Preparation and properties of crosslinkable waterborne polyurethanes containing aminoplast - Effect of curing condition

Ji Yun Kwon; Mohammad Mizanur Rahman; Han Do Kim

doi:10.1007/BF02908252

Preparation and properties of crosslinkable waterborne polyurethanes containing aminoplast - Effect of curing condition

Ji Yun Kwon
, Mohammad Mizanur Rahman
, Han Do Kim^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

In order to improve the water swelling, thermal/mechanical and adhesion properties of waterborne polyurethane (WBPU), a series of the crosslinkable WBPUs containing hydrophilic ionic component, dimethylol propionic acid (20 mole%), were prepared by in-situ polymerization using a cross-linker hexakis (methoxymethyl) melamine (HMMM). Effects of the HMMM content (2, 4, and 6 wt%) and curing temperature on these properties of the crosslinked WBPUs samples were investigated. All properties were found to increase with increasing HMMM content. It was found that the optimum curing temperature of the WBPU films and adhesives was near 120°C, which was not dependent on the HMMM content.

Original language	English
Pages (from-to)	95-104
Number of pages	10
Journal	Fibers and Polymers
Volume	7
Issue number	2
DOIs	https://doi.org/10.1007/BF02908252
State	Published - Jun 2006
Externally published	Yes

Keywords

Aminoplast
Crosslinking
Curing temperature
Waterborne-polyurethanes

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering
Polymers and Plastics

Access to Document

10.1007/BF02908252

Cite this

@article{cadf3e3f26d34d33a73093a2883e87fd,

title = "Preparation and properties of crosslinkable waterborne polyurethanes containing aminoplast - Effect of curing condition",

abstract = "In order to improve the water swelling, thermal/mechanical and adhesion properties of waterborne polyurethane (WBPU), a series of the crosslinkable WBPUs containing hydrophilic ionic component, dimethylol propionic acid (20 mole\%), were prepared by in-situ polymerization using a cross-linker hexakis (methoxymethyl) melamine (HMMM). Effects of the HMMM content (2, 4, and 6 wt\%) and curing temperature on these properties of the crosslinked WBPUs samples were investigated. All properties were found to increase with increasing HMMM content. It was found that the optimum curing temperature of the WBPU films and adhesives was near 120°C, which was not dependent on the HMMM content.",

keywords = "Aminoplast, Crosslinking, Curing temperature, Waterborne-polyurethanes",

author = "Kwon, \{Ji Yun\} and Rahman, \{Mohammad Mizanur\} and Kim, \{Han Do\}",

year = "2006",

month = jun,

doi = "10.1007/BF02908252",

language = "English",

volume = "7",

pages = "95--104",

journal = "Fibers and Polymers",

issn = "1229-9197",

number = "2",

}

TY - JOUR

T1 - Preparation and properties of crosslinkable waterborne polyurethanes containing aminoplast - Effect of curing condition

AU - Kwon, Ji Yun

AU - Rahman, Mohammad Mizanur

AU - Kim, Han Do

PY - 2006/6

Y1 - 2006/6

N2 - In order to improve the water swelling, thermal/mechanical and adhesion properties of waterborne polyurethane (WBPU), a series of the crosslinkable WBPUs containing hydrophilic ionic component, dimethylol propionic acid (20 mole%), were prepared by in-situ polymerization using a cross-linker hexakis (methoxymethyl) melamine (HMMM). Effects of the HMMM content (2, 4, and 6 wt%) and curing temperature on these properties of the crosslinked WBPUs samples were investigated. All properties were found to increase with increasing HMMM content. It was found that the optimum curing temperature of the WBPU films and adhesives was near 120°C, which was not dependent on the HMMM content.

AB - In order to improve the water swelling, thermal/mechanical and adhesion properties of waterborne polyurethane (WBPU), a series of the crosslinkable WBPUs containing hydrophilic ionic component, dimethylol propionic acid (20 mole%), were prepared by in-situ polymerization using a cross-linker hexakis (methoxymethyl) melamine (HMMM). Effects of the HMMM content (2, 4, and 6 wt%) and curing temperature on these properties of the crosslinked WBPUs samples were investigated. All properties were found to increase with increasing HMMM content. It was found that the optimum curing temperature of the WBPU films and adhesives was near 120°C, which was not dependent on the HMMM content.

KW - Aminoplast

KW - Crosslinking

KW - Curing temperature

KW - Waterborne-polyurethanes

UR - https://www.scopus.com/pages/publications/33746393243

U2 - 10.1007/BF02908252

DO - 10.1007/BF02908252

M3 - Article

AN - SCOPUS:33746393243

SN - 1229-9197

VL - 7

SP - 95

EP - 104

JO - Fibers and Polymers

JF - Fibers and Polymers

IS - 2

ER -

Preparation and properties of crosslinkable waterborne polyurethanes containing aminoplast - Effect of curing condition

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Fingerprint

Cite this