Role of metal–organic frameworks in catalysis

More than 95% chemical products are synthesized by catalytic reactions; exploring the area of research of catalysts is a very thrilling research field. The intriguing, porous, and tailorable metal–organic frameworks (MOFs) are very promising in this regard, thereby providing opportunities for designing catalysts on different supports. MOFs have gained attention due to their importance in both homogeneous and heterogeneous catalysis. For enhanced catalytic activity, various structural modifications can be done without altering the chemical nature. In this chapter, we summarize the recent advances in MOF’s functionalization in catalysis by modification of different components of MOFs. This chapter indicates significant characteristics of the MOFs with reference to conventional catalysts. We further present some synthetic and designing strategies for advanced heterogeneous catalysis by enhanced adsorption, diffusion, and accumulation of substrates at active sites. The chapter is concluded with the future challenges and limitations in further research directions.