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Semiconductor-mediated photocatalytic degradation of anazo dye, chrysoidine Y in aqueous suspensions

  • M. Qamar
  • , M. Saquib
  • , M. Muneer*
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

49 Scopus citations

Abstract

The photocatalytic degradation of an azo dye derivative, chrysoidine Y (1), was investigated in aqueous suspensions of titanium dioxide and zinc oxide by monitoring the change in substrate concentration employing UV spectroscopic analysis and decrease in total organic carbon content as a function of irradiation time under a variety of conditions. The degradation of the dye was studied under different conditions such as pH, catalyst concentration, substrate concentration and in the presence of electron acceptors such as hydrogen peroxide (H2 O2) and potassium bromate (KBrO3) besides molecular oxygen. The degradation rates were found to be strongly influenced by all the above parameters. The photocatalyst Degussa P25 was found to be more efficient as compared with zinc oxide.

Original languageEnglish
Pages (from-to)185-193
Number of pages9
JournalDesalination
Volume171
Issue number2
DOIs
StatePublished - 10 Jan 2005
Externally publishedYes

Bibliographical note

Funding Information:
The total organic carbon analyzer used for the analyses of the samples was a gift from the Alexander von Humboldt Foundation, Germany. Financial support by the Department of Science and Technology, Government of India, New Delhi, and The Third World Academy of Sciences, Trieste, Italy is gratefully acknowledged.

Keywords

  • Chrysoidine Y
  • Dye
  • Photocatalysis
  • Titanium dioxide
  • Zinc oxide

ASJC Scopus subject areas

  • General Chemistry
  • General Chemical Engineering
  • General Materials Science
  • Water Science and Technology
  • Mechanical Engineering

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