Rhodium(I) and rhodium(III)-heteropolyacids supported on MCM-41 for the catalytic hydroformylation of styrene derivatives

B. El Ali; J. Tijani; M. Fettouhi; M. El-Faer; A. Al-Arfaj

doi:10.1016/j.apcata.2005.01.005

Rhodium(I) and rhodium(III)-heteropolyacids supported on MCM-41 for the catalytic hydroformylation of styrene derivatives

B. El Ali
, J. Tijani
, M. Fettouhi
, M. El-Faer
, A. Al-Arfaj

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

Rh supported catalysts were prepared by impregnating rhodium(I) and rhodium(III) complexes with and without heteropolyacids for the hydroformylation of styrene derivatives. The effect of the pore size of MCM-41 was considered. The addition of water showed a promoting effect with Rh(III) based catalysts. The amount of water showed also a big effect on the catalytic activity of the Rh(III) supported catalyst. The change of the temperature affects the selectivity of the reaction time of the reaction. Different heteropolyacids such as H₃ PMo₁₂O₄₀·xH₂O (HPA-Mo₁₂) and H₃PW₁₂O₄₀ ·yH₂O (HPA-W₁₂) were used as co-catalysts that were impregnated along with rhodium complexes on the inorganic supports. The results showed a clear effect of the heteropolyacid H₃PW₁₂O₄₀·yH₂O (HPA-W₁₂) in increasing the catalytic activity of the rhodium supported catalyst.

Original language	English
Pages (from-to)	185-196
Number of pages	12
Journal	Applied Catalysis A: General
Volume	283
Issue number	1-2
DOIs	https://doi.org/10.1016/j.apcata.2005.01.005
State	Published - 8 Apr 2005

Bibliographical note

Funding Information:
We gratefully acknowledge King Abdulaziz City for Science and Technology (KACST-Saudi Arabia) for the financial support under the project KACST 18–15. We equally thank King Fahd University of Petroleum and Minerals (KFUPM-Saudi Arabia) for providing all support to this project.

Keywords

Clay
Heteropolyacid
Hydroformylation
MCM-41
Phosphine ligands
Rhodium
Styrene
Syngas
Zeolites

ASJC Scopus subject areas

Catalysis
Process Chemistry and Technology

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10.1016/j.apcata.2005.01.005

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title = "Rhodium(I) and rhodium(III)-heteropolyacids supported on MCM-41 for the catalytic hydroformylation of styrene derivatives",

abstract = "Rh supported catalysts were prepared by impregnating rhodium(I) and rhodium(III) complexes with and without heteropolyacids for the hydroformylation of styrene derivatives. The effect of the pore size of MCM-41 was considered. The addition of water showed a promoting effect with Rh(III) based catalysts. The amount of water showed also a big effect on the catalytic activity of the Rh(III) supported catalyst. The change of the temperature affects the selectivity of the reaction time of the reaction. Different heteropolyacids such as H3 PMo12O40·xH2O (HPA-Mo12) and H3PW12O40 ·yH2O (HPA-W12) were used as co-catalysts that were impregnated along with rhodium complexes on the inorganic supports. The results showed a clear effect of the heteropolyacid H3PW12O40·yH2O (HPA-W12) in increasing the catalytic activity of the rhodium supported catalyst.",

keywords = "Clay, Heteropolyacid, Hydroformylation, MCM-41, Phosphine ligands, Rhodium, Styrene, Syngas, Zeolites",

author = "\{El Ali\}, B. and J. Tijani and M. Fettouhi and M. El-Faer and A. Al-Arfaj",

note = "Funding Information: We gratefully acknowledge King Abdulaziz City for Science and Technology (KACST-Saudi Arabia) for the financial support under the project KACST 18–15. We equally thank King Fahd University of Petroleum and Minerals (KFUPM-Saudi Arabia) for providing all support to this project.",

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doi = "10.1016/j.apcata.2005.01.005",

language = "English",

volume = "283",

pages = "185--196",

journal = "Applied Catalysis A: General",

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TY - JOUR

T1 - Rhodium(I) and rhodium(III)-heteropolyacids supported on MCM-41 for the catalytic hydroformylation of styrene derivatives

AU - El Ali, B.

AU - Tijani, J.

AU - Fettouhi, M.

AU - El-Faer, M.

AU - Al-Arfaj, A.

N1 - Funding Information: We gratefully acknowledge King Abdulaziz City for Science and Technology (KACST-Saudi Arabia) for the financial support under the project KACST 18–15. We equally thank King Fahd University of Petroleum and Minerals (KFUPM-Saudi Arabia) for providing all support to this project.

PY - 2005/4/8

Y1 - 2005/4/8

N2 - Rh supported catalysts were prepared by impregnating rhodium(I) and rhodium(III) complexes with and without heteropolyacids for the hydroformylation of styrene derivatives. The effect of the pore size of MCM-41 was considered. The addition of water showed a promoting effect with Rh(III) based catalysts. The amount of water showed also a big effect on the catalytic activity of the Rh(III) supported catalyst. The change of the temperature affects the selectivity of the reaction time of the reaction. Different heteropolyacids such as H3 PMo12O40·xH2O (HPA-Mo12) and H3PW12O40 ·yH2O (HPA-W12) were used as co-catalysts that were impregnated along with rhodium complexes on the inorganic supports. The results showed a clear effect of the heteropolyacid H3PW12O40·yH2O (HPA-W12) in increasing the catalytic activity of the rhodium supported catalyst.

AB - Rh supported catalysts were prepared by impregnating rhodium(I) and rhodium(III) complexes with and without heteropolyacids for the hydroformylation of styrene derivatives. The effect of the pore size of MCM-41 was considered. The addition of water showed a promoting effect with Rh(III) based catalysts. The amount of water showed also a big effect on the catalytic activity of the Rh(III) supported catalyst. The change of the temperature affects the selectivity of the reaction time of the reaction. Different heteropolyacids such as H3 PMo12O40·xH2O (HPA-Mo12) and H3PW12O40 ·yH2O (HPA-W12) were used as co-catalysts that were impregnated along with rhodium complexes on the inorganic supports. The results showed a clear effect of the heteropolyacid H3PW12O40·yH2O (HPA-W12) in increasing the catalytic activity of the rhodium supported catalyst.

KW - Clay

KW - Heteropolyacid

KW - Hydroformylation

KW - MCM-41

KW - Phosphine ligands

KW - Rhodium

KW - Styrene

KW - Syngas

KW - Zeolites

UR - https://www.scopus.com/pages/publications/14844289592

U2 - 10.1016/j.apcata.2005.01.005

DO - 10.1016/j.apcata.2005.01.005

M3 - Article

AN - SCOPUS:14844289592

SN - 0926-860X

VL - 283

SP - 185

EP - 196

JO - Applied Catalysis A: General

JF - Applied Catalysis A: General

IS - 1-2

ER -

Rhodium(I) and rhodium(III)-heteropolyacids supported on MCM-41 for the catalytic hydroformylation of styrene derivatives

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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