Silicalite-1 as efficient catalyst for propylene production from olefins

Palani Arudra; M. Naseem Akhtar; Abdullah Aitani; Sulaiman Al-Khattaf; Hideshi Hattori

Silicalite-1 as efficient catalyst for propylene production from olefins

Palani Arudra
, M. Naseem Akhtar
, Abdullah Aitani
, Sulaiman Al-Khattaf
, Hideshi Hattori

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

Silicalite-1 was synthesized, and its catalytic activity was studied in the reaction of C₄-C₆ olefins. Silicalite-1 exhibited a higher yield of propylene as compared with H-ZSM-5 zeolites with a Si/Ab ratio of 23-280 due to minimization of hydrogen transfer reaction. It was proposed that the weakly acidic silanol groups on silicalite-1 acted as active sites for the formation of propylene at a high temperature. Strongly acidic OH groups bridged to Si and Al promote hydrogen transfer to consume olefins to form paraffins and aromatics. This is an abstract of a paper presented at the 25th Annual Saudi-Japan Symposium on Catalysts in Petroleum Refining and Petrochemicals 2015 (Dhahran, Saudi Arabia 12/7-8/2015).

Original language	English
Title of host publication	King Fahd University of Petroleum and Minerals, Research Institute - 25th Annual Saudi-Japan Symposium on Catalysts in Petroleum Refining and Petrochemicals 2015
Publisher	King Fahd University of Petroleum and Minerals
Pages	41-45
Number of pages	5
ISBN (Electronic)	9781510820098
State	Published - 2015

Publication series

Name	King Fahd University of Petroleum and Minerals, Research Institute - Annual Catalysts in Petroleum Refining and Petrochemicals Symposium Papers
Volume	2015-January

ASJC Scopus subject areas

Catalysis
General Chemistry
Fuel Technology
Energy Engineering and Power Technology

Cite this

Arudra, P., Akhtar, M. N., Aitani, A., Al-Khattaf, S., & Hattori, H. (2015). Silicalite-1 as efficient catalyst for propylene production from olefins. In King Fahd University of Petroleum and Minerals, Research Institute - 25th Annual Saudi-Japan Symposium on Catalysts in Petroleum Refining and Petrochemicals 2015 (pp. 41-45). (King Fahd University of Petroleum and Minerals, Research Institute - Annual Catalysts in Petroleum Refining and Petrochemicals Symposium Papers; Vol. 2015-January). King Fahd University of Petroleum and Minerals.

Arudra, Palani ; Akhtar, M. Naseem ; Aitani, Abdullah et al. / Silicalite-1 as efficient catalyst for propylene production from olefins. King Fahd University of Petroleum and Minerals, Research Institute - 25th Annual Saudi-Japan Symposium on Catalysts in Petroleum Refining and Petrochemicals 2015. King Fahd University of Petroleum and Minerals, 2015. pp. 41-45 (King Fahd University of Petroleum and Minerals, Research Institute - Annual Catalysts in Petroleum Refining and Petrochemicals Symposium Papers).

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title = "Silicalite-1 as efficient catalyst for propylene production from olefins",

abstract = "Silicalite-1 was synthesized, and its catalytic activity was studied in the reaction of C4-C6 olefins. Silicalite-1 exhibited a higher yield of propylene as compared with H-ZSM-5 zeolites with a Si/Ab ratio of 23-280 due to minimization of hydrogen transfer reaction. It was proposed that the weakly acidic silanol groups on silicalite-1 acted as active sites for the formation of propylene at a high temperature. Strongly acidic OH groups bridged to Si and Al promote hydrogen transfer to consume olefins to form paraffins and aromatics. This is an abstract of a paper presented at the 25th Annual Saudi-Japan Symposium on Catalysts in Petroleum Refining and Petrochemicals 2015 (Dhahran, Saudi Arabia 12/7-8/2015).",

author = "Palani Arudra and Akhtar, \{M. Naseem\} and Abdullah Aitani and Sulaiman Al-Khattaf and Hideshi Hattori",

year = "2015",

language = "English",

series = "King Fahd University of Petroleum and Minerals, Research Institute - Annual Catalysts in Petroleum Refining and Petrochemicals Symposium Papers",

publisher = "King Fahd University of Petroleum and Minerals",

pages = "41--45",

booktitle = "King Fahd University of Petroleum and Minerals, Research Institute - 25th Annual Saudi-Japan Symposium on Catalysts in Petroleum Refining and Petrochemicals 2015",

}

Arudra, P, Akhtar, MN, Aitani, A, Al-Khattaf, S & Hattori, H 2015, Silicalite-1 as efficient catalyst for propylene production from olefins. in King Fahd University of Petroleum and Minerals, Research Institute - 25th Annual Saudi-Japan Symposium on Catalysts in Petroleum Refining and Petrochemicals 2015. King Fahd University of Petroleum and Minerals, Research Institute - Annual Catalysts in Petroleum Refining and Petrochemicals Symposium Papers, vol. 2015-January, King Fahd University of Petroleum and Minerals, pp. 41-45.

Silicalite-1 as efficient catalyst for propylene production from olefins. / Arudra, Palani; Akhtar, M. Naseem; Aitani, Abdullah et al.
King Fahd University of Petroleum and Minerals, Research Institute - 25th Annual Saudi-Japan Symposium on Catalysts in Petroleum Refining and Petrochemicals 2015. King Fahd University of Petroleum and Minerals, 2015. p. 41-45 (King Fahd University of Petroleum and Minerals, Research Institute - Annual Catalysts in Petroleum Refining and Petrochemicals Symposium Papers; Vol. 2015-January).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Silicalite-1 as efficient catalyst for propylene production from olefins

AU - Arudra, Palani

AU - Akhtar, M. Naseem

AU - Aitani, Abdullah

AU - Al-Khattaf, Sulaiman

AU - Hattori, Hideshi

PY - 2015

Y1 - 2015

N2 - Silicalite-1 was synthesized, and its catalytic activity was studied in the reaction of C4-C6 olefins. Silicalite-1 exhibited a higher yield of propylene as compared with H-ZSM-5 zeolites with a Si/Ab ratio of 23-280 due to minimization of hydrogen transfer reaction. It was proposed that the weakly acidic silanol groups on silicalite-1 acted as active sites for the formation of propylene at a high temperature. Strongly acidic OH groups bridged to Si and Al promote hydrogen transfer to consume olefins to form paraffins and aromatics. This is an abstract of a paper presented at the 25th Annual Saudi-Japan Symposium on Catalysts in Petroleum Refining and Petrochemicals 2015 (Dhahran, Saudi Arabia 12/7-8/2015).

AB - Silicalite-1 was synthesized, and its catalytic activity was studied in the reaction of C4-C6 olefins. Silicalite-1 exhibited a higher yield of propylene as compared with H-ZSM-5 zeolites with a Si/Ab ratio of 23-280 due to minimization of hydrogen transfer reaction. It was proposed that the weakly acidic silanol groups on silicalite-1 acted as active sites for the formation of propylene at a high temperature. Strongly acidic OH groups bridged to Si and Al promote hydrogen transfer to consume olefins to form paraffins and aromatics. This is an abstract of a paper presented at the 25th Annual Saudi-Japan Symposium on Catalysts in Petroleum Refining and Petrochemicals 2015 (Dhahran, Saudi Arabia 12/7-8/2015).

UR - https://www.scopus.com/pages/publications/84975859231

M3 - Conference contribution

AN - SCOPUS:84975859231

T3 - King Fahd University of Petroleum and Minerals, Research Institute - Annual Catalysts in Petroleum Refining and Petrochemicals Symposium Papers

SP - 41

EP - 45

BT - King Fahd University of Petroleum and Minerals, Research Institute - 25th Annual Saudi-Japan Symposium on Catalysts in Petroleum Refining and Petrochemicals 2015

PB - King Fahd University of Petroleum and Minerals

ER -

Arudra P, Akhtar MN, Aitani A, Al-Khattaf S, Hattori H. Silicalite-1 as efficient catalyst for propylene production from olefins. In King Fahd University of Petroleum and Minerals, Research Institute - 25th Annual Saudi-Japan Symposium on Catalysts in Petroleum Refining and Petrochemicals 2015. King Fahd University of Petroleum and Minerals. 2015. p. 41-45. (King Fahd University of Petroleum and Minerals, Research Institute - Annual Catalysts in Petroleum Refining and Petrochemicals Symposium Papers).

Silicalite-1 as efficient catalyst for propylene production from olefins

Abstract

Publication series

ASJC Scopus subject areas

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