerized products formed initially.

Original language	English
Pages (from-to)	10-12
Number of pages	3
Journal	Inorganic Chemistry
Volume	49
Issue number	1
DOIs	https://doi.org/10.1021/ic902158w
State	Published - 4 Jan 2010
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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abstract = "A triple-stranded ladder coordination polymer, [Pb3(bpe) 3(O2CCF3)4(O2CCH 3)2] [bpe = trans-1,2-bis(4-pyridyl)ethene] undergoes a photochemical [2 + 2] cycloaddition reaction In the solid state to furnish 100% rctt-tetrakls(4-pyridyl)cyclobutane (rctt-tpcb) In two steps via cooperative molecular movements of the partially dimerized products formed initially.",

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N2 - A triple-stranded ladder coordination polymer, [Pb3(bpe) 3(O2CCF3)4(O2CCH 3)2] [bpe = trans-1,2-bis(4-pyridyl)ethene] undergoes a photochemical [2 + 2] cycloaddition reaction In the solid state to furnish 100% rctt-tetrakls(4-pyridyl)cyclobutane (rctt-tpcb) In two steps via cooperative molecular movements of the partially dimerized products formed initially.

AB - A triple-stranded ladder coordination polymer, [Pb3(bpe) 3(O2CCF3)4(O2CCH 3)2] [bpe = trans-1,2-bis(4-pyridyl)ethene] undergoes a photochemical [2 + 2] cycloaddition reaction In the solid state to furnish 100% rctt-tetrakls(4-pyridyl)cyclobutane (rctt-tpcb) In two steps via cooperative molecular movements of the partially dimerized products formed initially.

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Solid-state photochemical behavior of a triple-stranded ladder coordination polymer

Abstract

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