Palladium(II)-catalyzed regioselective carbonylative coupling of aniline derivatives with terminal aryl acetylenes to give acrylamides under syngas conditions

B. El Ali; A. El-Ghanam; M. Fettouhi; J. Tijani

doi:10.1016/S0040-4039(00)00899-6

Palladium(II)-catalyzed regioselective carbonylative coupling of aniline derivatives with terminal aryl acetylenes to give acrylamides under syngas conditions

B. El Ali, A. El-Ghanam, M. Fettouhi, J. Tijani

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

The carbonylative coupling of aniline derivatives (1a-h) with terminal aryl acetylenes (2a, b) catalyzed by Pd(OAc)₂ and 1,4- bis(diphenylphosphino)butane (dppb) under syngas conditions affords acrylamide derivatives 3 or 3' in excellent yields and selectivities. (C) 2000 Published by Elsevier Science Ltd.

Original language	English
Pages (from-to)	5761-5764
Number of pages	4
Journal	Tetrahedron Letters
Volume	41
Issue number	30
DOIs	https://doi.org/10.1016/S0040-4039(00)00899-6
State	Published - 22 Jul 2000

Bibliographical note

Funding Information:
We thank the King Fahd University of Petroleum and Minerals (KFUPM-Saudi Arabia) for financial support of this project.

Keywords

Acrylamides
Alkynes
Aniline
Carbonylative coupling
Palladium
Syngas

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)00899-6

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title = "Palladium(II)-catalyzed regioselective carbonylative coupling of aniline derivatives with terminal aryl acetylenes to give acrylamides under syngas conditions",

abstract = "The carbonylative coupling of aniline derivatives (1a-h) with terminal aryl acetylenes (2a, b) catalyzed by Pd(OAc)2 and 1,4- bis(diphenylphosphino)butane (dppb) under syngas conditions affords acrylamide derivatives 3 or 3' in excellent yields and selectivities. (C) 2000 Published by Elsevier Science Ltd.",

keywords = "Acrylamides, Alkynes, Aniline, Carbonylative coupling, Palladium, Syngas",

author = "\{El Ali\}, B. and A. El-Ghanam and M. Fettouhi and J. Tijani",

note = "Funding Information: We thank the King Fahd University of Petroleum and Minerals (KFUPM-Saudi Arabia) for financial support of this project. ",

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doi = "10.1016/S0040-4039(00)00899-6",

language = "English",

volume = "41",

pages = "5761--5764",

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T1 - Palladium(II)-catalyzed regioselective carbonylative coupling of aniline derivatives with terminal aryl acetylenes to give acrylamides under syngas conditions

AU - El Ali, B.

AU - El-Ghanam, A.

AU - Fettouhi, M.

AU - Tijani, J.

N1 - Funding Information: We thank the King Fahd University of Petroleum and Minerals (KFUPM-Saudi Arabia) for financial support of this project.

PY - 2000/7/22

Y1 - 2000/7/22

N2 - The carbonylative coupling of aniline derivatives (1a-h) with terminal aryl acetylenes (2a, b) catalyzed by Pd(OAc)2 and 1,4- bis(diphenylphosphino)butane (dppb) under syngas conditions affords acrylamide derivatives 3 or 3' in excellent yields and selectivities. (C) 2000 Published by Elsevier Science Ltd.

AB - The carbonylative coupling of aniline derivatives (1a-h) with terminal aryl acetylenes (2a, b) catalyzed by Pd(OAc)2 and 1,4- bis(diphenylphosphino)butane (dppb) under syngas conditions affords acrylamide derivatives 3 or 3' in excellent yields and selectivities. (C) 2000 Published by Elsevier Science Ltd.

KW - Acrylamides

KW - Alkynes

KW - Aniline

KW - Carbonylative coupling

KW - Palladium

KW - Syngas

UR - https://www.scopus.com/pages/publications/0034702592

U2 - 10.1016/S0040-4039(00)00899-6

DO - 10.1016/S0040-4039(00)00899-6

M3 - Article

AN - SCOPUS:0034702592

SN - 0040-4039

VL - 41

SP - 5761

EP - 5764

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 30

ER -

Palladium(II)-catalyzed regioselective carbonylative coupling of aniline derivatives with terminal aryl acetylenes to give acrylamides under syngas conditions

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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