Porous Anodic Aluminum Oxide as an Efficient Support for Ruthenium-Catalyzed Aerobic Oxidation of Alcohols and Amines

Muhammad Asif Hussain; Mobina Irshad; Ehsan Ul Haq; Sungho Park; Muhammad Atif; Abbas Saeed Hakeem; Bong Gill Choi; Jung Won Kim

doi:10.1021/acs.iecr.9b06054

Porous Anodic Aluminum Oxide as an Efficient Support for Ruthenium-Catalyzed Aerobic Oxidation of Alcohols and Amines

Muhammad Asif Hussain^*, Mobina Irshad, Ehsan Ul Haq, Sungho Park, Muhammad Atif, Abbas Saeed Hakeem, Bong Gill Choi, Jung Won Kim

^*Corresponding author for this work

Interdisciplinary Research Center for Hydrogen Technologies and Carbon Management

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The oxidation reactions of alcohols and amines to their respective aldehydes/ketones and nitriles are important reactions in the laboratory and industry. A highly robust and activated ruthenium-supported anodic aluminum oxide (Ru@AAO) has been synthesized through the sonochemical method. The sonochemical technique allowed a short synthesis time and uniform distribution of Ru on the AAO surface as confirmed by the scanning electron microscopy, transmission electron microscopy, X-ray diffraction analysis, and BET surface-area analysis. The synthesized catalyst was employed for the oxidation of alcohols and amines in the presence of atmospheric air at a relatively lower temperature. The synthesized catalyst showed excellent conversions of both alcohols and amines with high selectivities toward their respective aldehydes/ketones and nitriles. The function of the AAO support in Ru@AAO catalytic activity has also been elaborated in the present investigation.

Original language	English
Pages (from-to)	23025-23031
Number of pages	7
Journal	Industrial and Engineering Chemistry Research
Volume	58
Issue number	51
DOIs	https://doi.org/10.1021/acs.iecr.9b06054
State	Published - 26 Dec 2019

Bibliographical note

Publisher Copyright:
Copyright © 2019 American Chemical Society.

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering

Access to Document

10.1021/acs.iecr.9b06054

Cite this

@article{52063e26d656404cbbbce9f64068069a,

title = "Porous Anodic Aluminum Oxide as an Efficient Support for Ruthenium-Catalyzed Aerobic Oxidation of Alcohols and Amines",

abstract = "The oxidation reactions of alcohols and amines to their respective aldehydes/ketones and nitriles are important reactions in the laboratory and industry. A highly robust and activated ruthenium-supported anodic aluminum oxide (Ru@AAO) has been synthesized through the sonochemical method. The sonochemical technique allowed a short synthesis time and uniform distribution of Ru on the AAO surface as confirmed by the scanning electron microscopy, transmission electron microscopy, X-ray diffraction analysis, and BET surface-area analysis. The synthesized catalyst was employed for the oxidation of alcohols and amines in the presence of atmospheric air at a relatively lower temperature. The synthesized catalyst showed excellent conversions of both alcohols and amines with high selectivities toward their respective aldehydes/ketones and nitriles. The function of the AAO support in Ru@AAO catalytic activity has also been elaborated in the present investigation.",

author = "Hussain, {Muhammad Asif} and Mobina Irshad and Haq, {Ehsan Ul} and Sungho Park and Muhammad Atif and Hakeem, {Abbas Saeed} and Choi, {Bong Gill} and Kim, {Jung Won}",

note = "Publisher Copyright: Copyright {\textcopyright} 2019 American Chemical Society.",

year = "2019",

month = dec,

day = "26",

doi = "10.1021/acs.iecr.9b06054",

language = "English",

volume = "58",

pages = "23025--23031",

journal = "Industrial and Engineering Chemistry Research",

issn = "0888-5885",

number = "51",

}

TY - JOUR

T1 - Porous Anodic Aluminum Oxide as an Efficient Support for Ruthenium-Catalyzed Aerobic Oxidation of Alcohols and Amines

AU - Hussain, Muhammad Asif

AU - Irshad, Mobina

AU - Haq, Ehsan Ul

AU - Park, Sungho

AU - Atif, Muhammad

AU - Hakeem, Abbas Saeed

AU - Choi, Bong Gill

AU - Kim, Jung Won

PY - 2019/12/26

Y1 - 2019/12/26

N2 - The oxidation reactions of alcohols and amines to their respective aldehydes/ketones and nitriles are important reactions in the laboratory and industry. A highly robust and activated ruthenium-supported anodic aluminum oxide (Ru@AAO) has been synthesized through the sonochemical method. The sonochemical technique allowed a short synthesis time and uniform distribution of Ru on the AAO surface as confirmed by the scanning electron microscopy, transmission electron microscopy, X-ray diffraction analysis, and BET surface-area analysis. The synthesized catalyst was employed for the oxidation of alcohols and amines in the presence of atmospheric air at a relatively lower temperature. The synthesized catalyst showed excellent conversions of both alcohols and amines with high selectivities toward their respective aldehydes/ketones and nitriles. The function of the AAO support in Ru@AAO catalytic activity has also been elaborated in the present investigation.

AB - The oxidation reactions of alcohols and amines to their respective aldehydes/ketones and nitriles are important reactions in the laboratory and industry. A highly robust and activated ruthenium-supported anodic aluminum oxide (Ru@AAO) has been synthesized through the sonochemical method. The sonochemical technique allowed a short synthesis time and uniform distribution of Ru on the AAO surface as confirmed by the scanning electron microscopy, transmission electron microscopy, X-ray diffraction analysis, and BET surface-area analysis. The synthesized catalyst was employed for the oxidation of alcohols and amines in the presence of atmospheric air at a relatively lower temperature. The synthesized catalyst showed excellent conversions of both alcohols and amines with high selectivities toward their respective aldehydes/ketones and nitriles. The function of the AAO support in Ru@AAO catalytic activity has also been elaborated in the present investigation.

UR - http://www.scopus.com/inward/record.url?scp=85076536544&partnerID=8YFLogxK

U2 - 10.1021/acs.iecr.9b06054

DO - 10.1021/acs.iecr.9b06054

M3 - Article

AN - SCOPUS:85076536544

SN - 0888-5885

VL - 58

SP - 23025

EP - 23031

JO - Industrial and Engineering Chemistry Research

JF - Industrial and Engineering Chemistry Research

IS - 51

ER -

Porous Anodic Aluminum Oxide as an Efficient Support for Ruthenium-Catalyzed Aerobic Oxidation of Alcohols and Amines

Abstract

Bibliographical note

ASJC Scopus subject areas

Access to Document

Fingerprint

Cite this