Reactions of 2-thiazolin-2-ylthiophene with some metal ions

H. A. Tayim; A. S. Salameh

doi:10.1016/S0277-5387(00)81461-8

Reactions of 2-thiazolin-2-ylthiophene with some metal ions

H. A. Tayim^*
, A. S. Salameh

^*Corresponding author for this work

King Fahd University of Petroleum & Minerals

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

The condensation of o-aminobenzenthiol with 2-thiophenecarboxaldehyde yields 2-thiazolin-2-ylthiophene rather than the expected Schiff base. However, upon reaction with metal ions, the thiazoline rearranges to the expected thiolate Schiff base. Complexes of the Schiff base with Ni(II), Cu(II), Zn, Cd, Pb(II), Ag(I) and Pd(II) have been isolated and characterized.

Original language	English
Pages (from-to)	1091-1094
Number of pages	4
Journal	Polyhedron
Volume	2
Issue number	10
DOIs	https://doi.org/10.1016/S0277-5387(00)81461-8
State	Published - 1983

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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title = "Reactions of 2-thiazolin-2-ylthiophene with some metal ions",

abstract = "The condensation of o-aminobenzenthiol with 2-thiophenecarboxaldehyde yields 2-thiazolin-2-ylthiophene rather than the expected Schiff base. However, upon reaction with metal ions, the thiazoline rearranges to the expected thiolate Schiff base. Complexes of the Schiff base with Ni(II), Cu(II), Zn, Cd, Pb(II), Ag(I) and Pd(II) have been isolated and characterized.",

author = "Tayim, \{H. A.\} and Salameh, \{A. S.\}",

year = "1983",

doi = "10.1016/S0277-5387(00)81461-8",

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volume = "2",

pages = "1091--1094",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

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TY - JOUR

T1 - Reactions of 2-thiazolin-2-ylthiophene with some metal ions

AU - Tayim, H. A.

AU - Salameh, A. S.

PY - 1983

Y1 - 1983

N2 - The condensation of o-aminobenzenthiol with 2-thiophenecarboxaldehyde yields 2-thiazolin-2-ylthiophene rather than the expected Schiff base. However, upon reaction with metal ions, the thiazoline rearranges to the expected thiolate Schiff base. Complexes of the Schiff base with Ni(II), Cu(II), Zn, Cd, Pb(II), Ag(I) and Pd(II) have been isolated and characterized.

AB - The condensation of o-aminobenzenthiol with 2-thiophenecarboxaldehyde yields 2-thiazolin-2-ylthiophene rather than the expected Schiff base. However, upon reaction with metal ions, the thiazoline rearranges to the expected thiolate Schiff base. Complexes of the Schiff base with Ni(II), Cu(II), Zn, Cd, Pb(II), Ag(I) and Pd(II) have been isolated and characterized.

UR - https://www.scopus.com/pages/publications/33746352868

U2 - 10.1016/S0277-5387(00)81461-8

DO - 10.1016/S0277-5387(00)81461-8

M3 - Article

AN - SCOPUS:33746352868

SN - 0277-5387

VL - 2

SP - 1091

EP - 1094

JO - Polyhedron

JF - Polyhedron

IS - 10

ER -

Reactions of 2-thiazolin-2-ylthiophene with some metal ions

Abstract

ASJC Scopus subject areas

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