Reactions of 2,5-pyrrolediylbis[N-(o-hydroxyphenylaldimine)] with some metal ions

H. A. Tayim; A. S. Salameh; U. S.I. Meri

doi:10.1016/S0277-5387(00)84548-9

Reactions of 2,5-pyrrolediylbis[N-(o-hydroxyphenylaldimine)] with some metal ions

H. A. Tayim^*
, A. S. Salameh
, U. S.I. Meri

^*Corresponding author for this work

King Fahd University of Petroleum & Minerals

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

The novel Schiff-base 2,5-pyrrolediylbis[N-(o-hydroxyphenylaldimine)] (SBH₂) has been synthesized by the condensation of 2,5-pyrroledicarboxaldehyde and o-amino-phenol. The reactions of the Schiff-base with several transition- and post-transition-metal ions have been investigated. The Schiff-base reacts as a tetradentate dianion without deprotonation of the pyrrole. The complexes M(SB)·nH₂O have been isolated and characterized with n = 1, 2 or 3; SB is the dianion of the Schiff-base; and M = divalent Mn, Co, Ni, Cu, Zn, Pd, Cd, Pb or UO₂. The binuclear complexes M(SB)MX₂ for M = Cu, X = NO₃, and M = Ni or Pd, X = Cl, have also been isolated.

Original language	English
Pages (from-to)	1509-1511
Number of pages	3
Journal	Polyhedron
Volume	5
Issue number	10
DOIs	https://doi.org/10.1016/S0277-5387(00)84548-9
State	Published - 1986

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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@article{382802fd37d64a65bd4d711c93ac31a3,

title = "Reactions of 2,5-pyrrolediylbis[N-(o-hydroxyphenylaldimine)] with some metal ions",

abstract = "The novel Schiff-base 2,5-pyrrolediylbis[N-(o-hydroxyphenylaldimine)] (SBH2) has been synthesized by the condensation of 2,5-pyrroledicarboxaldehyde and o-amino-phenol. The reactions of the Schiff-base with several transition- and post-transition-metal ions have been investigated. The Schiff-base reacts as a tetradentate dianion without deprotonation of the pyrrole. The complexes M(SB)·nH2O have been isolated and characterized with n = 1, 2 or 3; SB is the dianion of the Schiff-base; and M = divalent Mn, Co, Ni, Cu, Zn, Pd, Cd, Pb or UO2. The binuclear complexes M(SB)MX2 for M = Cu, X = NO3, and M = Ni or Pd, X = Cl, have also been isolated.",

author = "Tayim, \{H. A.\} and Salameh, \{A. S.\} and Meri, \{U. S.I.\}",

year = "1986",

doi = "10.1016/S0277-5387(00)84548-9",

language = "English",

volume = "5",

pages = "1509--1511",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

number = "10",

}

TY - JOUR

T1 - Reactions of 2,5-pyrrolediylbis[N-(o-hydroxyphenylaldimine)] with some metal ions

AU - Tayim, H. A.

AU - Salameh, A. S.

AU - Meri, U. S.I.

PY - 1986

Y1 - 1986

N2 - The novel Schiff-base 2,5-pyrrolediylbis[N-(o-hydroxyphenylaldimine)] (SBH2) has been synthesized by the condensation of 2,5-pyrroledicarboxaldehyde and o-amino-phenol. The reactions of the Schiff-base with several transition- and post-transition-metal ions have been investigated. The Schiff-base reacts as a tetradentate dianion without deprotonation of the pyrrole. The complexes M(SB)·nH2O have been isolated and characterized with n = 1, 2 or 3; SB is the dianion of the Schiff-base; and M = divalent Mn, Co, Ni, Cu, Zn, Pd, Cd, Pb or UO2. The binuclear complexes M(SB)MX2 for M = Cu, X = NO3, and M = Ni or Pd, X = Cl, have also been isolated.

AB - The novel Schiff-base 2,5-pyrrolediylbis[N-(o-hydroxyphenylaldimine)] (SBH2) has been synthesized by the condensation of 2,5-pyrroledicarboxaldehyde and o-amino-phenol. The reactions of the Schiff-base with several transition- and post-transition-metal ions have been investigated. The Schiff-base reacts as a tetradentate dianion without deprotonation of the pyrrole. The complexes M(SB)·nH2O have been isolated and characterized with n = 1, 2 or 3; SB is the dianion of the Schiff-base; and M = divalent Mn, Co, Ni, Cu, Zn, Pd, Cd, Pb or UO2. The binuclear complexes M(SB)MX2 for M = Cu, X = NO3, and M = Ni or Pd, X = Cl, have also been isolated.

UR - https://www.scopus.com/pages/publications/0040773372

U2 - 10.1016/S0277-5387(00)84548-9

DO - 10.1016/S0277-5387(00)84548-9

M3 - Article

AN - SCOPUS:0040773372

SN - 0277-5387

VL - 5

SP - 1509

EP - 1511

JO - Polyhedron

JF - Polyhedron

IS - 10

ER -

Reactions of 2,5-pyrrolediylbis[N-(o-hydroxyphenylaldimine)] with some metal ions

Abstract

ASJC Scopus subject areas

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