Optimization of preoxidation to reduce scaling during cleaning-in-place of membrane treatment

This study investigated the potential for reducing scaling during chemical cleaning of polyvinylidene fluoride membranes by optimizing preoxidation dose and pH. Membranes were fouled by a solution containing inorganic foulants (aluminum, iron, and manganese), humic acid, and kaolin at a Ca⁺² strength of 0.5 mM and varying the preoxidation dose. Energy-dispersive spectroscopy was used to verify the presence of inorganic foulants after cleaning. Fourier-transform infrared spectroscopy revealed changes in C[sbnd]Cl and C–F functional groups, with bond vibrations at 542 cm⁻¹ and 1199 cm⁻¹, respectively. Minimum irreversible fouling of 5.4% and maximum flux recovery of 88.8% of the initial value were associated with a preoxidation dose of 1.5 mg/L and pH 8.5. A decrease in amount of aluminum from 5.79 ± 0.021 mg to 3.85 ± 0.054 mg in the presence of humic acid with a removal efficiency greater than 60% was due to alteration of the feed solution, as revealed by mass-balance analysis. Membrane characterization and fouling reversibility analysis confirmed that preoxidation of the feed solution produced less scaling during chemical cleaning. The cake layer fouling contribution was determined by fitting results of Hermia's fouling model analysis, with 1.34–1.85 times lower total fouling indices and 3–5.5 times lower chemically irreversible fouling indices at pH 8.5 and a preoxidation dose of 1.5 mg/L.