Oxygen vacancy-rich mesoporous silica KCC-1 for CO2 methanation

M. Y.S. Hamid; M. L. Firmansyah; S. Triwahyono; A. A. Jalil; R. R. Mukti; E. Febriyanti; V. Suendo; H. D. Setiabudi; M. Mohamed; W. Nabgan

doi:10.1016/j.apcata.2016.12.023

Oxygen vacancy-rich mesoporous silica KCC-1 for CO₂ methanation

M. Y.S. Hamid
, M. L. Firmansyah
, S. Triwahyono^*
, A. A. Jalil
, R. R. Mukti
, E. Febriyanti
, V. Suendo
, H. D. Setiabudi
, M. Mohamed
, W. Nabgan

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

168 Scopus citations

Abstract

Mesoporous silica KCC-1 was successfully synthesized by microemulsion system coupled with microwave-assisted hydrothermal method. Mesoporous silica KCC-1 exhibited spherical morphology surrounded with dendritic fiber with the particle size of 200–400 nm and BET surface area of 773 m²/g. Mesoporous silica KCC-1 has significantly higher number of basicity and oxygen vacancy than those of MCM-41 and SiO₂which directly correlated with the catalytic performance of the catalyst. The activity of mesoporous silica KCC-1 in CO₂methanation is five-fold higher than MCM-41 with the yield of CH₄reached 38.9% at 723 K.

Original language	English
Pages (from-to)	86-94
Number of pages	9
Journal	Applied Catalysis A: General
Volume	532
DOIs	https://doi.org/10.1016/j.apcata.2016.12.023
State	Published - 2017
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2016 Elsevier B.V.

Keywords

Basicity
COmethanation
Mesoporous silica KCC-1
Microemulsion system
Oxygen vacancy

ASJC Scopus subject areas

Catalysis
Process Chemistry and Technology

Access to Document

10.1016/j.apcata.2016.12.023

Cite this

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title = "Oxygen vacancy-rich mesoporous silica KCC-1 for CO2 methanation",

abstract = "Mesoporous silica KCC-1 was successfully synthesized by microemulsion system coupled with microwave-assisted hydrothermal method. Mesoporous silica KCC-1 exhibited spherical morphology surrounded with dendritic fiber with the particle size of 200–400 nm and BET surface area of 773 m2/g. Mesoporous silica KCC-1 has significantly higher number of basicity and oxygen vacancy than those of MCM-41 and SiO2which directly correlated with the catalytic performance of the catalyst. The activity of mesoporous silica KCC-1 in CO2methanation is five-fold higher than MCM-41 with the yield of CH4reached 38.9\% at 723 K.",

keywords = "Basicity, COmethanation, Mesoporous silica KCC-1, Microemulsion system, Oxygen vacancy",

author = "Hamid, \{M. Y.S.\} and Firmansyah, \{M. L.\} and S. Triwahyono and Jalil, \{A. A.\} and Mukti, \{R. R.\} and E. Febriyanti and V. Suendo and Setiabudi, \{H. D.\} and M. Mohamed and W. Nabgan",

note = "Publisher Copyright: {\textcopyright} 2016 Elsevier B.V.",

year = "2017",

doi = "10.1016/j.apcata.2016.12.023",

language = "English",

volume = "532",

pages = "86--94",

journal = "Applied Catalysis A: General",

issn = "0926-860X",

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T1 - Oxygen vacancy-rich mesoporous silica KCC-1 for CO2 methanation

AU - Hamid, M. Y.S.

AU - Firmansyah, M. L.

AU - Triwahyono, S.

AU - Jalil, A. A.

AU - Mukti, R. R.

AU - Febriyanti, E.

AU - Suendo, V.

AU - Setiabudi, H. D.

AU - Mohamed, M.

AU - Nabgan, W.

PY - 2017

Y1 - 2017

N2 - Mesoporous silica KCC-1 was successfully synthesized by microemulsion system coupled with microwave-assisted hydrothermal method. Mesoporous silica KCC-1 exhibited spherical morphology surrounded with dendritic fiber with the particle size of 200–400 nm and BET surface area of 773 m2/g. Mesoporous silica KCC-1 has significantly higher number of basicity and oxygen vacancy than those of MCM-41 and SiO2which directly correlated with the catalytic performance of the catalyst. The activity of mesoporous silica KCC-1 in CO2methanation is five-fold higher than MCM-41 with the yield of CH4reached 38.9% at 723 K.

AB - Mesoporous silica KCC-1 was successfully synthesized by microemulsion system coupled with microwave-assisted hydrothermal method. Mesoporous silica KCC-1 exhibited spherical morphology surrounded with dendritic fiber with the particle size of 200–400 nm and BET surface area of 773 m2/g. Mesoporous silica KCC-1 has significantly higher number of basicity and oxygen vacancy than those of MCM-41 and SiO2which directly correlated with the catalytic performance of the catalyst. The activity of mesoporous silica KCC-1 in CO2methanation is five-fold higher than MCM-41 with the yield of CH4reached 38.9% at 723 K.

KW - Basicity

KW - COmethanation

KW - Mesoporous silica KCC-1

KW - Microemulsion system

KW - Oxygen vacancy

UR - https://www.scopus.com/pages/publications/85008155990

U2 - 10.1016/j.apcata.2016.12.023

DO - 10.1016/j.apcata.2016.12.023

M3 - Article

AN - SCOPUS:85008155990

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VL - 532

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EP - 94

JO - Applied Catalysis A: General

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