Sequential extraction procedure for the determination of some trace elements in fertilizer samples

Yunus Emre Unsal; Mustafa Tuzen; Mustafa Soylak

doi:10.5740/jaoacint.13-002

Sequential extraction procedure for the determination of some trace elements in fertilizer samples

Yunus Emre Unsal, Mustafa Tuzen, Mustafa Soylak^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Total concentration of metal ions at trace levels does not give sufficient information about toxicity and biological availability of these elements in fertilizer samples. In the presented work, a sequential extraction procedure modified by the European Community Bureau of Reference (BCR) was applied to fractionate Cd, Cr, Co, Cu, Fe, Pb, Mn, Ni, and Zn levels in two fertilizer samples collected from cooperative agricultural retailers. The fractions extracted were exchangeable/dilute acid soluble, reducible bound to Fe/Mn oxides, oxidizable bound to organic matter and sulfides, and residual. The determination of analyte elements was done by flame atomic absorption spectrometry. The accuracy of the procedure was validated with BCR-701 sediment certified reference material. The RSD of the procedure was less than 10%.

Original language	English
Pages (from-to)	1034-1038
Number of pages	5
Journal	Journal of AOAC International
Volume	97
Issue number	4
DOIs	https://doi.org/10.5740/jaoacint.13-002
State	Published - 2014
Externally published	Yes

ASJC Scopus subject areas

Analytical Chemistry
Food Science
Environmental Chemistry
Agronomy and Crop Science
Pharmacology

Access to Document

10.5740/jaoacint.13-002

Cite this

@article{d47baaea771942f3b6e1ad8ad94f2397,

title = "Sequential extraction procedure for the determination of some trace elements in fertilizer samples",

abstract = "Total concentration of metal ions at trace levels does not give sufficient information about toxicity and biological availability of these elements in fertilizer samples. In the presented work, a sequential extraction procedure modified by the European Community Bureau of Reference (BCR) was applied to fractionate Cd, Cr, Co, Cu, Fe, Pb, Mn, Ni, and Zn levels in two fertilizer samples collected from cooperative agricultural retailers. The fractions extracted were exchangeable/dilute acid soluble, reducible bound to Fe/Mn oxides, oxidizable bound to organic matter and sulfides, and residual. The determination of analyte elements was done by flame atomic absorption spectrometry. The accuracy of the procedure was validated with BCR-701 sediment certified reference material. The RSD of the procedure was less than 10%.",

author = "Unsal, {Yunus Emre} and Mustafa Tuzen and Mustafa Soylak",

year = "2014",

doi = "10.5740/jaoacint.13-002",

language = "English",

volume = "97",

pages = "1034--1038",

journal = "Journal of AOAC International",

issn = "1060-3271",

publisher = "AOAC International",

number = "4",

}

TY - JOUR

T1 - Sequential extraction procedure for the determination of some trace elements in fertilizer samples

AU - Unsal, Yunus Emre

AU - Tuzen, Mustafa

AU - Soylak, Mustafa

PY - 2014

Y1 - 2014

N2 - Total concentration of metal ions at trace levels does not give sufficient information about toxicity and biological availability of these elements in fertilizer samples. In the presented work, a sequential extraction procedure modified by the European Community Bureau of Reference (BCR) was applied to fractionate Cd, Cr, Co, Cu, Fe, Pb, Mn, Ni, and Zn levels in two fertilizer samples collected from cooperative agricultural retailers. The fractions extracted were exchangeable/dilute acid soluble, reducible bound to Fe/Mn oxides, oxidizable bound to organic matter and sulfides, and residual. The determination of analyte elements was done by flame atomic absorption spectrometry. The accuracy of the procedure was validated with BCR-701 sediment certified reference material. The RSD of the procedure was less than 10%.

AB - Total concentration of metal ions at trace levels does not give sufficient information about toxicity and biological availability of these elements in fertilizer samples. In the presented work, a sequential extraction procedure modified by the European Community Bureau of Reference (BCR) was applied to fractionate Cd, Cr, Co, Cu, Fe, Pb, Mn, Ni, and Zn levels in two fertilizer samples collected from cooperative agricultural retailers. The fractions extracted were exchangeable/dilute acid soluble, reducible bound to Fe/Mn oxides, oxidizable bound to organic matter and sulfides, and residual. The determination of analyte elements was done by flame atomic absorption spectrometry. The accuracy of the procedure was validated with BCR-701 sediment certified reference material. The RSD of the procedure was less than 10%.

UR - http://www.scopus.com/inward/record.url?scp=84905386521&partnerID=8YFLogxK

U2 - 10.5740/jaoacint.13-002

DO - 10.5740/jaoacint.13-002

M3 - Article

C2 - 25145134

AN - SCOPUS:84905386521

SN - 1060-3271

VL - 97

SP - 1034

EP - 1038

JO - Journal of AOAC International

JF - Journal of AOAC International

IS - 4

ER -

Sequential extraction procedure for the determination of some trace elements in fertilizer samples

Abstract

ASJC Scopus subject areas

Access to Document

Fingerprint

Cite this