PdNPs@ZIF-8 Micro-Nanostructured Catalyst of Regioselective Mizoriki-Heck Olefination

Mohammed Nasiruzzaman Shaikh; Md Abdul Aziz; Aasif Helal; Abdul Nasar Kalanthoden; Zain H. Yamani

doi:10.1002/slct.201701270

PdNPs@ZIF-8 Micro-Nanostructured Catalyst of Regioselective Mizoriki-Heck Olefination

Mohammed Nasiruzzaman Shaikh^*, Md Abdul Aziz, Aasif Helal, Abdul Nasar Kalanthoden, Zain H. Yamani

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

ZIF-8-supported Pd nanoparticles (PdNPs) have been synthesized as a heterogeneous catalyst (PdNPs@ZIF-8) for the Mizoriki-Heck C−C bond formation reaction. The hexagonal ZIF-8 microcrystals were converted to rod- and flower-shaped PdNPs@ZIF-8 with the controlled addition of formic acid. PdNPs@ZIF-8 was applied to catalyze the coupling of arylhalides with substituted styrenes, achieving excellent conversion with very high selectivity.

Original language	English
Pages (from-to)	9052-9057
Number of pages	6
Journal	ChemistrySelect
Volume	2
Issue number	28
DOIs	https://doi.org/10.1002/slct.201701270
State	Published - 29 Sep 2017

Bibliographical note

Publisher Copyright:
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Keywords

Coupling reaction
MOFs
Mizoriki-Heck reaction
Pd nanoparticles
ZIF-8

ASJC Scopus subject areas

General Chemistry

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title = "PdNPs@ZIF-8 Micro-Nanostructured Catalyst of Regioselective Mizoriki-Heck Olefination",

abstract = "ZIF-8-supported Pd nanoparticles (PdNPs) have been synthesized as a heterogeneous catalyst (PdNPs@ZIF-8) for the Mizoriki-Heck C−C bond formation reaction. The hexagonal ZIF-8 microcrystals were converted to rod- and flower-shaped PdNPs@ZIF-8 with the controlled addition of formic acid. PdNPs@ZIF-8 was applied to catalyze the coupling of arylhalides with substituted styrenes, achieving excellent conversion with very high selectivity.",

keywords = "Coupling reaction, MOFs, Mizoriki-Heck reaction, Pd nanoparticles, ZIF-8",

author = "Shaikh, \{Mohammed Nasiruzzaman\} and Aziz, \{Md Abdul\} and Aasif Helal and Kalanthoden, \{Abdul Nasar\} and Yamani, \{Zain H.\}",

note = "Publisher Copyright: {\textcopyright} 2017 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2017",

month = sep,

day = "29",

doi = "10.1002/slct.201701270",

language = "English",

volume = "2",

pages = "9052--9057",

journal = "ChemistrySelect",

issn = "2365-6549",

publisher = "Wiley-Blackwell Publishing Ltd",

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T1 - PdNPs@ZIF-8 Micro-Nanostructured Catalyst of Regioselective Mizoriki-Heck Olefination

AU - Shaikh, Mohammed Nasiruzzaman

AU - Aziz, Md Abdul

AU - Helal, Aasif

AU - Kalanthoden, Abdul Nasar

AU - Yamani, Zain H.

PY - 2017/9/29

Y1 - 2017/9/29

N2 - ZIF-8-supported Pd nanoparticles (PdNPs) have been synthesized as a heterogeneous catalyst (PdNPs@ZIF-8) for the Mizoriki-Heck C−C bond formation reaction. The hexagonal ZIF-8 microcrystals were converted to rod- and flower-shaped PdNPs@ZIF-8 with the controlled addition of formic acid. PdNPs@ZIF-8 was applied to catalyze the coupling of arylhalides with substituted styrenes, achieving excellent conversion with very high selectivity.

AB - ZIF-8-supported Pd nanoparticles (PdNPs) have been synthesized as a heterogeneous catalyst (PdNPs@ZIF-8) for the Mizoriki-Heck C−C bond formation reaction. The hexagonal ZIF-8 microcrystals were converted to rod- and flower-shaped PdNPs@ZIF-8 with the controlled addition of formic acid. PdNPs@ZIF-8 was applied to catalyze the coupling of arylhalides with substituted styrenes, achieving excellent conversion with very high selectivity.

KW - Coupling reaction

KW - MOFs

KW - Mizoriki-Heck reaction

KW - Pd nanoparticles

KW - ZIF-8

UR - https://www.scopus.com/pages/publications/85041847260

U2 - 10.1002/slct.201701270

DO - 10.1002/slct.201701270

M3 - Article

AN - SCOPUS:85041847260

SN - 2365-6549

VL - 2

SP - 9052

EP - 9057

JO - ChemistrySelect

JF - ChemistrySelect

IS - 28

ER -

PdNPs@ZIF-8 Micro-Nanostructured Catalyst of Regioselective Mizoriki-Heck Olefination

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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