Preparation, identification, and X-ray structure of a novel high-nuclearity heterometallic anionic Ag6Cu7 cluster

Omar M. Abu-Salah; M. Sakhawat Hussain; Elmer O. Schlemper

doi:10.1039/C39880000212

Preparation, identification, and X-ray structure of a novel high-nuclearity heterometallic anionic Ag₆Cu₇ cluster

Omar M. Abu-Salah, M. Sakhawat Hussain^*, Elmer O. Schlemper

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

A novel silver-copper anionic cluster [Ag₆Cu₇(C ₂Ph)₁₄]^- has been synthesized from the reaction of [PhC₂AgC₂Ph]^- and a mixture of [AgC ₂Ph]_n and [CuC₂Ph]_n; its structure constitutes a central linearly co-ordinated copper atom linked through Cu-Ag interactions to three tetranuclear [Ag₂Cu₂(C ₂Ph)₄] subclusters, and within each unit of the sub-cluster, copper and silver atoms are bonded through metal-metal interactions and via bridged phenylethynyl ligands.

Original language	English
Pages (from-to)	212-213
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	3
DOIs	https://doi.org/10.1039/C39880000212
State	Published - 1988
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

Access to Document

10.1039/C39880000212

Cite this

@article{1791014ac5a24710818888a354b42cd0,

title = "Preparation, identification, and X-ray structure of a novel high-nuclearity heterometallic anionic Ag6Cu7 cluster",

abstract = "A novel silver-copper anionic cluster [Ag6Cu7(C 2Ph)14]- has been synthesized from the reaction of [PhC2AgC2Ph]- and a mixture of [AgC 2Ph]n and [CuC2Ph]n; its structure constitutes a central linearly co-ordinated copper atom linked through Cu-Ag interactions to three tetranuclear [Ag2Cu2(C 2Ph)4] subclusters, and within each unit of the sub-cluster, copper and silver atoms are bonded through metal-metal interactions and via bridged phenylethynyl ligands.",

author = "Abu-Salah, \{Omar M.\} and Hussain, \{M. Sakhawat\} and Schlemper, \{Elmer O.\}",

year = "1988",

doi = "10.1039/C39880000212",

language = "English",

pages = "212--213",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

number = "3",

}

TY - JOUR

T1 - Preparation, identification, and X-ray structure of a novel high-nuclearity heterometallic anionic Ag6Cu7 cluster

AU - Abu-Salah, Omar M.

AU - Hussain, M. Sakhawat

AU - Schlemper, Elmer O.

PY - 1988

Y1 - 1988

N2 - A novel silver-copper anionic cluster [Ag6Cu7(C 2Ph)14]- has been synthesized from the reaction of [PhC2AgC2Ph]- and a mixture of [AgC 2Ph]n and [CuC2Ph]n; its structure constitutes a central linearly co-ordinated copper atom linked through Cu-Ag interactions to three tetranuclear [Ag2Cu2(C 2Ph)4] subclusters, and within each unit of the sub-cluster, copper and silver atoms are bonded through metal-metal interactions and via bridged phenylethynyl ligands.

AB - A novel silver-copper anionic cluster [Ag6Cu7(C 2Ph)14]- has been synthesized from the reaction of [PhC2AgC2Ph]- and a mixture of [AgC 2Ph]n and [CuC2Ph]n; its structure constitutes a central linearly co-ordinated copper atom linked through Cu-Ag interactions to three tetranuclear [Ag2Cu2(C 2Ph)4] subclusters, and within each unit of the sub-cluster, copper and silver atoms are bonded through metal-metal interactions and via bridged phenylethynyl ligands.

UR - https://www.scopus.com/pages/publications/31444455509

U2 - 10.1039/C39880000212

DO - 10.1039/C39880000212

M3 - Article

AN - SCOPUS:31444455509

SN - 0022-4936

SP - 212

EP - 213

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 3