Significance of molecular-level behaviour incorporation in the constitutive models of expansive clays–a review

Expansive clays are widely prevalent all over the world as one of the most problematic soils. These soils undergo significant volume change with a change in the moisture regime, thereby posing problems to the stability of the structures founded on such strata. Efforts have been made to model the erratic behaviour of these soils at the macro, micro, and, to a lesser extent, nano levels. Micro and nano level fabrics, believed to have a central role in the overall behaviour of expansive clays, are only partially considered in the modelling concepts; natural clay fabrics with multiple clay minerals, silt and sand inclusions, micro fissures, cementation, overconsolidation, induration and other such features have never been considered. This paper covers a review of deficiencies in the existing constitutive models for the expansive characteristics of the natural clayey soils at macro, micro and nano levels. These shortcomings are discussed in the light of the understanding of the fundamentals including fabric and structure controlling the swelling mechanism of the expansive clayey soils at the molecular level. Finally, a framework based on authors’ work to incorporate molecular level behaviour in the constitutive modelling of expansive clays is presented.