Ruthenium nanoparticles intercalated in montmorillonite (Nano-ru@mmt) is highly efficient catalyst for the selective hydrogenation of 2-furaldehyde in benign aqueous medium

Farooq Ahmad Khan; Sana Yaqoob; Nourina Nasim; Yan Wang; Muhammad Usman; Anvarhusein A. Isab; Muhammad Altaf; Bing Sun; Islam H. El Azab; Hesham R. El-Seedi

doi:10.3390/catal11010066

Ruthenium nanoparticles intercalated in montmorillonite (Nano-ru@mmt) is highly efficient catalyst for the selective hydrogenation of 2-furaldehyde in benign aqueous medium

Farooq Ahmad Khan^*
, Sana Yaqoob
, Nourina Nasim
, Yan Wang
, Muhammad Usman
, Anvarhusein A. Isab
, Muhammad Altaf
, Bing Sun
, Islam H. El Azab
, Hesham R. El-Seedi^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Chemoselective hydrogenation of 2-furaldehyde to furfuryl alcohol using green solvents is an important research area to get eco-friendly fuels and fine chemicals. Herein, we report ruthenium nanoparticles (~1.8 nm) intercalated in montmorillonite as an efficient catalytic system, which can selectively hydrogenate 2-furaldehyde in a benign aqueous medium. The complete conversion was observed at 40^◦C with 1 MPa H₂, the selectivity of furfuryl alcohol being >99%, and turnover number 1165. After a catalytic run, the montmorillonite-supported ruthenium nanoparticles can be recycled and reused without losing their activity and selectivity.

Original language	English
Article number	66
Pages (from-to)	1-9
Number of pages	9
Journal	Catalysts
Volume	11
Issue number	1
DOIs	https://doi.org/10.3390/catal11010066
State	Published - Jan 2021

Bibliographical note

Publisher Copyright:
© 2021 by the authors. Licensee MDPI, Basel, Switzerland.

Keywords

2-furaldehyde
Biomass valorization
Eco-friendly fuels
Furfural
Furfuryl alcohol
Green solvent
Hydrogenation
Montmorillonite
Ruthe-nium nanoparticles
Smectite

ASJC Scopus subject areas

Catalysis
General Environmental Science
Physical and Theoretical Chemistry

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10.3390/catal11010066

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Khan, F. A., Yaqoob, S., Nasim, N., Wang, Y., Usman, M., Isab, A. A., Altaf, M., Sun, B., El Azab, I. H., & El-Seedi, H. R. (2021). Ruthenium nanoparticles intercalated in montmorillonite (Nano-ru@mmt) is highly efficient catalyst for the selective hydrogenation of 2-furaldehyde in benign aqueous medium. Catalysts, 11(1), 1-9. Article 66. https://doi.org/10.3390/catal11010066

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title = "Ruthenium nanoparticles intercalated in montmorillonite (Nano-ru@mmt) is highly efficient catalyst for the selective hydrogenation of 2-furaldehyde in benign aqueous medium",

abstract = "Chemoselective hydrogenation of 2-furaldehyde to furfuryl alcohol using green solvents is an important research area to get eco-friendly fuels and fine chemicals. Herein, we report ruthenium nanoparticles (\textasciitilde{}1.8 nm) intercalated in montmorillonite as an efficient catalytic system, which can selectively hydrogenate 2-furaldehyde in a benign aqueous medium. The complete conversion was observed at 40◦C with 1 MPa H2, the selectivity of furfuryl alcohol being >99\%, and turnover number 1165. After a catalytic run, the montmorillonite-supported ruthenium nanoparticles can be recycled and reused without losing their activity and selectivity.",

keywords = "2-furaldehyde, Biomass valorization, Eco-friendly fuels, Furfural, Furfuryl alcohol, Green solvent, Hydrogenation, Montmorillonite, Ruthe-nium nanoparticles, Smectite",

author = "Khan, \{Farooq Ahmad\} and Sana Yaqoob and Nourina Nasim and Yan Wang and Muhammad Usman and Isab, \{Anvarhusein A.\} and Muhammad Altaf and Bing Sun and \{El Azab\}, \{Islam H.\} and El-Seedi, \{Hesham R.\}",

note = "Publisher Copyright: {\textcopyright} 2021 by the authors. Licensee MDPI, Basel, Switzerland.",

year = "2021",

month = jan,

doi = "10.3390/catal11010066",

language = "English",

volume = "11",

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journal = "Catalysts",

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AU - Khan, Farooq Ahmad

AU - Yaqoob, Sana

AU - Nasim, Nourina

AU - Wang, Yan

AU - Usman, Muhammad

AU - Isab, Anvarhusein A.

AU - Altaf, Muhammad

AU - Sun, Bing

AU - El Azab, Islam H.

AU - El-Seedi, Hesham R.

PY - 2021/1

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AB - Chemoselective hydrogenation of 2-furaldehyde to furfuryl alcohol using green solvents is an important research area to get eco-friendly fuels and fine chemicals. Herein, we report ruthenium nanoparticles (~1.8 nm) intercalated in montmorillonite as an efficient catalytic system, which can selectively hydrogenate 2-furaldehyde in a benign aqueous medium. The complete conversion was observed at 40◦C with 1 MPa H2, the selectivity of furfuryl alcohol being >99%, and turnover number 1165. After a catalytic run, the montmorillonite-supported ruthenium nanoparticles can be recycled and reused without losing their activity and selectivity.

KW - 2-furaldehyde

KW - Biomass valorization

KW - Eco-friendly fuels

KW - Furfural

KW - Furfuryl alcohol

KW - Green solvent

KW - Hydrogenation

KW - Montmorillonite

KW - Ruthe-nium nanoparticles

KW - Smectite

UR - https://www.scopus.com/pages/publications/85099260136

U2 - 10.3390/catal11010066

DO - 10.3390/catal11010066

M3 - Article

AN - SCOPUS:85099260136

SN - 2073-4344

VL - 11

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JO - Catalysts

JF - Catalysts

IS - 1

M1 - 66

ER -

Ruthenium nanoparticles intercalated in montmorillonite (Nano-ru@mmt) is highly efficient catalyst for the selective hydrogenation of 2-furaldehyde in benign aqueous medium

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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