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Reduced viscosity, rheology and morphological properties of sulfonated poly (ether ether ketone): Polyetherimide blends

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

Blends of poly (ether ether ketone) (SPEEK) and polyetherimide (PEI) were prepared in five different weight ratios, using N,N-dimethylacetamide (DMAc) as solvent. Reduced viscosity and rheological parameters of these blends were investigated. Cannon-Fenske viscometer was used to study the viscoelastic parameters of the salt-free polyelectrolyte blends and the data obtained was fitted in Fuoss-Strauss equation. Effects of temperature and concentration have been investigated. It was observed that the storage modulus (G′) and dynamic viscosity (η′) of the blends varies significantly as compare to pure SPEEK and PEI. Surface morphology and thermal behavior of the membranes were studied using scanning electron microscopy (SEM) and differential scanning calorimetry (DSC). Form SEM results it was observed that the phase separation occurs at 25% PEI contents in blends.

Original languageEnglish
Pages (from-to)2295-2302
Number of pages8
JournalEuropean Polymer Journal
Volume47
Issue number12
DOIs
StatePublished - Dec 2011

Bibliographical note

Funding Information:
Authors would like to thank the King Abdul Aziz City for Science and Technology (KACST) through NSTIP office at the King Fahd University of Petroleum & Minerals, for funding this work under the Project ( 08-ENE53-4 ).

Keywords

  • Polyelectrolyte
  • Polyetherimide
  • Rheology
  • Sulfonated poly (ether ether ketone)
  • Viscosity

ASJC Scopus subject areas

  • General Physics and Astronomy
  • Polymers and Plastics
  • Organic Chemistry
  • Materials Chemistry

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