Regiochemistry of mercury(II) oxide oxidation of unsymmetrical N,N-disubstituted hydroxylamines

Sk Asrof Ali; S. M.Azhar Hashmi; Mohammad N. Siddiqui; Mohammed I.M. Wazeer

doi:10.1016/0040-4020(96)00904-0

Regiochemistry of mercury(II) oxide oxidation of unsymmetrical N,N-disubstituted hydroxylamines

Sk Asrof Ali
, S. M.Azhar Hashmi
, Mohammad N. Siddiqui
, Mohammed I.M. Wazeer

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

Mercury(II) oxide oxidation of N,N-disubstituted hydroxylamines with the α and α' carbon atoms containing one and two hydrogen atoms, respectively, gave aldonitrones in a highly regioselective manner. Removal of the α proton is involved in the rate determining step as shown by primary kinetic isotope effect.

Original language	English
Pages (from-to)	14917-14928
Number of pages	12
Journal	Tetrahedron
Volume	52
Issue number	47
DOIs	https://doi.org/10.1016/0040-4020(96)00904-0
State	Published - 18 Nov 1996

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/0040-4020(96)00904-0

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title = "Regiochemistry of mercury(II) oxide oxidation of unsymmetrical N,N-disubstituted hydroxylamines",

abstract = "Mercury(II) oxide oxidation of N,N-disubstituted hydroxylamines with the α and α' carbon atoms containing one and two hydrogen atoms, respectively, gave aldonitrones in a highly regioselective manner. Removal of the α proton is involved in the rate determining step as shown by primary kinetic isotope effect.",

author = "Ali, \{Sk Asrof\} and Hashmi, \{S. M.Azhar\} and Siddiqui, \{Mohammad N.\} and Wazeer, \{Mohammed I.M.\}",

year = "1996",

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doi = "10.1016/0040-4020(96)00904-0",

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journal = "Tetrahedron",

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T1 - Regiochemistry of mercury(II) oxide oxidation of unsymmetrical N,N-disubstituted hydroxylamines

AU - Ali, Sk Asrof

AU - Hashmi, S. M.Azhar

AU - Siddiqui, Mohammad N.

AU - Wazeer, Mohammed I.M.

PY - 1996/11/18

Y1 - 1996/11/18

N2 - Mercury(II) oxide oxidation of N,N-disubstituted hydroxylamines with the α and α' carbon atoms containing one and two hydrogen atoms, respectively, gave aldonitrones in a highly regioselective manner. Removal of the α proton is involved in the rate determining step as shown by primary kinetic isotope effect.

AB - Mercury(II) oxide oxidation of N,N-disubstituted hydroxylamines with the α and α' carbon atoms containing one and two hydrogen atoms, respectively, gave aldonitrones in a highly regioselective manner. Removal of the α proton is involved in the rate determining step as shown by primary kinetic isotope effect.

UR - https://www.scopus.com/pages/publications/0030592782

U2 - 10.1016/0040-4020(96)00904-0

DO - 10.1016/0040-4020(96)00904-0

M3 - Article

AN - SCOPUS:0030592782

SN - 0040-4020

VL - 52

SP - 14917

EP - 14928

JO - Tetrahedron

JF - Tetrahedron

IS - 47

ER -

Regiochemistry of mercury(II) oxide oxidation of unsymmetrical N,N-disubstituted hydroxylamines

Abstract

ASJC Scopus subject areas

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