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Regioselective palladium (II) catalyzed hydroesterification of alkynes and alkynols using formate esters

Research output: Contribution to journalArticlepeer-review

34 Scopus citations

Abstract

The catalytic system Pd(OAc)2/dppb/PPh3/p-TsOH Catalyzes the hydroesterification of alkynes and alkynols with formate esters to give unsaturated esters in good yields and selectivities.

Original languageEnglish
Pages (from-to)197-201
Number of pages5
JournalJournal of Molecular Catalysis A: Chemical
Volume96
Issue number3
DOIs
StatePublished - 8 Mar 1995
Externally publishedYes

Bibliographical note

Funding Information:
We are grateful to the Natural Sciences and Engineering Research Council of Canada, and to British Petroleum, for financial support.

Keywords

  • Alkynes
  • Alkynols
  • Formate esters
  • Hydroesterification
  • Palladium
  • Regioselectivity

ASJC Scopus subject areas

  • Catalysis
  • Process Chemistry and Technology
  • Physical and Theoretical Chemistry

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