Preparation, characterizations and its application of heterogeneous Fenton catalyst for the treatment of synthetic phenol solution

S. Karthikeyan; R. Boopathy; V. K. Gupta; G. Sekaran

doi:10.1016/j.molliq.2012.10.011

Preparation, characterizations and its application of heterogeneous Fenton catalyst for the treatment of synthetic phenol solution

S. Karthikeyan
, R. Boopathy
, V. K. Gupta
, G. Sekaran^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

32 Scopus citations

Abstract

Fe-Co-Al trimetal oxide (TMO) was prepared by the sol-gel route for the oxidation of phenol solution by catalytic wet peroxide oxidation (CWPO) method. The characteristic of Fe-Co-Al was carried out. The size of the catalyst was found to be between 1 and 5 μm with good porosity which was confirmed using scanning electron microscopy (SEM), transmission electron microscopy (TEM) and N₂ adsorption-desorption isotherms. The catalytic activity results showed almost complete oxidation of phenol up to 1000 mg/L. The oxidation process and the products formed were confirmed using various instrumental analyses. The TMO catalyst could be reused even after three cycles very effectively.

Original language	English
Pages (from-to)	402-408
Number of pages	7
Journal	Journal of Molecular Liquids
Volume	177
DOIs	https://doi.org/10.1016/j.molliq.2012.10.011
State	Published - Jan 2013
Externally published	Yes

Bibliographical note

Funding Information:
The author S. Karthikeyan is thankful to Central Leather Research Institute (CLRI) for providing the facilities to carry out the work and Council of Scientific and Industrial Research (CSIR) for awarding the senior research fellowship.

Keywords

CWPO
Heterogeneous Fenton-type catalyst
Hydrogen peroxide
Phenol
Sol-gel method

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Spectroscopy
Physical and Theoretical Chemistry
Materials Chemistry

Access to Document

10.1016/j.molliq.2012.10.011

Cite this

@article{81fb6f6d395c4dbc854f780c282b6d9b,

title = "Preparation, characterizations and its application of heterogeneous Fenton catalyst for the treatment of synthetic phenol solution",

abstract = "Fe-Co-Al trimetal oxide (TMO) was prepared by the sol-gel route for the oxidation of phenol solution by catalytic wet peroxide oxidation (CWPO) method. The characteristic of Fe-Co-Al was carried out. The size of the catalyst was found to be between 1 and 5 μm with good porosity which was confirmed using scanning electron microscopy (SEM), transmission electron microscopy (TEM) and N2 adsorption-desorption isotherms. The catalytic activity results showed almost complete oxidation of phenol up to 1000 mg/L. The oxidation process and the products formed were confirmed using various instrumental analyses. The TMO catalyst could be reused even after three cycles very effectively.",

keywords = "CWPO, Heterogeneous Fenton-type catalyst, Hydrogen peroxide, Phenol, Sol-gel method",

author = "S. Karthikeyan and R. Boopathy and Gupta, \{V. K.\} and G. Sekaran",

note = "Funding Information: The author S. Karthikeyan is thankful to Central Leather Research Institute (CLRI) for providing the facilities to carry out the work and Council of Scientific and Industrial Research (CSIR) for awarding the senior research fellowship. ",

year = "2013",

month = jan,

doi = "10.1016/j.molliq.2012.10.011",

language = "English",

volume = "177",

pages = "402--408",

journal = "Journal of Molecular Liquids",

issn = "0167-7322",

publisher = "Elsevier BV",

}

TY - JOUR

T1 - Preparation, characterizations and its application of heterogeneous Fenton catalyst for the treatment of synthetic phenol solution

AU - Karthikeyan, S.

AU - Boopathy, R.

AU - Gupta, V. K.

AU - Sekaran, G.

N1 - Funding Information: The author S. Karthikeyan is thankful to Central Leather Research Institute (CLRI) for providing the facilities to carry out the work and Council of Scientific and Industrial Research (CSIR) for awarding the senior research fellowship.

PY - 2013/1

Y1 - 2013/1

N2 - Fe-Co-Al trimetal oxide (TMO) was prepared by the sol-gel route for the oxidation of phenol solution by catalytic wet peroxide oxidation (CWPO) method. The characteristic of Fe-Co-Al was carried out. The size of the catalyst was found to be between 1 and 5 μm with good porosity which was confirmed using scanning electron microscopy (SEM), transmission electron microscopy (TEM) and N2 adsorption-desorption isotherms. The catalytic activity results showed almost complete oxidation of phenol up to 1000 mg/L. The oxidation process and the products formed were confirmed using various instrumental analyses. The TMO catalyst could be reused even after three cycles very effectively.

AB - Fe-Co-Al trimetal oxide (TMO) was prepared by the sol-gel route for the oxidation of phenol solution by catalytic wet peroxide oxidation (CWPO) method. The characteristic of Fe-Co-Al was carried out. The size of the catalyst was found to be between 1 and 5 μm with good porosity which was confirmed using scanning electron microscopy (SEM), transmission electron microscopy (TEM) and N2 adsorption-desorption isotherms. The catalytic activity results showed almost complete oxidation of phenol up to 1000 mg/L. The oxidation process and the products formed were confirmed using various instrumental analyses. The TMO catalyst could be reused even after three cycles very effectively.

KW - CWPO

KW - Heterogeneous Fenton-type catalyst

KW - Hydrogen peroxide

KW - Phenol

KW - Sol-gel method

UR - https://www.scopus.com/pages/publications/84870683881

U2 - 10.1016/j.molliq.2012.10.011

DO - 10.1016/j.molliq.2012.10.011

M3 - Article

AN - SCOPUS:84870683881

SN - 0167-7322

VL - 177

SP - 402

EP - 408

JO - Journal of Molecular Liquids

JF - Journal of Molecular Liquids

ER -

Preparation, characterizations and its application of heterogeneous Fenton catalyst for the treatment of synthetic phenol solution

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

Access to Document

Fingerprint

Cite this