Phenazine Porous Polymers for Radioactive Iodine Capture

Hassan A. Amasha; Nagendra Kulal; Munzir H. Sulaiman; Tariq A. Al-Abdullah; Othman Charles S. Al Hamouz

doi:10.1007/978-3-031-64362-0_16

Phenazine Porous Polymers for Radioactive Iodine Capture

Hassan A. Amasha, Nagendra Kulal, Munzir H. Sulaiman, Tariq A. Al-Abdullah, Othman Charles S. Al Hamouz^*

^*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

The removal of radioactive iodine from different environments enables the use of nuclear energy in a sustainable and efficient way. In this study we report the synthesis of three novel porous polymers via microwave assisted Friedel crafts polymerization of phenazine with pyrrole (PHP), Thiophene (PHT) and furan (PHF) with dimethoxymethane as a linker and iron (III) chloride as a catalyst. The polymers showed permanent porosity with surface areas of 137–330 m²/g and good thermal stability. The efficiency of the synthesized porous polymers in the removal of volatile iodine reached 885- 1005 mg/g capacity whereas the removal capacities reached 202–222 mg/g in cyclohexane solution. Their excellent removal capabilities accompanied with their rigid and stable structures makes them an excellent choice for the removal of radioactive iodine waste.

Original language	English
Title of host publication	Challenges and Recent Advancements in Nuclear Energy Systems - Proceedings of Saudi International Conference on Nuclear Power Engineering SCOPE
Editors	Afaque Shams, Khaled Al-Athel, Iztok Tiselj, Andreas Pautz, Tomasz Kwiatkowski
Publisher	Springer Science and Business Media Deutschland GmbH
Pages	141-153
Number of pages	13
ISBN (Print)	9783031643613
DOIs	https://doi.org/10.1007/978-3-031-64362-0_16
State	Published - 2024
Event	Saudi International Conference on Nuclear Power Engineering, SCOPE 2023 - Dhahran, Saudi Arabia Duration: 13 Nov 2023 → 15 Nov 2023

Publication series

Name	Lecture Notes in Mechanical Engineering
ISSN (Print)	2195-4356
ISSN (Electronic)	2195-4364

Conference

Conference	Saudi International Conference on Nuclear Power Engineering, SCOPE 2023
Country/Territory	Saudi Arabia
City	Dhahran
Period	13/11/23 → 15/11/23

Bibliographical note

Publisher Copyright:
© The Author(s), under exclusive license to Springer Nature Switzerland AG 2024.

Keywords

Porous polymers
Radioactive Iodine
adsorption
nuclear waste treatment

ASJC Scopus subject areas

Automotive Engineering
Aerospace Engineering
Mechanical Engineering
Fluid Flow and Transfer Processes

Access to Document

10.1007/978-3-031-64362-0_16

Cite this

Amasha, H. A., Kulal, N., Sulaiman, M. H., Al-Abdullah, T. A., & Al Hamouz, O. C. S. (2024). Phenazine Porous Polymers for Radioactive Iodine Capture. In A. Shams, K. Al-Athel, I. Tiselj, A. Pautz, & T. Kwiatkowski (Eds.), Challenges and Recent Advancements in Nuclear Energy Systems - Proceedings of Saudi International Conference on Nuclear Power Engineering SCOPE (pp. 141-153). (Lecture Notes in Mechanical Engineering). Springer Science and Business Media Deutschland GmbH. https://doi.org/10.1007/978-3-031-64362-0_16

Amasha, Hassan A. ; Kulal, Nagendra ; Sulaiman, Munzir H. et al. / Phenazine Porous Polymers for Radioactive Iodine Capture. Challenges and Recent Advancements in Nuclear Energy Systems - Proceedings of Saudi International Conference on Nuclear Power Engineering SCOPE. editor / Afaque Shams ; Khaled Al-Athel ; Iztok Tiselj ; Andreas Pautz ; Tomasz Kwiatkowski. Springer Science and Business Media Deutschland GmbH, 2024. pp. 141-153 (Lecture Notes in Mechanical Engineering).

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abstract = "The removal of radioactive iodine from different environments enables the use of nuclear energy in a sustainable and efficient way. In this study we report the synthesis of three novel porous polymers via microwave assisted Friedel crafts polymerization of phenazine with pyrrole (PHP), Thiophene (PHT) and furan (PHF) with dimethoxymethane as a linker and iron (III) chloride as a catalyst. The polymers showed permanent porosity with surface areas of 137–330 m2/g and good thermal stability. The efficiency of the synthesized porous polymers in the removal of volatile iodine reached 885- 1005 mg/g capacity whereas the removal capacities reached 202–222 mg/g in cyclohexane solution. Their excellent removal capabilities accompanied with their rigid and stable structures makes them an excellent choice for the removal of radioactive iodine waste.",

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Amasha, HA, Kulal, N, Sulaiman, MH, Al-Abdullah, TA & Al Hamouz, OCS 2024, Phenazine Porous Polymers for Radioactive Iodine Capture. in A Shams, K Al-Athel, I Tiselj, A Pautz & T Kwiatkowski (eds), Challenges and Recent Advancements in Nuclear Energy Systems - Proceedings of Saudi International Conference on Nuclear Power Engineering SCOPE. Lecture Notes in Mechanical Engineering, Springer Science and Business Media Deutschland GmbH, pp. 141-153, Saudi International Conference on Nuclear Power Engineering, SCOPE 2023, Dhahran, Saudi Arabia, 13/11/23. https://doi.org/10.1007/978-3-031-64362-0_16

Phenazine Porous Polymers for Radioactive Iodine Capture. / Amasha, Hassan A.; Kulal, Nagendra; Sulaiman, Munzir H. et al.
Challenges and Recent Advancements in Nuclear Energy Systems - Proceedings of Saudi International Conference on Nuclear Power Engineering SCOPE. ed. / Afaque Shams; Khaled Al-Athel; Iztok Tiselj; Andreas Pautz; Tomasz Kwiatkowski. Springer Science and Business Media Deutschland GmbH, 2024. p. 141-153 (Lecture Notes in Mechanical Engineering).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

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AU - Amasha, Hassan A.

AU - Kulal, Nagendra

AU - Sulaiman, Munzir H.

AU - Al-Abdullah, Tariq A.

AU - Al Hamouz, Othman Charles S.

N1 - Publisher Copyright: © The Author(s), under exclusive license to Springer Nature Switzerland AG 2024.

PY - 2024

Y1 - 2024

N2 - The removal of radioactive iodine from different environments enables the use of nuclear energy in a sustainable and efficient way. In this study we report the synthesis of three novel porous polymers via microwave assisted Friedel crafts polymerization of phenazine with pyrrole (PHP), Thiophene (PHT) and furan (PHF) with dimethoxymethane as a linker and iron (III) chloride as a catalyst. The polymers showed permanent porosity with surface areas of 137–330 m2/g and good thermal stability. The efficiency of the synthesized porous polymers in the removal of volatile iodine reached 885- 1005 mg/g capacity whereas the removal capacities reached 202–222 mg/g in cyclohexane solution. Their excellent removal capabilities accompanied with their rigid and stable structures makes them an excellent choice for the removal of radioactive iodine waste.

AB - The removal of radioactive iodine from different environments enables the use of nuclear energy in a sustainable and efficient way. In this study we report the synthesis of three novel porous polymers via microwave assisted Friedel crafts polymerization of phenazine with pyrrole (PHP), Thiophene (PHT) and furan (PHF) with dimethoxymethane as a linker and iron (III) chloride as a catalyst. The polymers showed permanent porosity with surface areas of 137–330 m2/g and good thermal stability. The efficiency of the synthesized porous polymers in the removal of volatile iodine reached 885- 1005 mg/g capacity whereas the removal capacities reached 202–222 mg/g in cyclohexane solution. Their excellent removal capabilities accompanied with their rigid and stable structures makes them an excellent choice for the removal of radioactive iodine waste.

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T2 - Saudi International Conference on Nuclear Power Engineering, SCOPE 2023

Y2 - 13 November 2023 through 15 November 2023

ER -

Amasha HA, Kulal N, Sulaiman MH, Al-Abdullah TA , Al Hamouz OCS. Phenazine Porous Polymers for Radioactive Iodine Capture. In Shams A, Al-Athel K, Tiselj I, Pautz A, Kwiatkowski T, editors, Challenges and Recent Advancements in Nuclear Energy Systems - Proceedings of Saudi International Conference on Nuclear Power Engineering SCOPE. Springer Science and Business Media Deutschland GmbH. 2024. p. 141-153. (Lecture Notes in Mechanical Engineering). doi: 10.1007/978-3-031-64362-0_16

Phenazine Porous Polymers for Radioactive Iodine Capture

Abstract

Publication series

Conference

Bibliographical note

Keywords

ASJC Scopus subject areas

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