Probing the use of silane-grafted fumed silica nanoparticles to produce stable transformer oil-based nanofluids

In this experimental investigation, hydrophobic silane-grafted fumed nano-silica was employed in transformer oil to formulate nanofluids (NFs). A cold-air atmosphere-pressure plasma reactor working on the principle of dielectric barrier discharge was designed and utilized to functionalize the surface of these nanoparticles. A field emission scanning electron microscope (FE-SEM) coupled with energy-dispersive X-ray (EDX) module and Fourier transform infrared (FTIR) spectroscopy were used to scan surface features of new and plasma-treated nanoparticles. The study revealed considerable changes in the surface chemistry of nanoparticles, which led to good dispersibility and stability of nanofluids. The measurements of AC breakdown voltages (AC-BDV) of nanofluids so prepared were conducted according to IEC-Std 60156, and a significant improvement in the dielectric strength was achieved. A statistical analysis of these results was performed using Weibull probabilistic law. At a 5% probability of failure, modified nanofluid remarkably exhibited a 60% increase in breakdown voltage. The dielectric properties such as variation of ε_r and tan δ in temperature of up to 70^◦ C were measured and compared with untreated fluid. Results exhibit an increase in tan δ and a slight decrease in permittivity of nanofluids. The analysis also revealed that while unpolar silane coating of NPs increased the breakdown strength, the polar-amino-silane-coated NPs in oil resulted in a drastic reduction. Details of this antagonistic trend are elaborated in this paper.