Selectively capturing carbon dioxide from mixed gas streams using a new microporous organic copolymer

Ahmed M. Alloush; Mahmoud M. Abdelnaby; Kyle E. Cordova; Naef A.A. Qasem; Bassem A. Al-Maythalony; Almaz Jalilov; Youcef Mankour; Othman Charles S. Al Hamouz

doi:10.1016/j.micromeso.2020.110391

Selectively capturing carbon dioxide from mixed gas streams using a new microporous organic copolymer

Ahmed M. Alloush
, Mahmoud M. Abdelnaby
, Kyle E. Cordova
, Naef A.A. Qasem
, Bassem A. Al-Maythalony
, Almaz Jalilov
, Youcef Mankour
, Othman Charles S. Al Hamouz^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

A novel crosslinked microporous polymer was synthesized via a modified acid-catalyzed Friedel-Crafts polycondensation reaction. By virtue of the rigid and polarizable monomers (aniline and pyrrole), the polymer, termed KFUPM-4, was proven permanently porous (Brunauer-Emmett-Teller surface area = 650 m² g⁻¹) with a high CO₂ capacity (33 cm³ g⁻¹ at 760 Torr and 298 K) and selectivity (CO₂:CH₄ selectivity = 15:1 at 298 K). As a result of these properties, KFUPM-4 was subjected to breakthrough measurements, whereby the material's ability to selectively capture CO₂ under dynamic conditions from both dry and wet mixed gas streams was clearly demonstrated.

Original language	English
Article number	110391
Journal	Microporous and Mesoporous Materials
Volume	305
DOIs	https://doi.org/10.1016/j.micromeso.2020.110391
State	Published - 1 Oct 2020

Bibliographical note

Publisher Copyright:
© 2020 Elsevier Inc.

Keywords

Carbon capture and sequestration
Gas separation
Microporous organic polymers
Polymer chemistry

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics
Mechanics of Materials

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.micromeso.2020.110391

Cite this

@article{6d29428df0304daca5f9996036ffee55,

title = "Selectively capturing carbon dioxide from mixed gas streams using a new microporous organic copolymer",

abstract = "A novel crosslinked microporous polymer was synthesized via a modified acid-catalyzed Friedel-Crafts polycondensation reaction. By virtue of the rigid and polarizable monomers (aniline and pyrrole), the polymer, termed KFUPM-4, was proven permanently porous (Brunauer-Emmett-Teller surface area = 650 m2 g−1) with a high CO2 capacity (33 cm3 g−1 at 760 Torr and 298 K) and selectivity (CO2:CH4 selectivity = 15:1 at 298 K). As a result of these properties, KFUPM-4 was subjected to breakthrough measurements, whereby the material's ability to selectively capture CO2 under dynamic conditions from both dry and wet mixed gas streams was clearly demonstrated.",

keywords = "Carbon capture and sequestration, Gas separation, Microporous organic polymers, Polymer chemistry",

author = "Alloush, \{Ahmed M.\} and Abdelnaby, \{Mahmoud M.\} and Cordova, \{Kyle E.\} and Qasem, \{Naef A.A.\} and Al-Maythalony, \{Bassem A.\} and Almaz Jalilov and Youcef Mankour and \{Al Hamouz\}, \{Othman Charles S.\}",

note = "Publisher Copyright: {\textcopyright} 2020 Elsevier Inc.",

year = "2020",

month = oct,

day = "1",

doi = "10.1016/j.micromeso.2020.110391",

language = "English",

volume = "305",

journal = "Microporous and Mesoporous Materials",

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T1 - Selectively capturing carbon dioxide from mixed gas streams using a new microporous organic copolymer

AU - Alloush, Ahmed M.

AU - Abdelnaby, Mahmoud M.

AU - Cordova, Kyle E.

AU - Qasem, Naef A.A.

AU - Al-Maythalony, Bassem A.

AU - Jalilov, Almaz

AU - Mankour, Youcef

AU - Al Hamouz, Othman Charles S.

PY - 2020/10/1

Y1 - 2020/10/1

N2 - A novel crosslinked microporous polymer was synthesized via a modified acid-catalyzed Friedel-Crafts polycondensation reaction. By virtue of the rigid and polarizable monomers (aniline and pyrrole), the polymer, termed KFUPM-4, was proven permanently porous (Brunauer-Emmett-Teller surface area = 650 m2 g−1) with a high CO2 capacity (33 cm3 g−1 at 760 Torr and 298 K) and selectivity (CO2:CH4 selectivity = 15:1 at 298 K). As a result of these properties, KFUPM-4 was subjected to breakthrough measurements, whereby the material's ability to selectively capture CO2 under dynamic conditions from both dry and wet mixed gas streams was clearly demonstrated.

AB - A novel crosslinked microporous polymer was synthesized via a modified acid-catalyzed Friedel-Crafts polycondensation reaction. By virtue of the rigid and polarizable monomers (aniline and pyrrole), the polymer, termed KFUPM-4, was proven permanently porous (Brunauer-Emmett-Teller surface area = 650 m2 g−1) with a high CO2 capacity (33 cm3 g−1 at 760 Torr and 298 K) and selectivity (CO2:CH4 selectivity = 15:1 at 298 K). As a result of these properties, KFUPM-4 was subjected to breakthrough measurements, whereby the material's ability to selectively capture CO2 under dynamic conditions from both dry and wet mixed gas streams was clearly demonstrated.

KW - Carbon capture and sequestration

KW - Gas separation

KW - Microporous organic polymers

KW - Polymer chemistry

UR - https://www.scopus.com/pages/publications/85086935258

U2 - 10.1016/j.micromeso.2020.110391

DO - 10.1016/j.micromeso.2020.110391

M3 - Article

AN - SCOPUS:85086935258

SN - 1387-1811

VL - 305

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

M1 - 110391

ER -

Selectively capturing carbon dioxide from mixed gas streams using a new microporous organic copolymer

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

UN SDGs

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