Rh6(CO)16-H3PW12O 40-catalyzed one pot hydroformylation-cyclotrimerization of cyclohexene and cyclopentene into 2,4,6-trisubstituted-1,3,5-trioxanes

Bassam El Ali

doi:10.1016/S1381-1169(03)00375-3

Rh₆(CO)₁₆-H₃PW₁₂O ₄₀-catalyzed one pot hydroformylation-cyclotrimerization of cyclohexene and cyclopentene into 2,4,6-trisubstituted-1,3,5-trioxanes

Bassam El Ali^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

A new one pot reaction of hydroformylation-cyclotrimerization of cyclopentene 1a and cyclohexene 1b was selectively catalyzed by Rh ₆(CO)₁₆ and H₃PW₁₂O ₄₀·xH₂O (HPA-W₁₂) in THF as a solvent at 40 atm (CO/H₂ = 1/1) to give 2,4,6-trisubstituted-1,3,5-trioxanes 3a and 3b as major products along with the corresponding aldehydes 2a and 2b.

Original language	English
Pages (from-to)	53-58
Number of pages	6
Journal	Journal of Molecular Catalysis A: Chemical
Volume	203
Issue number	1-2
DOIs	https://doi.org/10.1016/S1381-1169(03)00375-3
State	Published - 1 Sep 2003

Bibliographical note

Funding Information:
We thank King Fahd University of Petroleum & Minerals (KFUPM, Saudi Arabia) for providing the facility and for financial support for this project.

Keywords

Cyclohexene
Cyclotrimerization
Heteropolyacid
Hydroformylation
Rhodium
Trioxane

ASJC Scopus subject areas

Catalysis
Process Chemistry and Technology
Physical and Theoretical Chemistry

Access to Document

10.1016/S1381-1169(03)00375-3

Cite this

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title = "Rh6(CO)16-H3PW12O 40-catalyzed one pot hydroformylation-cyclotrimerization of cyclohexene and cyclopentene into 2,4,6-trisubstituted-1,3,5-trioxanes",

abstract = "A new one pot reaction of hydroformylation-cyclotrimerization of cyclopentene 1a and cyclohexene 1b was selectively catalyzed by Rh 6(CO)16 and H3PW12O 40·xH2O (HPA-W12) in THF as a solvent at 40 atm (CO/H2 = 1/1) to give 2,4,6-trisubstituted-1,3,5-trioxanes 3a and 3b as major products along with the corresponding aldehydes 2a and 2b.",

keywords = "Cyclohexene, Cyclotrimerization, Heteropolyacid, Hydroformylation, Rhodium, Trioxane",

author = "\{El Ali\}, Bassam",

note = "Funding Information: We thank King Fahd University of Petroleum \& Minerals (KFUPM, Saudi Arabia) for providing the facility and for financial support for this project. ",

year = "2003",

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doi = "10.1016/S1381-1169(03)00375-3",

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TY - JOUR

T1 - Rh6(CO)16-H3PW12O 40-catalyzed one pot hydroformylation-cyclotrimerization of cyclohexene and cyclopentene into 2,4,6-trisubstituted-1,3,5-trioxanes

AU - El Ali, Bassam

N1 - Funding Information: We thank King Fahd University of Petroleum & Minerals (KFUPM, Saudi Arabia) for providing the facility and for financial support for this project.

PY - 2003/9/1

Y1 - 2003/9/1

N2 - A new one pot reaction of hydroformylation-cyclotrimerization of cyclopentene 1a and cyclohexene 1b was selectively catalyzed by Rh 6(CO)16 and H3PW12O 40·xH2O (HPA-W12) in THF as a solvent at 40 atm (CO/H2 = 1/1) to give 2,4,6-trisubstituted-1,3,5-trioxanes 3a and 3b as major products along with the corresponding aldehydes 2a and 2b.

AB - A new one pot reaction of hydroformylation-cyclotrimerization of cyclopentene 1a and cyclohexene 1b was selectively catalyzed by Rh 6(CO)16 and H3PW12O 40·xH2O (HPA-W12) in THF as a solvent at 40 atm (CO/H2 = 1/1) to give 2,4,6-trisubstituted-1,3,5-trioxanes 3a and 3b as major products along with the corresponding aldehydes 2a and 2b.

KW - Cyclohexene

KW - Cyclotrimerization

KW - Heteropolyacid

KW - Hydroformylation

KW - Rhodium

KW - Trioxane

UR - https://www.scopus.com/pages/publications/0141446164

U2 - 10.1016/S1381-1169(03)00375-3

DO - 10.1016/S1381-1169(03)00375-3

M3 - Article

AN - SCOPUS:0141446164

SN - 1381-1169

VL - 203

SP - 53

EP - 58

JO - Journal of Molecular Catalysis A: Chemical

JF - Journal of Molecular Catalysis A: Chemical

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