Sodium dodecyl benzene sulfonate as a sustainable inhibitor for zinc corrosion in 26% NH4Cl solution

Yujie Qiang; Shengtao Zhang; Lei Guo; Shenying Xu; Li Feng; Ime B. Obot; Shijin Chen

doi:10.1016/j.jclepro.2017.03.104

Sodium dodecyl benzene sulfonate as a sustainable inhibitor for zinc corrosion in 26% NH₄Cl solution

Yujie Qiang^*
, Shengtao Zhang
, Lei Guo
, Shenying Xu
, Li Feng
, Ime B. Obot
, Shijin Chen

^*Corresponding author for this work

Interdisciplinary Research Center for Advanced Materials

Research output: Contribution to journal › Article › peer-review

133 Scopus citations

Abstract

Sodium dodecyl benzene sulfonate (SDBS) was investigated as an eco-friendly inhibitor for zinc corrosion in 26% NH₄Cl solution using corrosion experiments and theoretical calculations. Gravimetric and electrochemical results reveal that SDBS is an anodic inhibitor with excellent inhibition efficiency, which is further confirmed by field emission scanning electron microscope (FE-SEM) and atomic force microscopy (AFM) observation. The inhibitory effect diminishes with positive shift of potential, exhibiting a desirable characteristic for battery application. Despite the inhibition efficiencies decrease as increasing temperature from 298 to 328 K, the compound still shows favorable inhibitive ability at each temperature. In addition, the adsorption of SDBS on zinc surface obeys Langmuir adsorption model. Quantum chemical calculations and molecular dynamic simulations were further performed to correlate the adsorption mechanism with the structure of SDBS molecule.

Original language	English
Pages (from-to)	17-25
Number of pages	9
Journal	Journal of Cleaner Production
Volume	152
DOIs	https://doi.org/10.1016/j.jclepro.2017.03.104
State	Published - 20 May 2017

Bibliographical note

Publisher Copyright:
© 2017 Elsevier Ltd

Keywords

Battery
Corrosion inhibitor
Electrochemistry
Quantum chemical calculation
Zinc

ASJC Scopus subject areas

Renewable Energy, Sustainability and the Environment
General Environmental Science
Strategy and Management
Industrial and Manufacturing Engineering

Access to Document

10.1016/j.jclepro.2017.03.104

Cite this

@article{8c83d246ffc54dfda4a0fc984a8e1773,

title = "Sodium dodecyl benzene sulfonate as a sustainable inhibitor for zinc corrosion in 26\% NH4Cl solution",

abstract = "Sodium dodecyl benzene sulfonate (SDBS) was investigated as an eco-friendly inhibitor for zinc corrosion in 26\% NH4Cl solution using corrosion experiments and theoretical calculations. Gravimetric and electrochemical results reveal that SDBS is an anodic inhibitor with excellent inhibition efficiency, which is further confirmed by field emission scanning electron microscope (FE-SEM) and atomic force microscopy (AFM) observation. The inhibitory effect diminishes with positive shift of potential, exhibiting a desirable characteristic for battery application. Despite the inhibition efficiencies decrease as increasing temperature from 298 to 328 K, the compound still shows favorable inhibitive ability at each temperature. In addition, the adsorption of SDBS on zinc surface obeys Langmuir adsorption model. Quantum chemical calculations and molecular dynamic simulations were further performed to correlate the adsorption mechanism with the structure of SDBS molecule.",

keywords = "Battery, Corrosion inhibitor, Electrochemistry, Quantum chemical calculation, Zinc",

author = "Yujie Qiang and Shengtao Zhang and Lei Guo and Shenying Xu and Li Feng and Obot, \{Ime B.\} and Shijin Chen",

note = "Publisher Copyright: {\textcopyright} 2017 Elsevier Ltd",

year = "2017",

month = may,

day = "20",

doi = "10.1016/j.jclepro.2017.03.104",

language = "English",

volume = "152",

pages = "17--25",

journal = "Journal of Cleaner Production",

issn = "0959-6526",

publisher = "Elsevier Ltd.",

}

TY - JOUR

T1 - Sodium dodecyl benzene sulfonate as a sustainable inhibitor for zinc corrosion in 26% NH4Cl solution

AU - Qiang, Yujie

AU - Zhang, Shengtao

AU - Guo, Lei

AU - Xu, Shenying

AU - Feng, Li

AU - Obot, Ime B.

AU - Chen, Shijin

PY - 2017/5/20

Y1 - 2017/5/20

N2 - Sodium dodecyl benzene sulfonate (SDBS) was investigated as an eco-friendly inhibitor for zinc corrosion in 26% NH4Cl solution using corrosion experiments and theoretical calculations. Gravimetric and electrochemical results reveal that SDBS is an anodic inhibitor with excellent inhibition efficiency, which is further confirmed by field emission scanning electron microscope (FE-SEM) and atomic force microscopy (AFM) observation. The inhibitory effect diminishes with positive shift of potential, exhibiting a desirable characteristic for battery application. Despite the inhibition efficiencies decrease as increasing temperature from 298 to 328 K, the compound still shows favorable inhibitive ability at each temperature. In addition, the adsorption of SDBS on zinc surface obeys Langmuir adsorption model. Quantum chemical calculations and molecular dynamic simulations were further performed to correlate the adsorption mechanism with the structure of SDBS molecule.

AB - Sodium dodecyl benzene sulfonate (SDBS) was investigated as an eco-friendly inhibitor for zinc corrosion in 26% NH4Cl solution using corrosion experiments and theoretical calculations. Gravimetric and electrochemical results reveal that SDBS is an anodic inhibitor with excellent inhibition efficiency, which is further confirmed by field emission scanning electron microscope (FE-SEM) and atomic force microscopy (AFM) observation. The inhibitory effect diminishes with positive shift of potential, exhibiting a desirable characteristic for battery application. Despite the inhibition efficiencies decrease as increasing temperature from 298 to 328 K, the compound still shows favorable inhibitive ability at each temperature. In addition, the adsorption of SDBS on zinc surface obeys Langmuir adsorption model. Quantum chemical calculations and molecular dynamic simulations were further performed to correlate the adsorption mechanism with the structure of SDBS molecule.

KW - Battery

KW - Corrosion inhibitor

KW - Electrochemistry

KW - Quantum chemical calculation

KW - Zinc

UR - https://www.scopus.com/pages/publications/85017603742

U2 - 10.1016/j.jclepro.2017.03.104

DO - 10.1016/j.jclepro.2017.03.104

M3 - Article

AN - SCOPUS:85017603742

SN - 0959-6526

VL - 152

SP - 17

EP - 25

JO - Journal of Cleaner Production

JF - Journal of Cleaner Production

ER -