Silver(I) complexes of selenourea (13C and 15N labeled); characterization by 13C, 15N and 107Ag NMR

Saeed Ahmad; Anvarhusein A. Isab

doi:10.1016/S1387-7003(02)00405-7

Silver(I) complexes of selenourea (¹³C and ¹⁵N labeled); characterization by ¹³C, ¹⁵N and ¹⁰⁷Ag NMR

Saeed Ahmad
, Anvarhusein A. Isab^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Silver(I) complexes of selenourea (Seu), Ag(Seu)NO₃ and Ag(Seu)₂NO₃ have been prepared and characterized by elemental analysis, IR and NMR (¹H, ¹³C, ¹⁵N and ¹⁰⁷Ag) spectroscopy. An upfield shift in ¹³C NMR and downfield shifts in ¹H and ¹⁵N NMR for selenourea resonances are consistent with the selenium coordination to Ag(I). In ¹⁰⁷Ag NMR, the AgNO₃ signal is deshielded by more than 600 ppm on its coordination to selenourea.

Original language	English
Pages (from-to)	355-357
Number of pages	3
Journal	Inorganic Chemistry Communication
Volume	5
Issue number	5
DOIs	https://doi.org/10.1016/S1387-7003(02)00405-7
State	Published - 2002

Bibliographical note

Funding Information:
This research was supported by the KFUPM Research Committee under project no. CY/NMR-STUDIES/214.

Keywords

Complexes
NMR
Selenourea
Silver(I)

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S1387-7003(02)00405-7

Cite this

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title = "Silver(I) complexes of selenourea (13C and 15N labeled); characterization by 13C, 15N and 107Ag NMR",

abstract = "Silver(I) complexes of selenourea (Seu), Ag(Seu)NO3 and Ag(Seu)2NO3 have been prepared and characterized by elemental analysis, IR and NMR (1H, 13C, 15N and 107Ag) spectroscopy. An upfield shift in 13C NMR and downfield shifts in 1H and 15N NMR for selenourea resonances are consistent with the selenium coordination to Ag(I). In 107Ag NMR, the AgNO3 signal is deshielded by more than 600 ppm on its coordination to selenourea.",

keywords = "Complexes, NMR, Selenourea, Silver(I)",

author = "Saeed Ahmad and Isab, \{Anvarhusein A.\}",

note = "Funding Information: This research was supported by the KFUPM Research Committee under project no. CY/NMR-STUDIES/214.",

year = "2002",

doi = "10.1016/S1387-7003(02)00405-7",

language = "English",

volume = "5",

pages = "355--357",

journal = "Inorganic Chemistry Communication",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "5",

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TY - JOUR

T1 - Silver(I) complexes of selenourea (13C and 15N labeled); characterization by 13C, 15N and 107Ag NMR

AU - Ahmad, Saeed

AU - Isab, Anvarhusein A.

N1 - Funding Information: This research was supported by the KFUPM Research Committee under project no. CY/NMR-STUDIES/214.

PY - 2002

Y1 - 2002

N2 - Silver(I) complexes of selenourea (Seu), Ag(Seu)NO3 and Ag(Seu)2NO3 have been prepared and characterized by elemental analysis, IR and NMR (1H, 13C, 15N and 107Ag) spectroscopy. An upfield shift in 13C NMR and downfield shifts in 1H and 15N NMR for selenourea resonances are consistent with the selenium coordination to Ag(I). In 107Ag NMR, the AgNO3 signal is deshielded by more than 600 ppm on its coordination to selenourea.

AB - Silver(I) complexes of selenourea (Seu), Ag(Seu)NO3 and Ag(Seu)2NO3 have been prepared and characterized by elemental analysis, IR and NMR (1H, 13C, 15N and 107Ag) spectroscopy. An upfield shift in 13C NMR and downfield shifts in 1H and 15N NMR for selenourea resonances are consistent with the selenium coordination to Ag(I). In 107Ag NMR, the AgNO3 signal is deshielded by more than 600 ppm on its coordination to selenourea.

KW - Complexes

KW - NMR

KW - Selenourea

KW - Silver(I)

UR - https://www.scopus.com/pages/publications/0036249643

U2 - 10.1016/S1387-7003(02)00405-7

DO - 10.1016/S1387-7003(02)00405-7

M3 - Article

AN - SCOPUS:0036249643

SN - 1387-7003

VL - 5

SP - 355

EP - 357

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

IS - 5

ER -