Solid state and solution NMR, X-ray and antimicrobial studies of 1:1 and 2:1 complexes of silver(I) cyanide with alkanediamine ligands

Anvarhusein A. Isab; Mohamed I.M. Wazeer; Mohammed Fettouhi; Bassem A. Al-Maythalony; Abdul Rahman Al-Arfaj; Norah O. Al-Zamil

doi:10.1016/j.ica.2007.04.036

Solid state and solution NMR, X-ray and antimicrobial studies of 1:1 and 2:1 complexes of silver(I) cyanide with alkanediamine ligands

Anvarhusein A. Isab^*
, Mohamed I.M. Wazeer
, Mohammed Fettouhi
, Bassem A. Al-Maythalony
, Abdul Rahman Al-Arfaj
, Norah O. Al-Zamil

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Several complexes of AgCN with alkanediamine ligands (where the ligands are ethylenediamine, propane-1,3-diamine, butane-1,4-diamine, N,N′-dimethyl-ethylenediamine, N,N′-di-iso-propyl-ethylenediamine, etc.) have been synthesized and structurally characterized. In these species, alkanediamine ligands act as chelating ligands. The X-ray structure of the complex cyano-(N,N′-di-iso-propyl-ethylenediamine)-silver(I) was determined. These complexes have been also characterized by IR, solution as well as solid-state NMR studies. There are two types of IR absorptions observed for mono and dinuclear complexes. For the mono nuclear complexes, a sharp CN band is observed between 2111 and 2131 cm^-1 range, whereas for binuclear complexes the bands are in the range 2136-2140 cm^-1. The effect of the size of the ligands as well as their substituents is discussed. The antimicrobial activity studies of AgCN and its complexes show that the former exhibits substantial antibacterial activities compared to its complexes.

Original language	English
Pages (from-to)	3719-3726
Number of pages	8
Journal	Inorganica Chimica Acta
Volume	360
Issue number	12
DOIs	https://doi.org/10.1016/j.ica.2007.04.036
State	Published - 1 Sep 2007

Bibliographical note

Funding Information:
This research was supported by the KFUPM Research Committee under Project No. SABIC 2006-08.

Keywords

AgCN-alkanediamine complexes
Antimicrobial activity
CPMAS NMR studies
X-ray crystal structure

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.ica.2007.04.036

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@article{beda24c751754d4da01d18df32cbc0ba,

title = "Solid state and solution NMR, X-ray and antimicrobial studies of 1:1 and 2:1 complexes of silver(I) cyanide with alkanediamine ligands",

abstract = "Several complexes of AgCN with alkanediamine ligands (where the ligands are ethylenediamine, propane-1,3-diamine, butane-1,4-diamine, N,N′-dimethyl-ethylenediamine, N,N′-di-iso-propyl-ethylenediamine, etc.) have been synthesized and structurally characterized. In these species, alkanediamine ligands act as chelating ligands. The X-ray structure of the complex cyano-(N,N′-di-iso-propyl-ethylenediamine)-silver(I) was determined. These complexes have been also characterized by IR, solution as well as solid-state NMR studies. There are two types of IR absorptions observed for mono and dinuclear complexes. For the mono nuclear complexes, a sharp CN band is observed between 2111 and 2131 cm-1 range, whereas for binuclear complexes the bands are in the range 2136-2140 cm-1. The effect of the size of the ligands as well as their substituents is discussed. The antimicrobial activity studies of AgCN and its complexes show that the former exhibits substantial antibacterial activities compared to its complexes.",

keywords = "AgCN-alkanediamine complexes, Antimicrobial activity, CPMAS NMR studies, X-ray crystal structure",

author = "Isab, \{Anvarhusein A.\} and Wazeer, \{Mohamed I.M.\} and Mohammed Fettouhi and Al-Maythalony, \{Bassem A.\} and Al-Arfaj, \{Abdul Rahman\} and Al-Zamil, \{Norah O.\}",

note = "Funding Information: This research was supported by the KFUPM Research Committee under Project No. SABIC 2006-08.",

year = "2007",

month = sep,

day = "1",

doi = "10.1016/j.ica.2007.04.036",

language = "English",

volume = "360",

pages = "3719--3726",

journal = "Inorganica Chimica Acta",

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publisher = "Elsevier BV",

number = "12",

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TY - JOUR

T1 - Solid state and solution NMR, X-ray and antimicrobial studies of 1:1 and 2:1 complexes of silver(I) cyanide with alkanediamine ligands

AU - Isab, Anvarhusein A.

AU - Wazeer, Mohamed I.M.

AU - Fettouhi, Mohammed

AU - Al-Maythalony, Bassem A.

AU - Al-Arfaj, Abdul Rahman

AU - Al-Zamil, Norah O.

N1 - Funding Information: This research was supported by the KFUPM Research Committee under Project No. SABIC 2006-08.

PY - 2007/9/1

Y1 - 2007/9/1

N2 - Several complexes of AgCN with alkanediamine ligands (where the ligands are ethylenediamine, propane-1,3-diamine, butane-1,4-diamine, N,N′-dimethyl-ethylenediamine, N,N′-di-iso-propyl-ethylenediamine, etc.) have been synthesized and structurally characterized. In these species, alkanediamine ligands act as chelating ligands. The X-ray structure of the complex cyano-(N,N′-di-iso-propyl-ethylenediamine)-silver(I) was determined. These complexes have been also characterized by IR, solution as well as solid-state NMR studies. There are two types of IR absorptions observed for mono and dinuclear complexes. For the mono nuclear complexes, a sharp CN band is observed between 2111 and 2131 cm-1 range, whereas for binuclear complexes the bands are in the range 2136-2140 cm-1. The effect of the size of the ligands as well as their substituents is discussed. The antimicrobial activity studies of AgCN and its complexes show that the former exhibits substantial antibacterial activities compared to its complexes.

AB - Several complexes of AgCN with alkanediamine ligands (where the ligands are ethylenediamine, propane-1,3-diamine, butane-1,4-diamine, N,N′-dimethyl-ethylenediamine, N,N′-di-iso-propyl-ethylenediamine, etc.) have been synthesized and structurally characterized. In these species, alkanediamine ligands act as chelating ligands. The X-ray structure of the complex cyano-(N,N′-di-iso-propyl-ethylenediamine)-silver(I) was determined. These complexes have been also characterized by IR, solution as well as solid-state NMR studies. There are two types of IR absorptions observed for mono and dinuclear complexes. For the mono nuclear complexes, a sharp CN band is observed between 2111 and 2131 cm-1 range, whereas for binuclear complexes the bands are in the range 2136-2140 cm-1. The effect of the size of the ligands as well as their substituents is discussed. The antimicrobial activity studies of AgCN and its complexes show that the former exhibits substantial antibacterial activities compared to its complexes.

KW - AgCN-alkanediamine complexes

KW - Antimicrobial activity

KW - CPMAS NMR studies

KW - X-ray crystal structure

UR - https://www.scopus.com/pages/publications/34547756363

U2 - 10.1016/j.ica.2007.04.036

DO - 10.1016/j.ica.2007.04.036

M3 - Article

AN - SCOPUS:34547756363

SN - 0020-1693

VL - 360

SP - 3719

EP - 3726

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 12

ER -

Solid state and solution NMR, X-ray and antimicrobial studies of 1:1 and 2:1 complexes of silver(I) cyanide with alkanediamine ligands

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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