Photocatalytic performances and mechanisms of two coordination polymers based on rigid tricarboxylate

Jing Wen Yan; Jian Wu; Lu Lu; Jun Wang; Jian Guo; Hiroshi Sakiyama; Mohd Muddassir; M. Shahnawaz Khan

doi:10.1016/j.jssc.2022.123602

Photocatalytic performances and mechanisms of two coordination polymers based on rigid tricarboxylate

Jing Wen Yan
, Jian Wu
, Lu Lu^*
, Jun Wang
, Jian Guo^*
, Hiroshi Sakiyama
, Mohd Muddassir
, M. Shahnawaz Khan

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

In this work two new coordination polymers (CPs) with formulas [Zn₂(Cl)(BTC)(bmb)₂] (1) and [Cd₂(H₂O)₂(BTC)₂·H₂bmb·6H₂O] (2) (bmb=1,4-bis(2-methylimidazol-1-yl)butane and H₃BTC = 1,3,5-benzenetricarboxylic acid), have been prepared and characterized by various spectroscopic data. The single crystal X-ray data suggests that 1 comprises a 2D layered network and 2 has a 3D porous framework with pcu-type topology. The photocatalytic properties revealed that 2 could successfully degrade organic dyes such as Rhodamine B (Rh B), methylene orange (MO), and methylene blue (MB). Further, the trapping experiment established the active species in the photodegradation process.

Original language	English
Article number	123602
Journal	Journal of Solid State Chemistry
Volume	316
DOIs	https://doi.org/10.1016/j.jssc.2022.123602
State	Published - Dec 2022
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2022 Elsevier Inc.

Keywords

Cd(II)
Coordination polymer
Dyes
Mechanism
Photocatalysis

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.jssc.2022.123602

Cite this

@article{06685e283d4147a7b56e7d4674615372,

title = "Photocatalytic performances and mechanisms of two coordination polymers based on rigid tricarboxylate",

abstract = "In this work two new coordination polymers (CPs) with formulas [Zn2(Cl)(BTC)(bmb)2] (1) and [Cd2(H2O)2(BTC)2·H2bmb·6H2O] (2) (bmb=1,4-bis(2-methylimidazol-1-yl)butane and H3BTC = 1,3,5-benzenetricarboxylic acid), have been prepared and characterized by various spectroscopic data. The single crystal X-ray data suggests that 1 comprises a 2D layered network and 2 has a 3D porous framework with pcu-type topology. The photocatalytic properties revealed that 2 could successfully degrade organic dyes such as Rhodamine B (Rh B), methylene orange (MO), and methylene blue (MB). Further, the trapping experiment established the active species in the photodegradation process.",

keywords = "Cd(II), Coordination polymer, Dyes, Mechanism, Photocatalysis",

author = "Yan, \{Jing Wen\} and Jian Wu and Lu Lu and Jun Wang and Jian Guo and Hiroshi Sakiyama and Mohd Muddassir and Khan, \{M. Shahnawaz\}",

note = "Publisher Copyright: {\textcopyright} 2022 Elsevier Inc.",

year = "2022",

month = dec,

doi = "10.1016/j.jssc.2022.123602",

language = "English",

volume = "316",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

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TY - JOUR

T1 - Photocatalytic performances and mechanisms of two coordination polymers based on rigid tricarboxylate

AU - Yan, Jing Wen

AU - Wu, Jian

AU - Lu, Lu

AU - Wang, Jun

AU - Guo, Jian

AU - Sakiyama, Hiroshi

AU - Muddassir, Mohd

AU - Khan, M. Shahnawaz

PY - 2022/12

Y1 - 2022/12

N2 - In this work two new coordination polymers (CPs) with formulas [Zn2(Cl)(BTC)(bmb)2] (1) and [Cd2(H2O)2(BTC)2·H2bmb·6H2O] (2) (bmb=1,4-bis(2-methylimidazol-1-yl)butane and H3BTC = 1,3,5-benzenetricarboxylic acid), have been prepared and characterized by various spectroscopic data. The single crystal X-ray data suggests that 1 comprises a 2D layered network and 2 has a 3D porous framework with pcu-type topology. The photocatalytic properties revealed that 2 could successfully degrade organic dyes such as Rhodamine B (Rh B), methylene orange (MO), and methylene blue (MB). Further, the trapping experiment established the active species in the photodegradation process.

AB - In this work two new coordination polymers (CPs) with formulas [Zn2(Cl)(BTC)(bmb)2] (1) and [Cd2(H2O)2(BTC)2·H2bmb·6H2O] (2) (bmb=1,4-bis(2-methylimidazol-1-yl)butane and H3BTC = 1,3,5-benzenetricarboxylic acid), have been prepared and characterized by various spectroscopic data. The single crystal X-ray data suggests that 1 comprises a 2D layered network and 2 has a 3D porous framework with pcu-type topology. The photocatalytic properties revealed that 2 could successfully degrade organic dyes such as Rhodamine B (Rh B), methylene orange (MO), and methylene blue (MB). Further, the trapping experiment established the active species in the photodegradation process.

KW - Cd(II)

KW - Coordination polymer

KW - Dyes

KW - Mechanism

KW - Photocatalysis

UR - https://www.scopus.com/pages/publications/85139300511

U2 - 10.1016/j.jssc.2022.123602

DO - 10.1016/j.jssc.2022.123602

M3 - Article

AN - SCOPUS:85139300511

SN - 0022-4596

VL - 316

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

M1 - 123602

ER -

Photocatalytic performances and mechanisms of two coordination polymers based on rigid tricarboxylate

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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