Significance of an Environmental Gas Cell to Obtain a Fully Dehydrated Form and CO2-Pressurized Structure of a Metal-Organic Framework Using in Situ Single-Crystal X-ray Diffraction at 298 K

Prem Lama; Ashutosh Rawat; Phumile Sikiti; Tapan K. Pal

doi:10.1021/acs.inorgchem.1c02933

Significance of an Environmental Gas Cell to Obtain a Fully Dehydrated Form and CO₂-Pressurized Structure of a Metal-Organic Framework Using in Situ Single-Crystal X-ray Diffraction at 298 K

Prem Lama^*
, Ashutosh Rawat
, Phumile Sikiti
, Tapan K. Pal

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

The single-crystal X-ray diffraction method was employed to characterize a rigid hydrated metal-organic framework (MOF), [Co2(MA)(INA)·2H2O]n, that displays an affinity toward water molecules under ambient conditions after dehydration. The fully dehydrated form was obtained using an environmental gas cell technique in a stepwise manner followed by its CO2-pressurized structure at 298 K using in situ crystallography.

Original language	English
Pages (from-to)	939-943
Number of pages	5
Journal	Inorganic Chemistry
Volume	61
Issue number	2
DOIs	https://doi.org/10.1021/acs.inorgchem.1c02933
State	Published - 17 Jan 2022
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2022 American Chemical Society.

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

Access to Document

10.1021/acs.inorgchem.1c02933

Cite this

@article{e9dd68df5e3741688a8f731b42a9a9b9,

title = "Significance of an Environmental Gas Cell to Obtain a Fully Dehydrated Form and CO2-Pressurized Structure of a Metal-Organic Framework Using in Situ Single-Crystal X-ray Diffraction at 298 K",

abstract = "The single-crystal X-ray diffraction method was employed to characterize a rigid hydrated metal-organic framework (MOF), [Co2(MA)(INA)·2H2O]n, that displays an affinity toward water molecules under ambient conditions after dehydration. The fully dehydrated form was obtained using an environmental gas cell technique in a stepwise manner followed by its CO2-pressurized structure at 298 K using in situ crystallography.",

author = "Prem Lama and Ashutosh Rawat and Phumile Sikiti and Pal, \{Tapan K.\}",

note = "Publisher Copyright: {\textcopyright} 2022 American Chemical Society.",

year = "2022",

month = jan,

day = "17",

doi = "10.1021/acs.inorgchem.1c02933",

language = "English",

volume = "61",

pages = "939--943",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "2",

}

Significance of an Environmental Gas Cell to Obtain a Fully Dehydrated Form and CO₂-Pressurized Structure of a Metal-Organic Framework Using in Situ Single-Crystal X-ray Diffraction at 298 K. / Lama, Prem; Rawat, Ashutosh; Sikiti, Phumile et al.
In: Inorganic Chemistry, Vol. 61, No. 2, 17.01.2022, p. 939-943.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Significance of an Environmental Gas Cell to Obtain a Fully Dehydrated Form and CO2-Pressurized Structure of a Metal-Organic Framework Using in Situ Single-Crystal X-ray Diffraction at 298 K

AU - Lama, Prem

AU - Rawat, Ashutosh

AU - Sikiti, Phumile

AU - Pal, Tapan K.

PY - 2022/1/17

Y1 - 2022/1/17

N2 - The single-crystal X-ray diffraction method was employed to characterize a rigid hydrated metal-organic framework (MOF), [Co2(MA)(INA)·2H2O]n, that displays an affinity toward water molecules under ambient conditions after dehydration. The fully dehydrated form was obtained using an environmental gas cell technique in a stepwise manner followed by its CO2-pressurized structure at 298 K using in situ crystallography.

AB - The single-crystal X-ray diffraction method was employed to characterize a rigid hydrated metal-organic framework (MOF), [Co2(MA)(INA)·2H2O]n, that displays an affinity toward water molecules under ambient conditions after dehydration. The fully dehydrated form was obtained using an environmental gas cell technique in a stepwise manner followed by its CO2-pressurized structure at 298 K using in situ crystallography.

UR - https://www.scopus.com/pages/publications/85122726939

U2 - 10.1021/acs.inorgchem.1c02933

DO - 10.1021/acs.inorgchem.1c02933

M3 - Article

C2 - 34974708

AN - SCOPUS:85122726939

SN - 0020-1669

VL - 61

SP - 939

EP - 943

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 2

ER -