Solid poly-N-heterocyclic carbene catalyzed CO2 reduction with hydrosilanes

Siti Nurhanna Riduan; Jackie Y. Ying; Yugen Zhang

doi:10.1016/j.jcat.2015.09.009

Solid poly-N-heterocyclic carbene catalyzed CO₂ reduction with hydrosilanes

Siti Nurhanna Riduan
, Jackie Y. Ying^*
, Yugen Zhang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

54 Scopus citations

Abstract

The utility of solid poly-N-heterocyclic carbene (poly-NHC) materials as organocatalysts for carbon dioxide reduction was studied. These poly-NHC particles were demonstrated to be useful as heterogeneous organocatalysts for the reduction of carbon dioxide to methanol and for the formylation of N–H bonds with hydrosilanes as a hydride donor. These solid catalysts could potentially be useful in large-scale syntheses due to the ease of catalyst recycle and reuse, providing cost savings and environmental sustainability in the long run.

Original language	English
Pages (from-to)	46-51
Number of pages	6
Journal	Journal of Catalysis
Volume	343
DOIs	https://doi.org/10.1016/j.jcat.2015.09.009
State	Published - 1 Nov 2016
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2015 Elsevier Inc.

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 13 Climate Action

Keywords

Carbon dioxide transformation
Heterogeneous organocatalysis
Hydrosilylation
N-heterocyclic carbene

ASJC Scopus subject areas

Catalysis
Physical and Theoretical Chemistry

Access to Document

10.1016/j.jcat.2015.09.009

Cite this

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title = "Solid poly-N-heterocyclic carbene catalyzed CO2 reduction with hydrosilanes",

abstract = "The utility of solid poly-N-heterocyclic carbene (poly-NHC) materials as organocatalysts for carbon dioxide reduction was studied. These poly-NHC particles were demonstrated to be useful as heterogeneous organocatalysts for the reduction of carbon dioxide to methanol and for the formylation of N–H bonds with hydrosilanes as a hydride donor. These solid catalysts could potentially be useful in large-scale syntheses due to the ease of catalyst recycle and reuse, providing cost savings and environmental sustainability in the long run.",

keywords = "Carbon dioxide transformation, Heterogeneous organocatalysis, Hydrosilylation, N-heterocyclic carbene",

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doi = "10.1016/j.jcat.2015.09.009",

language = "English",

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AU - Riduan, Siti Nurhanna

AU - Ying, Jackie Y.

AU - Zhang, Yugen

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Y1 - 2016/11/1

N2 - The utility of solid poly-N-heterocyclic carbene (poly-NHC) materials as organocatalysts for carbon dioxide reduction was studied. These poly-NHC particles were demonstrated to be useful as heterogeneous organocatalysts for the reduction of carbon dioxide to methanol and for the formylation of N–H bonds with hydrosilanes as a hydride donor. These solid catalysts could potentially be useful in large-scale syntheses due to the ease of catalyst recycle and reuse, providing cost savings and environmental sustainability in the long run.

AB - The utility of solid poly-N-heterocyclic carbene (poly-NHC) materials as organocatalysts for carbon dioxide reduction was studied. These poly-NHC particles were demonstrated to be useful as heterogeneous organocatalysts for the reduction of carbon dioxide to methanol and for the formylation of N–H bonds with hydrosilanes as a hydride donor. These solid catalysts could potentially be useful in large-scale syntheses due to the ease of catalyst recycle and reuse, providing cost savings and environmental sustainability in the long run.

KW - Carbon dioxide transformation

KW - Heterogeneous organocatalysis

KW - Hydrosilylation

KW - N-heterocyclic carbene

UR - https://www.scopus.com/pages/publications/84951788111

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DO - 10.1016/j.jcat.2015.09.009

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