Optimization of membrane modification using SiO₂ for robust anti-fouling performance with calcium-humic acid feed in membrane distillation

The goal of this study was to prepare a robust anti-wetting and anti-fouling polyethersulfone (PES) membrane for the rejection of a highly saline (NaCl and CaCl₂·2H₂O) feed solution containing humic acid (HA) in direct contact membrane distillation (DCMD). Response surface methodology (RSM) was used to determine the optimum formulation of the used materials. The variable factors selected were polydimethyl siloxane (PDMS) and silica (SiO₂); liquid entry pressure (LEP) and contact angle (CA) were selected as responses. Scanning electron microscopy (SEM) analysis confirmed the SiO₂ deposition and Fourier-transform infrared spectroscopy (FTIR) test evidenced the new functional groups i.e., Si–OH, siloxane, and C–F bond vibrations at 3446, 1099 cm⁻¹, and 1150–1240 cm⁻¹ respectively on the membrane surface. The average roughness (Ra) was increased four times for the coated membranes (0.202–0.242 µm) as compared to that for pristine PES membrane (0.053 µm). The optimum PES-13 membrane exhibited consistent flux of 12 LMH and salt rejection (> 99%) with anti-fouling characteristic in DCMD using the feed solution of 3.5 wt% NaCl + 10 mM CaCl₂·2H₂O + 10 mg L⁻¹ HA. The PES-13 membrane may therefore be a key membrane for application in DCMD against CaCl₂·2H₂O-containing salty solutions with HA.