Polymerization of functionalized diallyl quaternary ammonium salt to poly(ampholyte-electrolyte)

M. M. Ali; H. P. Perzanowski; Sk A. Ali

doi:10.1016/S0032-3861(99)00764-8

Polymerization of functionalized diallyl quaternary ammonium salt to poly(ampholyte-electrolyte)

M. M. Ali, H. P. Perzanowski, Sk A. Ali

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

The quaternary ammonium salt, N,N-diallyl-N-carboethoxymethyl-N- carbomethoxypentylammonium chloride 13, on polymerization in aqueous solution using tert-butylhydroperoxide, afforded the polyelectrolyte 14. The copolymer 15 of the monomer 13 and sulfur dioxide was synthesized in excellent yield. The polyelectrolytes 14 and 15 on acidic hydrolysis gave the poly(ampholyte-electrolytes) 16 and 17 which contain structural features common to both polyampholytes and conventional polyelectrolytes. The solution properties of these polymers are discussed in detail. The poly(ampholyte-electrolyte)s, 16 and 17 are shown to have considerably higher viscosity than their corresponding polyelectrolytes 14 and 15. (C) 2000 Elsevier Science Ltd. All rights reserved.

Original language	English
Pages (from-to)	5591-5600
Number of pages	10
Journal	Polymer
Volume	41
Issue number	15
DOIs	https://doi.org/10.1016/S0032-3861(99)00764-8
State	Published - Jul 2000

Keywords

Poly(quaternary ammonium salt)
Polyampholyte
Polyelectrolyte

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Materials Chemistry

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10.1016/S0032-3861(99)00764-8

Cite this

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title = "Polymerization of functionalized diallyl quaternary ammonium salt to poly(ampholyte-electrolyte)",

abstract = "The quaternary ammonium salt, N,N-diallyl-N-carboethoxymethyl-N- carbomethoxypentylammonium chloride 13, on polymerization in aqueous solution using tert-butylhydroperoxide, afforded the polyelectrolyte 14. The copolymer 15 of the monomer 13 and sulfur dioxide was synthesized in excellent yield. The polyelectrolytes 14 and 15 on acidic hydrolysis gave the poly(ampholyte-electrolytes) 16 and 17 which contain structural features common to both polyampholytes and conventional polyelectrolytes. The solution properties of these polymers are discussed in detail. The poly(ampholyte-electrolyte)s, 16 and 17 are shown to have considerably higher viscosity than their corresponding polyelectrolytes 14 and 15. (C) 2000 Elsevier Science Ltd. All rights reserved.",

keywords = "Poly(quaternary ammonium salt), Polyampholyte, Polyelectrolyte",

author = "Ali, \{M. M.\} and Perzanowski, \{H. P.\} and Ali, \{Sk A.\}",

year = "2000",

month = jul,

doi = "10.1016/S0032-3861(99)00764-8",

language = "English",

volume = "41",

pages = "5591--5600",

journal = "Polymer",

issn = "0032-3861",

number = "15",

}

TY - JOUR

T1 - Polymerization of functionalized diallyl quaternary ammonium salt to poly(ampholyte-electrolyte)

AU - Ali, M. M.

AU - Perzanowski, H. P.

AU - Ali, Sk A.

PY - 2000/7

Y1 - 2000/7

N2 - The quaternary ammonium salt, N,N-diallyl-N-carboethoxymethyl-N- carbomethoxypentylammonium chloride 13, on polymerization in aqueous solution using tert-butylhydroperoxide, afforded the polyelectrolyte 14. The copolymer 15 of the monomer 13 and sulfur dioxide was synthesized in excellent yield. The polyelectrolytes 14 and 15 on acidic hydrolysis gave the poly(ampholyte-electrolytes) 16 and 17 which contain structural features common to both polyampholytes and conventional polyelectrolytes. The solution properties of these polymers are discussed in detail. The poly(ampholyte-electrolyte)s, 16 and 17 are shown to have considerably higher viscosity than their corresponding polyelectrolytes 14 and 15. (C) 2000 Elsevier Science Ltd. All rights reserved.

AB - The quaternary ammonium salt, N,N-diallyl-N-carboethoxymethyl-N- carbomethoxypentylammonium chloride 13, on polymerization in aqueous solution using tert-butylhydroperoxide, afforded the polyelectrolyte 14. The copolymer 15 of the monomer 13 and sulfur dioxide was synthesized in excellent yield. The polyelectrolytes 14 and 15 on acidic hydrolysis gave the poly(ampholyte-electrolytes) 16 and 17 which contain structural features common to both polyampholytes and conventional polyelectrolytes. The solution properties of these polymers are discussed in detail. The poly(ampholyte-electrolyte)s, 16 and 17 are shown to have considerably higher viscosity than their corresponding polyelectrolytes 14 and 15. (C) 2000 Elsevier Science Ltd. All rights reserved.

KW - Poly(quaternary ammonium salt)

KW - Polyampholyte

KW - Polyelectrolyte

UR - https://www.scopus.com/pages/publications/0342313468

U2 - 10.1016/S0032-3861(99)00764-8

DO - 10.1016/S0032-3861(99)00764-8

M3 - Article

AN - SCOPUS:0342313468

SN - 0032-3861

VL - 41

SP - 5591

EP - 5600

JO - Polymer

JF - Polymer

IS - 15

ER -

Polymerization of functionalized diallyl quaternary ammonium salt to poly(ampholyte-electrolyte)

Abstract

Keywords

ASJC Scopus subject areas

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