Poly(m-phenylendiamine-co-o-aminophenol) coatings on mild steel: Effect of comonomers feed ratio on surface and corrosion protection aspects

A. Madhankumar; N. Rajendran

doi:10.1016/j.porgcoat.2013.05.033

Poly(m-phenylendiamine-co-o-aminophenol) coatings on mild steel: Effect of comonomers feed ratio on surface and corrosion protection aspects

A. Madhankumar
, N. Rajendran^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

Copolymer of m-phenylendiamine (mPD) and o-aminophenol (oAP) has been electrochemically deposited on mild steel from an aqueous solution of oxalic acid using cyclic voltammetric technique. The copolymer structure was confirmed by Proton Nuclear Magnetic Resonance (¹H NMR) and Attenuated Total Reflection Infrared (ATR-IR) spectroscopic techniques. Surface characterisation results indicated that the formed copolymer coatings posses uniform, smooth surface and strong adherence towards the metal surface. Corrosion performance of copolymer coatings was investigated in 0.5 M HCl solution using potentiodynamic polarisation and electrochemical impedance spectroscopy (EIS) methods. Results showed that corrosion performance of copolymer coatings depends on the feed ratio of both the monomer units in copolymer chain. It was found that the copolymer feed ratio of mPD:oAP = 70/30 in coatings exhibited the highest performance due to its superior surface nature than other copolymer coatings.

Original language	English
Pages (from-to)	1445-1453
Number of pages	9
Journal	Progress in Organic Coatings
Volume	76
Issue number	10
DOIs	https://doi.org/10.1016/j.porgcoat.2013.05.033
State	Published - Oct 2013
Externally published	Yes

Keywords

AFM
Corrosion
EIS
Polymer coatings
Porosity
Surface

ASJC Scopus subject areas

General Chemical Engineering
Surfaces, Coatings and Films
Organic Chemistry
Materials Chemistry

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10.1016/j.porgcoat.2013.05.033

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title = "Poly(m-phenylendiamine-co-o-aminophenol) coatings on mild steel: Effect of comonomers feed ratio on surface and corrosion protection aspects",

abstract = "Copolymer of m-phenylendiamine (mPD) and o-aminophenol (oAP) has been electrochemically deposited on mild steel from an aqueous solution of oxalic acid using cyclic voltammetric technique. The copolymer structure was confirmed by Proton Nuclear Magnetic Resonance (1H NMR) and Attenuated Total Reflection Infrared (ATR-IR) spectroscopic techniques. Surface characterisation results indicated that the formed copolymer coatings posses uniform, smooth surface and strong adherence towards the metal surface. Corrosion performance of copolymer coatings was investigated in 0.5 M HCl solution using potentiodynamic polarisation and electrochemical impedance spectroscopy (EIS) methods. Results showed that corrosion performance of copolymer coatings depends on the feed ratio of both the monomer units in copolymer chain. It was found that the copolymer feed ratio of mPD:oAP = 70/30 in coatings exhibited the highest performance due to its superior surface nature than other copolymer coatings.",

keywords = "AFM, Corrosion, EIS, Polymer coatings, Porosity, Surface",

author = "A. Madhankumar and N. Rajendran",

year = "2013",

month = oct,

doi = "10.1016/j.porgcoat.2013.05.033",

language = "English",

volume = "76",

pages = "1445--1453",

journal = "Progress in Organic Coatings",

issn = "0300-9440",

publisher = "Elsevier",

number = "10",

}

TY - JOUR

T1 - Poly(m-phenylendiamine-co-o-aminophenol) coatings on mild steel

T2 - Effect of comonomers feed ratio on surface and corrosion protection aspects

AU - Madhankumar, A.

AU - Rajendran, N.

PY - 2013/10

Y1 - 2013/10

N2 - Copolymer of m-phenylendiamine (mPD) and o-aminophenol (oAP) has been electrochemically deposited on mild steel from an aqueous solution of oxalic acid using cyclic voltammetric technique. The copolymer structure was confirmed by Proton Nuclear Magnetic Resonance (1H NMR) and Attenuated Total Reflection Infrared (ATR-IR) spectroscopic techniques. Surface characterisation results indicated that the formed copolymer coatings posses uniform, smooth surface and strong adherence towards the metal surface. Corrosion performance of copolymer coatings was investigated in 0.5 M HCl solution using potentiodynamic polarisation and electrochemical impedance spectroscopy (EIS) methods. Results showed that corrosion performance of copolymer coatings depends on the feed ratio of both the monomer units in copolymer chain. It was found that the copolymer feed ratio of mPD:oAP = 70/30 in coatings exhibited the highest performance due to its superior surface nature than other copolymer coatings.

AB - Copolymer of m-phenylendiamine (mPD) and o-aminophenol (oAP) has been electrochemically deposited on mild steel from an aqueous solution of oxalic acid using cyclic voltammetric technique. The copolymer structure was confirmed by Proton Nuclear Magnetic Resonance (1H NMR) and Attenuated Total Reflection Infrared (ATR-IR) spectroscopic techniques. Surface characterisation results indicated that the formed copolymer coatings posses uniform, smooth surface and strong adherence towards the metal surface. Corrosion performance of copolymer coatings was investigated in 0.5 M HCl solution using potentiodynamic polarisation and electrochemical impedance spectroscopy (EIS) methods. Results showed that corrosion performance of copolymer coatings depends on the feed ratio of both the monomer units in copolymer chain. It was found that the copolymer feed ratio of mPD:oAP = 70/30 in coatings exhibited the highest performance due to its superior surface nature than other copolymer coatings.

KW - AFM

KW - Corrosion

KW - EIS

KW - Polymer coatings

KW - Porosity

KW - Surface

UR - https://www.scopus.com/pages/publications/84880288626

U2 - 10.1016/j.porgcoat.2013.05.033

DO - 10.1016/j.porgcoat.2013.05.033

M3 - Article

AN - SCOPUS:84880288626

SN - 0300-9440

VL - 76

SP - 1445

EP - 1453

JO - Progress in Organic Coatings

JF - Progress in Organic Coatings

IS - 10

ER -

Poly(m-phenylendiamine-co-o-aminophenol) coatings on mild steel: Effect of comonomers feed ratio on surface and corrosion protection aspects

Abstract

Keywords

ASJC Scopus subject areas

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