Polyhydroxybutyrate-b-polyethyleneglycol block copolymer for the solid phase extraction of lead and copper in water, baby foods, tea and coffee samples

Sham Kumar Wadhwa; Mustafa Tuzen; Tasneem Gul Kazi; Mustafa Soylak; Baki Hazer

doi:10.1016/j.foodchem.2013.11.133

Polyhydroxybutyrate-b-polyethyleneglycol block copolymer for the solid phase extraction of lead and copper in water, baby foods, tea and coffee samples

Sham Kumar Wadhwa
, Mustafa Tuzen
, Tasneem Gul Kazi
, Mustafa Soylak^*
, Baki Hazer

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

67 Scopus citations

Abstract

A new adsorbent, polyhydroxybutyrate-b-polyethyleneglycol, was used for the separation and preconcentration of copper(II) and lead(II) ions prior to their flame atomic absorption spectrometric detections. The influences of parameters such as pH, amount of adsorbent, flow rates and sample volumes were investigated. The polymer does not interact with alkaline, alkaline-earth metals and transition metals. The enrichment factor was 50. The detection limits were 0.32 μg L^-1 and 1.82 μg L^-1 for copper and lead, respectively. The recovery values were found >95%. The relative standard deviations were found to be less than 6%. The validation of the procedure was performed by analysing certified reference materials; NIST SRM 1515 Apple leaves, IAEA-336 Lichen and GBW-07605 Tea. The method was successfully applied for the analysis of analytes in water and food samples.

Original language	English
Pages (from-to)	75-80
Number of pages	6
Journal	Food Chemistry
Volume	152
DOIs	https://doi.org/10.1016/j.foodchem.2013.11.133
State	Published - 1 Jun 2014
Externally published	Yes

Bibliographical note

Funding Information:
Sham Kumar wishes to thank TUBITAK-BIDEB, Ankara, Turkey, for sponsoring this research project under the Research Fellowship Program for Foreign Citizens (2216). Dr. Mustafa Tuzen wishes to thank Turkish Academy of Sciences for financial support. This work was also partially supported by TUBITAK (Grant # 211T016 ) in terms of the preparation of the polyester.

Keywords

Copper
Food
Lead
Polyhydroxybutyrate-b-polyethyleneglycol
Solid phase extraction
Water

ASJC Scopus subject areas

Analytical Chemistry
Food Science

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10.1016/j.foodchem.2013.11.133

Cite this

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title = "Polyhydroxybutyrate-b-polyethyleneglycol block copolymer for the solid phase extraction of lead and copper in water, baby foods, tea and coffee samples",

abstract = "A new adsorbent, polyhydroxybutyrate-b-polyethyleneglycol, was used for the separation and preconcentration of copper(II) and lead(II) ions prior to their flame atomic absorption spectrometric detections. The influences of parameters such as pH, amount of adsorbent, flow rates and sample volumes were investigated. The polymer does not interact with alkaline, alkaline-earth metals and transition metals. The enrichment factor was 50. The detection limits were 0.32 μg L-1 and 1.82 μg L-1 for copper and lead, respectively. The recovery values were found >95\%. The relative standard deviations were found to be less than 6\%. The validation of the procedure was performed by analysing certified reference materials; NIST SRM 1515 Apple leaves, IAEA-336 Lichen and GBW-07605 Tea. The method was successfully applied for the analysis of analytes in water and food samples.",

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author = "Wadhwa, \{Sham Kumar\} and Mustafa Tuzen and Kazi, \{Tasneem Gul\} and Mustafa Soylak and Baki Hazer",

note = "Funding Information: Sham Kumar wishes to thank TUBITAK-BIDEB, Ankara, Turkey, for sponsoring this research project under the Research Fellowship Program for Foreign Citizens (2216). Dr. Mustafa Tuzen wishes to thank Turkish Academy of Sciences for financial support. This work was also partially supported by TUBITAK (Grant \# 211T016 ) in terms of the preparation of the polyester.",

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doi = "10.1016/j.foodchem.2013.11.133",

language = "English",

volume = "152",

pages = "75--80",

journal = "Food Chemistry",

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T1 - Polyhydroxybutyrate-b-polyethyleneglycol block copolymer for the solid phase extraction of lead and copper in water, baby foods, tea and coffee samples

AU - Wadhwa, Sham Kumar

AU - Tuzen, Mustafa

AU - Kazi, Tasneem Gul

AU - Soylak, Mustafa

AU - Hazer, Baki

N1 - Funding Information: Sham Kumar wishes to thank TUBITAK-BIDEB, Ankara, Turkey, for sponsoring this research project under the Research Fellowship Program for Foreign Citizens (2216). Dr. Mustafa Tuzen wishes to thank Turkish Academy of Sciences for financial support. This work was also partially supported by TUBITAK (Grant # 211T016 ) in terms of the preparation of the polyester.

PY - 2014/6/1

Y1 - 2014/6/1

N2 - A new adsorbent, polyhydroxybutyrate-b-polyethyleneglycol, was used for the separation and preconcentration of copper(II) and lead(II) ions prior to their flame atomic absorption spectrometric detections. The influences of parameters such as pH, amount of adsorbent, flow rates and sample volumes were investigated. The polymer does not interact with alkaline, alkaline-earth metals and transition metals. The enrichment factor was 50. The detection limits were 0.32 μg L-1 and 1.82 μg L-1 for copper and lead, respectively. The recovery values were found >95%. The relative standard deviations were found to be less than 6%. The validation of the procedure was performed by analysing certified reference materials; NIST SRM 1515 Apple leaves, IAEA-336 Lichen and GBW-07605 Tea. The method was successfully applied for the analysis of analytes in water and food samples.

AB - A new adsorbent, polyhydroxybutyrate-b-polyethyleneglycol, was used for the separation and preconcentration of copper(II) and lead(II) ions prior to their flame atomic absorption spectrometric detections. The influences of parameters such as pH, amount of adsorbent, flow rates and sample volumes were investigated. The polymer does not interact with alkaline, alkaline-earth metals and transition metals. The enrichment factor was 50. The detection limits were 0.32 μg L-1 and 1.82 μg L-1 for copper and lead, respectively. The recovery values were found >95%. The relative standard deviations were found to be less than 6%. The validation of the procedure was performed by analysing certified reference materials; NIST SRM 1515 Apple leaves, IAEA-336 Lichen and GBW-07605 Tea. The method was successfully applied for the analysis of analytes in water and food samples.

KW - Copper

KW - Food

KW - Lead

KW - Polyhydroxybutyrate-b-polyethyleneglycol

KW - Solid phase extraction

KW - Water

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M3 - Article

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AN - SCOPUS:84890514745

SN - 0308-8146

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JO - Food Chemistry

JF - Food Chemistry

ER -

Polyhydroxybutyrate-b-polyethyleneglycol block copolymer for the solid phase extraction of lead and copper in water, baby foods, tea and coffee samples

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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