@inproceedings{7eaa5d205d6d4029a0a9a583ed28a69e,
title = "Quantum-dynamical modeling of the rydberg to valence excited-state internal conversion in cyclobutanone and cyclopentanone",
abstract = "In this paper we present 4-state, 5-dimensional Vibronic Coupling Hamiltonians for cyclobutanone and cyclopentanone. Wave packet calculations using these Hamiltonians reveal that for cyclobutanone the (n,3s) to (n,π*) internal conversion involves direct motion in nuclear modes coupling the two states leading to fast population transfer. For cyclopentanone, internal vibrational energy redistribution is a bottleneck for activating reactive nuclear modes leading to slower population transfer.",
author = "Kuhlman, \{T. S.\} and Sauer, \{S. P.A.\} and S{\o}lling, \{T. I.\} and M{\o}ller, \{K. B.\}",
year = "2013",
doi = "10.1051/epjconf/20134102033",
language = "English",
isbn = "9782759809561",
series = "EPJ Web of Conferences",
booktitle = "18th International Conference on Ultrafast Phenomena, UP 2012",
}