Role of surface functionalization on corrosion resistance and thermal stability of epoxy/glass flake composite coating on cold rolled steel

H. Alhumade; R. P. Nogueira; A. Yu; A. Elkamel; L. Simon; A. Abdala

doi:10.1016/j.porgcoat.2018.01.030

Role of surface functionalization on corrosion resistance and thermal stability of epoxy/glass flake composite coating on cold rolled steel

H. Alhumade, R. P. Nogueira, A. Yu, A. Elkamel, L. Simon, A. Abdala^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

Composites of epoxy and functionalized glass flake (FGF) with enhanced corrosion protection for cold rolled steel (CRS) are developed. The influence of glass flake (GF) functionalization on their dispersion in the epoxy matrix was examined using TEM and the interface adhesion was evaluated using SEM. The coating corrosion resistance was investigated via Electrochemical Impedance Spectroscopy and Potentiodynamic Polarization measurements and the long-term protection was measured gravimetrically by immersing bare and coated CRS specimens in 3.5 wt.% NaCl for 90 days. The study demonstrates attaching aminosilane groups to the surface of GF leads to substantial enhancement in corrosion protection and thermal stability of the epoxy-FGF (E/FGF) composite coating at small FGF loading.

Original language	English
Pages (from-to)	180-188
Number of pages	9
Journal	Progress in Organic Coatings
Volume	122
DOIs	https://doi.org/10.1016/j.porgcoat.2018.01.030
State	Published - Sep 2018
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2018 Elsevier B.V.

Keywords

Adhesion
Coatings
Cold rolled steel
Corrosion
Epoxy
Glass flake

ASJC Scopus subject areas

General Chemical Engineering
Surfaces, Coatings and Films
Organic Chemistry
Materials Chemistry

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10.1016/j.porgcoat.2018.01.030

Cite this

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title = "Role of surface functionalization on corrosion resistance and thermal stability of epoxy/glass flake composite coating on cold rolled steel",

abstract = "Composites of epoxy and functionalized glass flake (FGF) with enhanced corrosion protection for cold rolled steel (CRS) are developed. The influence of glass flake (GF) functionalization on their dispersion in the epoxy matrix was examined using TEM and the interface adhesion was evaluated using SEM. The coating corrosion resistance was investigated via Electrochemical Impedance Spectroscopy and Potentiodynamic Polarization measurements and the long-term protection was measured gravimetrically by immersing bare and coated CRS specimens in 3.5 wt.\% NaCl for 90 days. The study demonstrates attaching aminosilane groups to the surface of GF leads to substantial enhancement in corrosion protection and thermal stability of the epoxy-FGF (E/FGF) composite coating at small FGF loading.",

keywords = "Adhesion, Coatings, Cold rolled steel, Corrosion, Epoxy, Glass flake",

author = "H. Alhumade and Nogueira, \{R. P.\} and A. Yu and A. Elkamel and L. Simon and A. Abdala",

note = "Publisher Copyright: {\textcopyright} 2018 Elsevier B.V.",

year = "2018",

month = sep,

doi = "10.1016/j.porgcoat.2018.01.030",

language = "English",

volume = "122",

pages = "180--188",

journal = "Progress in Organic Coatings",

issn = "0300-9440",

publisher = "Elsevier",

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TY - JOUR

T1 - Role of surface functionalization on corrosion resistance and thermal stability of epoxy/glass flake composite coating on cold rolled steel

AU - Alhumade, H.

AU - Nogueira, R. P.

AU - Yu, A.

AU - Elkamel, A.

AU - Simon, L.

AU - Abdala, A.

PY - 2018/9

Y1 - 2018/9

N2 - Composites of epoxy and functionalized glass flake (FGF) with enhanced corrosion protection for cold rolled steel (CRS) are developed. The influence of glass flake (GF) functionalization on their dispersion in the epoxy matrix was examined using TEM and the interface adhesion was evaluated using SEM. The coating corrosion resistance was investigated via Electrochemical Impedance Spectroscopy and Potentiodynamic Polarization measurements and the long-term protection was measured gravimetrically by immersing bare and coated CRS specimens in 3.5 wt.% NaCl for 90 days. The study demonstrates attaching aminosilane groups to the surface of GF leads to substantial enhancement in corrosion protection and thermal stability of the epoxy-FGF (E/FGF) composite coating at small FGF loading.

AB - Composites of epoxy and functionalized glass flake (FGF) with enhanced corrosion protection for cold rolled steel (CRS) are developed. The influence of glass flake (GF) functionalization on their dispersion in the epoxy matrix was examined using TEM and the interface adhesion was evaluated using SEM. The coating corrosion resistance was investigated via Electrochemical Impedance Spectroscopy and Potentiodynamic Polarization measurements and the long-term protection was measured gravimetrically by immersing bare and coated CRS specimens in 3.5 wt.% NaCl for 90 days. The study demonstrates attaching aminosilane groups to the surface of GF leads to substantial enhancement in corrosion protection and thermal stability of the epoxy-FGF (E/FGF) composite coating at small FGF loading.

KW - Adhesion

KW - Coatings

KW - Cold rolled steel

KW - Corrosion

KW - Epoxy

KW - Glass flake

UR - https://www.scopus.com/pages/publications/85047783148

U2 - 10.1016/j.porgcoat.2018.01.030

DO - 10.1016/j.porgcoat.2018.01.030

M3 - Article

AN - SCOPUS:85047783148

SN - 0300-9440

VL - 122

SP - 180

EP - 188

JO - Progress in Organic Coatings

JF - Progress in Organic Coatings

ER -

Role of surface functionalization on corrosion resistance and thermal stability of epoxy/glass flake composite coating on cold rolled steel

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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