Abstract
Reactions of imidazolidine-2-thione (Imt), 1,3-diazinane-2-thione (Diaz) and 1,3-diazipane-2-thione (Diap) with mercury(II) selenocyanate in acetonitrile resulted in formation of 2:1 complexes. Both solid state and solution NMR, confirm the exocyclic sulfur atom to be the donor in all cases. 199Hg shielding tensors and anisotropies were calculated from the solid-state NMR spectra. Based on the solid NMR data a distorted tetrahedral disposition of ligands around mercury is proposed.
| Original language | English |
|---|---|
| Pages (from-to) | 2649-2657 |
| Number of pages | 9 |
| Journal | Journal of Coordination Chemistry |
| Volume | 60 |
| Issue number | 24 |
| DOIs | |
| State | Published - Dec 2007 |
Bibliographical note
Funding Information:This research was supported by the KFUPM Research Committee under project numbers SABIC 2006-08.
Keywords
- CP MAS NMR studies
- Imidazolidine-2-thione
- Mercury(II) complexes
- Selenocyanate complexes
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Materials Chemistry
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