Reversible sidewall functionalization of buckytubes

P. J. Boul; J. Liu; E. T. Mickelson; C. B. Huffman; L. M. Ericson; I. W. Chiang; K. A. Smith; D. T. Colbert; R. H. Hauge; J. L. Margrave; R. E. Smalley

doi:10.1016/S0009-2614(99)00713-7

Reversible sidewall functionalization of buckytubes

P. J. Boul^*
, J. Liu
, E. T. Mickelson
, C. B. Huffman
, L. M. Ericson
, I. W. Chiang
, K. A. Smith
, D. T. Colbert
, R. H. Hauge
, J. L. Margrave
, R. E. Smalley

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

492 Scopus citations

Abstract

Single-wall fullerene nanotubes have been made soluble in various organic solvents, including chloroform, methylene chloride, and tetrahydrofuran by covalently attaching alkanes to their sidewalls. Sidewall-alkylated nanotubes are obtained by reacting sidewall-fluorinated nanotubes with alkyl magnesium bromides in a Grignard synthesis or by reaction with alkyllithium precursors. Covalent attachment to the sidewalls was confirmed by UV-visible spectroscopy, which is also used to show that the alkane sidewall groups can be removed by oxidizing them in air to recover pristine nanotubes.

Original language	English
Pages (from-to)	367-372
Number of pages	6
Journal	Chemical Physics Letters
Volume	310
Issue number	3-4
DOIs	https://doi.org/10.1016/S0009-2614(99)00713-7
State	Published - 3 Sep 1999
Externally published	Yes

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1016/S0009-2614(99)00713-7

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title = "Reversible sidewall functionalization of buckytubes",

abstract = "Single-wall fullerene nanotubes have been made soluble in various organic solvents, including chloroform, methylene chloride, and tetrahydrofuran by covalently attaching alkanes to their sidewalls. Sidewall-alkylated nanotubes are obtained by reacting sidewall-fluorinated nanotubes with alkyl magnesium bromides in a Grignard synthesis or by reaction with alkyllithium precursors. Covalent attachment to the sidewalls was confirmed by UV-visible spectroscopy, which is also used to show that the alkane sidewall groups can be removed by oxidizing them in air to recover pristine nanotubes.",

author = "Boul, \{P. J.\} and J. Liu and Mickelson, \{E. T.\} and Huffman, \{C. B.\} and Ericson, \{L. M.\} and Chiang, \{I. W.\} and Smith, \{K. A.\} and Colbert, \{D. T.\} and Hauge, \{R. H.\} and Margrave, \{J. L.\} and Smalley, \{R. E.\}",

year = "1999",

month = sep,

day = "3",

doi = "10.1016/S0009-2614(99)00713-7",

language = "English",

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pages = "367--372",

journal = "Chemical Physics Letters",

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TY - JOUR

T1 - Reversible sidewall functionalization of buckytubes

AU - Boul, P. J.

AU - Liu, J.

AU - Mickelson, E. T.

AU - Huffman, C. B.

AU - Ericson, L. M.

AU - Chiang, I. W.

AU - Smith, K. A.

AU - Colbert, D. T.

AU - Hauge, R. H.

AU - Margrave, J. L.

AU - Smalley, R. E.

PY - 1999/9/3

Y1 - 1999/9/3

N2 - Single-wall fullerene nanotubes have been made soluble in various organic solvents, including chloroform, methylene chloride, and tetrahydrofuran by covalently attaching alkanes to their sidewalls. Sidewall-alkylated nanotubes are obtained by reacting sidewall-fluorinated nanotubes with alkyl magnesium bromides in a Grignard synthesis or by reaction with alkyllithium precursors. Covalent attachment to the sidewalls was confirmed by UV-visible spectroscopy, which is also used to show that the alkane sidewall groups can be removed by oxidizing them in air to recover pristine nanotubes.

AB - Single-wall fullerene nanotubes have been made soluble in various organic solvents, including chloroform, methylene chloride, and tetrahydrofuran by covalently attaching alkanes to their sidewalls. Sidewall-alkylated nanotubes are obtained by reacting sidewall-fluorinated nanotubes with alkyl magnesium bromides in a Grignard synthesis or by reaction with alkyllithium precursors. Covalent attachment to the sidewalls was confirmed by UV-visible spectroscopy, which is also used to show that the alkane sidewall groups can be removed by oxidizing them in air to recover pristine nanotubes.

UR - https://www.scopus.com/pages/publications/0000529299

U2 - 10.1016/S0009-2614(99)00713-7

DO - 10.1016/S0009-2614(99)00713-7

M3 - Article

AN - SCOPUS:0000529299

SN - 0009-2614

VL - 310

SP - 367

EP - 372

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 3-4

ER -

Reversible sidewall functionalization of buckytubes

Abstract

ASJC Scopus subject areas

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